Skip to main content
Log in

Effect of 2D WS2 Addition on Cold-Sprayed Aluminum Coating

  • Peer Reviewed
  • Published:
Journal of Thermal Spray Technology Aims and scope Submit manuscript

Abstract

Tungsten disulfide (WS2) has excellent solid lubrication properties due to its 2D layered structure. This study focuses on depositing Al-2 wt.% WS2 composite coating by cold spray technique. The effect of WS2 addition on the microstructure, mechanical and tribological properties of the composite coatings is examined in the as-deposited and heat-treated conditions. After heat treatment, the coating density increased to 99% with improved intersplat bonding. The microhardness of the heat-treated Al-2 wt.% WS2 coating increased by 56% as compared to the as-sprayed coating. The wear resistance of heat-treated Al-2 wt.% WS2 coating improved by 75% with a synergistic reduction in the coefficient of friction (COF) by 51%. Transmission electron microscopy investigation reveals the presence of layered WS2 within aluminum splats with a strong interface. This study shows that cold spraying can be effectively used to integrate 2D layered WS2 as a solid lubricant in the metallic coatings.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14

Similar content being viewed by others

References

  1. A.P. Alkhimov, V.F. Kosarev, and A.N. Papyrin, A Method of Cold Gas-Dynamic Deposition, Sov. Phys. Dokl. 35(12), 1047-1049 (1990) (in Russian, Transl: American Inst. of Phys., 1991)

  2. E. Irissou, J.G. Legoux, A.N. Ryabinin, B. Jodoin, and C. Moreau, Review on Cold Spray Process and Technology: Part I—Intellectual Property, J. Therm. Spray Technol., 2008, 17(4), p 495-516

    Article  Google Scholar 

  3. H. Assadi, F. Gartner, T. Stoltenhoff, and H. Kreye, Bonding Mechanism in Cold Gas Spraying, Acta Mater., 2003, 51(15), p 4379-4394

    Article  Google Scholar 

  4. A. Papyrin, V. Kosarev, K.V. Klinkov, and V.M. Fomin, Cold Spray Technology, Elsevier Ltd., Amsterdam, 2006

    Google Scholar 

  5. A.P. Alkhimov, A.N. Papyrin, and V.F. Kosarev, Gas-Dynamic Spray Method for Applying a Coating, U.S. Patent 5, 302-414 (1994)

  6. R. Morgan, P. Fox, J. Pattison, C. Sutcliffe, and W. O’Neill, Analysis of Cold Gas Dynamically Sprayed Aluminum Deposits, Mater. Lett., 2004, 58(7-8), p 1317-1320

    Article  Google Scholar 

  7. L. Ajdelsztajn, B. Jodoin, G.E. Kim, and J.M. Schoenung, Cold Spray Deposition of Nanocrystalline Aluminum Alloys, Metall. Mater. Trans. A, 2005, 36A(3), p 657-666

    Article  Google Scholar 

  8. B. Jodoin, L. Ajdelsztajn, E. Sansoucy, A. Zuniga, P. Richer, and E.J. Lavernia, Effect of Particle Size, Morphology, and Hardness on Cold Gas Dynamic Sprayed Aluminum Alloy Coatings, Surf. Coat. Technol., 2006, 201(6), p 3422-3429

    Article  Google Scholar 

  9. X.J. Ning, J.H. Kim, H.J. Kim, and C.H. Lee, Characteristics and Heat Treatment of Cold-sprayed Al-Sn Binary Alloy Coatings, Appl. Surf. Sci., 2009, 255, p 3933-3939

    Article  Google Scholar 

  10. M. Yandouzi, P. Richer, and B. Jodoin, SiC Particulate Reinforced Al-12Si Alloy Composite Coatings Produced by the Pulsed Gas Dynamic Spray Process: Microstructure and Properties, Surf. Coat. Technol., 2009, 203(20-21), p 3260-3270

    Article  Google Scholar 

  11. J. Villafuerte and W. Zheng, Corrosion Protection of Magnesium Alloys by Cold Spray, Adv. Mater. Process., 2007, 165(9), p 53-64

    Google Scholar 

  12. H.J. Kim, C.H. Lee, and S.Y. Hwang, Superhard Nano WC-12% Co Coating by Cold Spray Deposition, Mater. Sci. Eng. A, 2005, A391, p 243-248

