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The Ba-Ge phase diagram in [Massalski2] was redrawn from [Moffatt].
Figure 1 shows the Ba-Ge phase diagram revised by [2008Pan] based on thermal analysis data measured for the range 0-75 at.% Ge. The Ge-rich part was adopted from [2005Car]. This phase diagram is more complex in comparison with the [Massalski2] phase diagram, which showed only four intermediate phases.
Table 1 shows Ba-Ge crystal structure data.
References
W. Carrillo-Cabrera, H. Borrmann, S. Paschen, M. Baenitz, F. Steglich, and Y. Grin, “Ba6Ge25; Low-temperature Ge-Ge Bond Breaking during Temperature-Induced Structure Transformation,” J. Solid State Chem., 2005, 178(3), p. 715-728
M. Pani and A. Palenzona, “The Phase Diagram of the Ba-Ge System,” J. Alloys Compds., 2008, 462, p. L9-L11
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Okamoto, H. Ba-Ge (Barium-Germanium). J. Phase Equilib. Diffus. 30, 114 (2009). https://doi.org/10.1007/s11669-008-9428-3
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DOI: https://doi.org/10.1007/s11669-008-9428-3