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TDS-Eh graph analysis: a new water quality index and rural water supply implications of a river affected by mining in south-eastern Nigeria

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Abstract

The Ivo River Basin of south-eastern Nigeria is a water scarce and mining region, which suffers from water scarcity. The influence of mining activities on the quality of the Ivo River and its capacity for community water supply was investigated. Also the efficacy of TDS-Eh graph in explaining water quality was presented. Results indicated that the TDS-Eh graph highlights subtle chemical relationships which control water quality and provide a simple but generic pollution index for rapid water quality assessment. It was also discovered that the Ivo River could become an adequate alternative to groundwater as a source of rural water supply in the study area with an estimated average daily discharge of 6726000 L and a rural population of less than 200000 persons. The Ivo River meets the WHO drinking water standards in 20 physicochemical water quality parameters (pH, temperature, conductivity, turbidity, salinity, TDS, Eh, alkalinity, chloride, nitrate, sulfate, phosphate, calcium, magnesium, iron, manganese, zinc, lead and cadmium) analyzed and can therefore (with little treatment) provide up to 133.4% of average community water demand and 83.8% of maximum community water demand. The impact of mining on Ivo River quality was found to have been moderated by the presence of carbonate rocks which may have enhanced the precipitation of heavy metals from the river.

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References

  • Aguasanta S, Miguel J N, Manuel O, Carlos C (2005). Environmental impact of mining activities in the Odiel River Basin (Sw Spain). Mine Water and the Environment, 24(1): 1

    Article  Google Scholar 

  • APHA (1995). Standard Methods for the Examination of Water and Wastewater. 19th ed.. Washington DC: American Public Health Association

    Google Scholar 

  • Argent R M, Western A W, Neumann L E (2007). Hydrological process investigation using water quality monitoring data. In: Proceedings of the International Congress on Modelling and Simulation, 2347–2353. Canberra, Australia: The Modelling and Simulation Society of Australia and New Zealand

    Google Scholar 

  • Aroh K N, Eze C L, Abam T K S, Gobo A E, Ubong I U (2007). Physicochemical properties of Pit-Water from Ishiagu lead-zinc (Pb/Zn) mine as an index for alkaline classification of the mine drainage. International Journal of Applied Environmental Sciences, 11(4): 19–24

    Google Scholar 

  • Arrigo J S (2011). Using cooperative water quality data for a holistic understanding of rivers and streams: a study of the Neponset River, Massachusetts. Prof Geogr, 63(3): 364–378

    Article  Google Scholar 

  • Awalla C O, Ezeigbo H I (2002). An appraisal of water quality in the Uburu-Okposi Area, Ebonyi State, South Eastern Nigeria. Water Res, 13: 33–39

    Google Scholar 

  • Brown E, Skougslad M W, Fishman M J (1970). Methods for collection and analysis of water samples for dissolved minerals and gases. US Geological Survey, Techniques for Water Resources Investigations, Book 5

  • Brown J G, Glynn P D, Bassett R L (1999). Geochemistry and reactive-transport of metal contaminants in ground water, Pinal Creek Basin, Arizona. Contamination from Hard Rock Mining: 1(3): US Geological Survey, Water Resources Investigations Report 99-4018A: 41–153

    Google Scholar 

  • Caeiro S, Costa M H, Ramos T B, Fernandes F, Silveira N, Coimbra A, Medeiros G, Painho M (2005). Assessing heavy metal contamination in Sado Estuary sediment: An index analysis approach. Ecol Indic, 5(2): 151–169

    Article  Google Scholar 

  • Chima G N, Ezekwe I C, Ijioma M A, Opuene K (2010a). Preliminary assessment of heavy metals in active stream and lake bottom sediments in the Ivo River Basin, Southeast Nigeria. International Journal of Applied Environmental Sciences, 5(6): 803–812

    Google Scholar 

  • Chima G N, Nwaugo V O, Ezekwe I C (2010b). Impact of rock quarrying on Akwukwuo Tributary of the Ivo River in Ishiagu Ebonyi State, Nigeria. International Journal of Applied Environmental Sciences, 6(2): 68–73

