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Kinetics of glycine oxidation by N-bromophthalimide in the presence of sodium dodecyl sulfate

  • Published:
Journal of Surfactants and Detergents

Abstract

The kinetics of oxidation of glycine by N-bromophthalimide (NBP) were studied in the presence of an anionic surfactant, sodium dodecyl sulfate, in acidic medium at 308 K. The rate of reaction was found to have first-order dependence on [NBP] and fractional-order dependence on [glycine] and [H+]. The addition of reduced product of the oxidant had no significant effect on the rate of reaction. Increasing [Hg(OAc)2] and [Br−] increased the rate of reaction, whereas a change in ionic strength (μ) of the medium had no effect on oxidation velocity. The rate of reaction decreased with a decrease in dielectric constant of the medium. HCN was identified as the main oxidation product of the reactions. The various activation parameters have been computed. A suitable mechanism consistent with the experimental findings has been proposed. The index of cooperativity and the micelle binding constant have been calculated.

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Abbreviations

CMC:

critical micelle concentration

NBP:

N-bromophthalimide

NBS:

N-bromosuccinimide

NBSA:

N-bromosaccharin

SDS:

sodium dodecyl sulfate

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Authors and Affiliations

  1. Department of Chemistry, Government Vishwanath Yadar Tamaskar Post Graduate (V.Y.T.P.G.). Autonomous College, Durg, India

    Ajaya K. Singh

  2. Department of Chemistry, Kalyan Mahavidyalaya, Bhilai Nagar, Sector-7, 490006, Durg, Chhattisgarh, India

    Ghanat K. Joshi & Y. R. Katre

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  1. Ghanat K. Joshi
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  2. Y. R. Katre
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Correspondence to Y. R. Katre.

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Joshi, G.K., Katre, Y.R. & Singh, A.K. Kinetics of glycine oxidation by N-bromophthalimide in the presence of sodium dodecyl sulfate. J Surfact Deterg 9, 231–235 (2006). https://doi.org/10.1007/s11743-006-5002-3

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  • DOI: https://doi.org/10.1007/s11743-006-5002-3

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