Abstract
A gliding arc discharge (GRD) reactor was used to decompose ethanol into primarily H2 and CO with small amounts of CH4, C2H2, C2H4, and C2H6. The ethanol concentration, electrode gap, input voltage and Ar flow rate all affected the conversion of ethanol with results ranging from 40.7% to 58.0%. Interestingly, for all experimental conditions the SH2/SCO selectivity ratio was quite stable at around 1.03. The mechanism for the decomposition of ethanol is also described.
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Joensen F, Jens R, Nielsen R. Conversion of hydrocarbons and alcohols for fuel cells. Journal of Power Sources, 2002, 105(2): 195–201
Navarro R, Peña M, Fierro J. Hydrogen production reactions from carbon feedstocks: fossil fuels and biomass. Chemical Reviews, 2007, 107(10): 3952–3991
Haryanto A, Fernando S, Murali N, Adhikari S. Current status of hydrogen production techniques by steam reforming of ethanol: a review. Energy & Fuels, 2005, 19(5): 2098–2106
Goltsov V, Veziroglu T, Goltsova L. Hydrogen civilization of the future—A new conception of the IAHE. International Journal of Hydrogen Energy, 2006, 31(2): 153–159
Meng N, Michael L, Sumathy K, Dennis L. Potential of renewable hydrogen production for energy supply in HongKong. International Journal of Hydrogen Energy, 2006, 31(10): 1401–1412
Meng N, Dennis L, Michael L, Sumathy K. An overview of hydrogen production from biomass. Fuel Processing Technology, 2006, 87(5): 461–472
Meng N, Dennis L, Michael L. A review on reforming bio-ethanol for hydrogen production. International Journal of Hydrogen Energy, 2007, 32(15): 3238–3247
Li J, Kazakov A, Dryer F. Experimental and numerical studies of ethanol decomposition reactions. Journal of Physical Chemistry A, 2004, 108(38): 7671–7680
Diagne C, Idriss H, Kiennemann A. Hydrogen production by ethanol reforming over Rh/CeO2-ZrO2 catalysts. Catalysis Communications, 2002, 3(12): 565–571
Toshiya N, Tomoaki M, Hiroyoshi K, Kazunori U, Yasuyuki M, Shen W, Seiichiro I. Catalytic steam reforming of ethanol to produce hydrogen and acetone. Applied Catalysis A, General, 2005, 279(1–2): 273–277
Fishtik I, Alexander A, Datta R, Geana D. A thermodynamic analysis of hydrogen production by steam reforming of ethanol via response reactions. International Journal of Hydrogen Energy, 2000, 25(1): 31–45
Fierro V, Klouz V, Akdim O, Mirodatos C. Oxidative reforming of biomass derived ethanol for hydrogen production in fuel cell applications. Catalysis Today, 2002, 75(1–4): 141–144
Cavallaro S, Chiodo V, Vita A, Freni S. Hydrogen production by auto-thermal reforming of ethanol on Rh/Al2O3 catalyst. Journal of Power Sources, 2003, 123(1): 10–16
Matsumura Y, Nakamori T. Steam reforming of methane over nickel catalysts at low reaction temperature. Applied Catalysis A, General, 2004, 258(1): 107–114
Petitpasa G, Rollier J, Darmon A, Gonzalez-Aguilar J, Metkemeijer R, Fulcheri L. A comparative study of non-thermal plasma assisted reforming technologies. International Journal of Hydrogen Energy, 2007, 32(14): 2848–2867
Aubry O, Met C, Khacef A, Cormier J. On the use of a non-thermal plasma reactor for ethanol steam reforming. Chemical Engineering Journal, 2005, 106(3): 241–247
Zheng B, Yan J, Li X, Chi Y, Cen K. Plasma assisted dry methane reforming using gliding arc gas discharge: effect of feed gases proportion. International Journal of Hydrogen Energy, 2008, 33(20): 5545–5553
Yang Y, Lee B, Chun Y. Characteristics of methane reforming using gliding arc reactor. Energy, 2009, 34(2): 172–177
Rueangjitt N, Sreethawonga T, Chavadej S, Sekiguchi H. Plasmacatalytic reforming of methane in AC microsized gliding arc discharge: effects of input power, reactor thickness, and catalyst existence. Chemical Engineering Journal, 2009, 155(3): 874–880
Burlica R, Shih K, Hnatiuc B, Locke B. Hydrogen generation by pulsed gliding arc discharge plasma with sprays of alcohol solutions. Industrial & Engineering Chemistry Research, 2011, 50(15): 9466–9470
Yanguas-Gil A, Hueso J, Cotrino J, Caballero A, González-Elipe A. Reforming of ethanol in a microwave surface-wave plasma discharge. Applied Physics Letters, 2004, 85(18): 4004–4006
Tanabe S, Matsuguma H, Okitsu K, Matsumoto H. Generation of hydrogen from methanol in a dielectric-barrier discharge-plasma system. Chemistry Letters, 2000, 29(10): 1116–1117
Wang B, Lv Y, Zhang X, Hu S. Hydrogen generation from steam reforming of ethanol in dielectric barrier discharge. Journal of Natural Gas Chemistry, 2011, 20(2): 151–154
Henriques J, Bundaleska N, Tatarova E, Dias F, Ferreira C. Microwave plasma torches driven by surface wave applied for hydrogen production. International Journal of Hydrogen Energy, 2011, 36(1): 345–354
Petitpas G, José G, Adeline D, Laurent F. Ethanol and E85 reforming assisted by a non-thermal arc discharge. Energy & Fuels, 2011, 24(4): 2607–2613
Du C, Li H, Zhang L, Wang J, Huang D, Xiao M, Cai J, Chen Y, Yan H, Xiong Y, Xiong Y. Hydrogen production by steam-oxidative reforming of bio-ethanol assisted by Laval nozzle arc discharge. International Journal of Hydrogen Energy, 2012, 37(10): 8318–8329
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Wang, B., Ge, W., Lü, Y. et al. H2 production by ethanol decomposition with a gliding arc discharge plasma reactor. Front. Chem. Sci. Eng. 7, 145–153 (2013). https://doi.org/10.1007/s11705-013-1327-4
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DOI: https://doi.org/10.1007/s11705-013-1327-4