    Google Scholar 

  • Church S E, Von Guerard P, Finger S E (2007). Environmental Effects of Historical Mining in the Animas River Watershed, Southwestern. Colorado: US Geological Survey, Fact Sheet, 2007–3051

    Google Scholar 

  • Davis A D, Webb C J, Sorensen J L (1999). Bio-indicator evaluation of water quality impacts from inactive and abandoned mines in the Bear Butte Creek Basin of the Black Hills. SME Annual Meeting, March 1–3, 1999, Denver, USA

  • Destouni G (2005). Sweden. In: Wolkersdorfer C, Bowell R, eds. Contemporary reviews of mine water studies in Europe. Mine Water and the Environment, 24, Supplementary Material. Springer Verlag

  • Duruibe J O, Ogwuegbu M O C, Egwurugwu J N (2007). Heavy metal pollution and human biotoxic effects. International Journal of Physical Science, 2(5): 112–118

    Google Scholar 

  • European Union (1998). Drinking Water Standards. Council Directive 98/83/EC on the Quality ofWater Intended for Human Consumption. Adopted by the Council, on 3 Nov. 1998. http://www.lenntech.com/applications/drinking/standards/eu-s-drinking-water-standards

  • Ezekwe I C (2009). Impact of Mining on the Water Resources of the Ishiagu Area of south-eastern Nigeria. Unpublished Ph.D Thesis. Department of Geography and Planning, Abia State University, Uturu, Nigeria

    Google Scholar 

  • Garbarino J R, Hayes H C, Roth D A, Antweiler R C, Brinton T I, Taylor H E (1995). Heavy Metals in the Mississippi River in Contaminants in the Mississippi River, Meade RH ed.. US Geological Survey, Circular 1133. http://pubs.usgs.gov/circ/circ1133/heavy-metals.html

  • Hanrahan G, Gledhill M, House W A, Worsfold P J (2003). Evaluation of phosphorus concentrations in relation to annual and seasonal physico-chemical water quality parameters in a UK chalk stream. Water Res, 37(15): 3579–3589

    Article  Google Scholar 

  • Hasche-Berger A, Wolkersdorfer C (2005). Germany. In: Wolkersdorfer C, Bowell R, eds. Contemporary reviews of mine water studies in Europe. Mine Water and the Environment, 24, Supplementary Material. Springer Verlag

  • Hutton M, Symon C (1986). The quantities of cadmium, lead, mercury and arsenic entering the UK environment from human activities. Sci Total Environ, 57: 129–150

    Article  Google Scholar 

  • Imes J L (2003). Geohydrologic and biological investigations associated with a New lead-zinc exploration area nearWinona, Missouri and the Viburnum trend of southeastern Missouri. http://Missouri.usgs.gov/fact_sheets/FS-005-02-Imes

  • Imo State Ministry of Works and Transport (IMWT) (1984). Atlas of Imo State Nigeria. C&G Company, Italy

    Google Scholar 

  • Kaverina I, Pogozheva V (2005). Geochemical Study of Lake Imandra Russia: Evaluation of the Effect of Mining Industries on the Water Quality. Master’s Degree Thesis, Department of Civil and Mining Engineering, Lulea University of Technology, Sweden

    Google Scholar 

  • Kentucky River Authority (KRA) (2008). Water Quality Parameters, Kentucky River Basin Report. http://www.uky.edu/WaterResources/Watershed/KRBAR/krwwparameters.htm

  • McBean A E, Rovers F A, Farquhar G J (1995). Solid Landfill Engineering and Design. New Jersey: Prentice-Hall

    Google Scholar 

  • Montgomery C W (2007). Environmental Geology. 5th ed. New York: McGraw-Hill

    Google Scholar 

  • Mountain Empire Community Water Program (2011). Introduction to Water Treatment Math. http://water.me.vccs.edu/courses/ENV115/lesson3_2.htm

  • Narváez J, Richter P, Toral M I (2007). Preliminary physical chemical characterization of river waters and sediments affected by copper mining activity in Central Chile. Application of multivariate analysis. Journal of the Chilean Chemical Society, 52(3) 1261–1265