    Google Scholar 

  13. W.Y. Li, G. Zhang, X.P. Guo, H.L. Liao, and C. Coddet, Characterizations of Cold-Sprayed TiN Particle-Reinforced Al Alloy-Based Composites-from Structures to Tribological Behaviour, Adv. Eng. Mater., 2007, 9, p 577-583

    Article  Google Scholar 

  14. W.Y. Li, C.L. Yang, and H.L. Liao, Effect of Vacuum Heat Treatment on Microstructure and Microhardness of Cold-Sprayed TiN Particle-Reinforced Al Alloy-based Composites, Mater. Des., 2011, 32, p 388-394

    Article  Google Scholar 

  15. E. Sansoucy, P. Marcoux, L. Ajdelsztajn, and B. Jodoin, Properties of SiC-reinforced Aluminum Alloy Coatings Produced by the Cold Gas Dynamic Spraying Process, Surf. Coat. Technol., 2008, 202, p 3988-3996

    Article  Google Scholar 

  16. M. Yandouzi, A.J. Bottger, R.W.A. Hendrikx, M. Brochu, P. Richer, A. Charest, and B. Jodoin, Microstructure and Mechanical Properties of B4C Reinforced Al-Based Matrix Composite Coatings Deposited by CGDS and PGDS Processes, Surf. Coat. Technol., 2010, 205, p 2234-2246

    Article  Google Scholar 

  17. J.M. Shockley, H.W. Strauss, R.R. Chromik, N. Brodusch, R. Gauvin, E. Irissou, and J.G. Legoux, In Situ Tribometry of Cold-Sprayed Al-Al2O3 Composite Coatings, Surf. Coat. Technol., 2013, 215, p 350-356

    Article  Google Scholar 

  18. K. Spencer, D.M. Fabijanic, and M.X. Zhang, The Use of Al-Al2O3 Cold Spray Coatings to Improve the Surface Properties of Magnesium Alloys, Surf. Coat. Technol., 2009, 204, p 336-344

    Article  Google Scholar 

  19. S. Xu, X. Gao, M. Hu, J. Sun, D. Jiang, D. Wang, F. Zhou, L. Wenga, and W. Li, Dependence of Atomic Oxygen Resistance and the Tribological Properties on Microstructures of WS2 films, Appl. Surf. Sci., 2014, 298, p 36-43

    Article  Google Scholar 

  20. E. Selvi, Y. Ma, R. Aksoy, A. Ertas, and A. White, High Pressure x-ray Diffraction Study of Tungsten Disulfide, J. Phys. Chem. Solids, 2006, 67, p 2183-2186

    Article  Google Scholar 

  21. S. Prasad and J. Zabinski, Lubricants Super Slippery Solids, Nature, 1997, 387, p 761-763

    Article  Google Scholar 

  22. S.V. Prasad, N.T. McDevitt, and J.S. Zabinski, Tribology of Tungsten Disulfide Films in Humid Environments: The Role of a Tailored Metal-Matrix Composite Substrate, Wear, 1999, 230, p 24-34

    Article  Google Scholar 

  23. O.D. Greenwood, S.C. Moulzolf, P.J. Blau, and R.J. Lad, The Influence of Microstructure on Tribological Properties of WO Thin Films, Wear, 1999, 232, p 84-90

    Article  Google Scholar 

  24. K. Balani, T. Laha, A. Agarwal, J. Karthikeyan, and N. Munroe, Effect of Carrier Gases on Microstructural and Electrochemical Behavior of Cold-Sprayed 1100 Aluminum Coating, Surf. Coat. Technol., 2005, 95, p 272-279

    Article  Google Scholar 

  25. W. Wong, P. Vo, E. Irissou, A.N. Ryabinin, J.G. Legoux, and S. Yue, Effect of Particle Morphology and Size Distribution on Cold-Sprayed Pure Titanium Coatings, J. Therm. Spray Technol., 2013, 22(7), p 1140-1153

    Article  Google Scholar 

  26. P.R. Soni, Mechanical Alloying: Fundamentals and Applications, Cambridge International Science Publishing Limited, Cambridge, 2001

    Google Scholar 

  27. K. Morsi and A. Esawi, Effect of Mechanical Alloying Time and Carbon Nanotube (CNT) Content on the Evolution of Aluminum (Al)-CNT Composite Powders, J. Mater. Sci., 2007, 42, p 4954-4959