    Google Scholar 

  • National Population Commission (NPC) (1991). Estimates from Nigeria 1991 Census Figures

  • Nauges C, Whittington D (2010). Estimation of water demand in developing countries: An overview. World Bank Res Obs, 25(2): 263–294

    Article  Google Scholar 

  • Nwaugo V O, Obiekezie S O, Etok C A (2007). Post operational effects of heavy metal mining on soil quality in Ishiagu, Ebonyi State. Journal of Biotechnology and Allied Sciences, 2(3): 242–246

    Google Scholar 

  • Obiekezie S O, Okereke J N, Anyalogbu E, Okorondu S I, Ezejiofor T I N (2006). Underground water quality of rock mining in Ishiagu, Ebonyi State, Nigeria. Estudos de Biologia, 28(63): 61–71

    Google Scholar 

  • Offodile M E (2002). Groundwater study and development in Nigeria, Mecon Geology and Engineering Services Limited, Jos

    Google Scholar 

  • Oteze G E (1990). Trace elements in the groundwater in the Sokoto Basin, Nigeria. Water Res, 12(1): 7–13

    Google Scholar 

  • Peplow D (1999). Environmental impacts of mining in Eastern Washington. Center for Water and Watershed Studies Fact Sheet. University of Washington, Seattle

    Google Scholar 

  • Pope L M (1998). Watershed Trend Analysis and Water Quality Assessment Using Bottom-sediment Cores from Cheney Reservoir, South-Central Kansas. US Geological Survey, Water Resources Investigations Report, 98-4227

  • Gong Q J, Deng J, Xiang Y C, Wang Q F, Yang L Q (2008). Calculating indices by heavy metals in ecological geochemistry assessment and a case study of parks of Beijing. Journal of China University of Geosciences, 19(3): 230–241

    Article  Google Scholar 

  • Rahn P H, Davis A D, Webb C J, Nichols A D (1996). Water quality impacts from mining in the Black Hills, South Dakota. Environmental Geology, 27(1): 38–53

    Article  Google Scholar 

  • Rainwater F H, Thatcher L L (1960). Methods for Collection and Analysis of Water Samples. US Water Supply Pap, 1454: 1–301

    Google Scholar 

  • Therkildsen O (1988). Watering white elephants: lessons from donorfunded planning and implementation of rural water supplies in Tanzania. Scandinavian Institute of African Studies, Uppsala

    Google Scholar 

  • Todd D K (1980). Groundwater Hydrology. John Wiley and Sons

  • USEPA (1996). Environmental indicators of water quality in the United States. EPA 841R96002: http://www.yosemite.epa.gov/water/owrccatalog.nsf

  • Usero J, Gonzalez-Regalado E, Gracia I (1996). Trace metals in the bivalve mollusc Chamelea gallina from the Atlantic coast of southern Spain. Mar Pollut Bull, 32(3): 305–310

    Article  Google Scholar 

  • Walder I F, Nilssen S (2005). Acid rock drainage from Norwegian Mines. In: Wolkersdorfer C, Bowell R, eds. Contemporary Reviews of Mine Water Studies in Europe. Mine Water and the Environment, 24, Supplementary Material. Springer Verlag

  • WHO (1993). Guidelines for Drinking-water Quality, 2nd ed. WHO, Geneva

    Google Scholar 

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Authors and Affiliations

  1. Department of Geography and Environmental Management, Niger Delta University, Wilberforce Island, PMB 071, Yenegoa, Nigeria

    I. C. Ezekwe, A. O. Aisubeogun & E. Odubo

  2. Department of Geography and Planning, Abia State University, PMB 2000, Uturu, Nigeria

    G. N. Chima

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  1. I. C. Ezekwe
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  2. A. O. Aisubeogun
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  3. G. N. Chima
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  4. E. Odubo
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Correspondence to I. C. Ezekwe.

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Ezekwe, I.C., Aisubeogun, A.O., Chima, G.N. et al. TDS-Eh graph analysis: a new water quality index and rural water supply implications of a river affected by mining in south-eastern Nigeria. Front. Earth Sci. 6, 66–74 (2012). https://doi.org/10.1007/s11707-011-0201-2

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