    Article  Google Scholar 

  28. S. Rengifo, M.S thesis Florida International University, 2015

  29. F. Liu, X. Chen, Q. Xia, L. Tian, and X. Chen, Ultrathin Tungsten Oxide Nanowires: Oleylamine Assisted Nonhydrolytic Growth, Oxygen Vacancies and gooD Photocatalytic Properties, RSC Adv., 2015, 5, p 77423-77428

    Article  Google Scholar 

  30. V.K. Champagne, D.J. Helfritch, M.D. Trexler, and B.M. Gabrial, The Effect of Cold Spray Impact Velocity on Deposit Hardness, Model. Simul. Mater. Sci. Eng., 2010, 18, p 1-8

    Article  Google Scholar 

  31. T. Price, Ph.D. thesis University of Nottingham, 2008

  32. W.H. Qi, M.P. Wang, and Q.H. Li, Shape Factor of Non- spherical Nanoparticles, J. Mater. Sci., 2005, 40, p 2737-2739

    Article  Google Scholar 

  33. W.Y. Li and C.J. Li, Optimization of Spray Conditions in Cold Spraying Based on the Numerical Analysis of Particle Velocity, Trans. Nonferrous Met. Soc. China, 2004, 14, p 43-48

    Google Scholar 

  34. A.C. Hall, D.J. Cook, R.A. Neiser, T.J. Roemer, and D.A. Hirschfeld, The Effect of a Simple Annealing Heat Treatment on the Mechanical Properties of Cold Sprayed Aluminum, J. Therm. Spray Technol., 2006, 15(2), p 233-238

    Article  Google Scholar 

  35. P.S. Phani, D.S. Rao, S.V. Joshi, and G. Sundararajan, Effect of Process Parameters and Heat Treatments on Properties of Cold Sprayed Copper Coatings, J. Therm. Spray Technol., 2007, 16(3), p 425-434

    Article  Google Scholar 

  36. G. Sundararajan, P.S. Phani, A. Jyothirmayi, and R.C. Gundakaram, The Influence of Heat Treatment on the Microstructural, Mechanical and Corrosion Behavior of Cold Sprayed SS 316L Coatings, J. Mater. Sci., 2009, 44, p 2320-2326

    Article  Google Scholar 

  37. J.Y. Huang, Y.T. Zhu, H. Jiang, and T.C. Lowe, Microstructures and Dislocation Configurations in Nanostructured Cu Processed by Repetitive Corrugation and Straightening, Acta Mater., 2001, 49, p 1497-1505

    Article  Google Scholar 

  38. K.H. Ko, J.O. Choi, and H. Lee, Intermixing and Interfacial Morphology of Cold-Sprayed Al Coatings on Steel, Mater. Lett., 2014, 136, p 45-47

    Article  Google Scholar 

  39. P.C. King, S.H. Zahiri, and M.H. Jahedi, Focused Ion Beam Micro-Dissection of Cold Sprayed Particles, Acta Mater., 2008, 56(19), p 5617-5626

    Article  Google Scholar 

  40. F. Gartner, C. Borchers, T. Stoltenhoff, H. Kreye, and H. Assadi, Thermal Spray, Advancing the Science and Applying the Technology, B.R. Marple and C. Moreau, Ed., ASM International, Materials Park, 2003, p 1

    Google Scholar 

  41. H.Y. Bu, M. Yandouzi, C. Lu, and B. Jodoin, Post-heat Treatment Effects on Cold-Sprayed Aluminum Coatings on AZ91D Magnesium Substrates, J. Therm. Spray Technol., 2012, 21(3–4), p 731-739

    Article  Google Scholar 

  42. R.S. Lima, Microstructural Characteristics of Cold-Sprayed Nanostructured WC-Co Coatings, Thin Solid Films, 2002, 416(1–2), p 129-135

    Article  Google Scholar 

  43. S.R. Bakshi, V. Singh, K. Balani, D.G. McCartney, S. Seal, and A. Agarwal, Carbon Nanotube Reinforced Aluminum Composite Coating Via Cold Spraying, Surf. Coat. Technol., 2008, 202, p 5162-5169

    Article  Google Scholar 

  44. P.S. Phani, V. Vishnukanthan, and G. Sundararajan, Effect of Heat Treatment on Properties of Cold Sprayed Nanocrystalline Copper Alumina Coatings, Acta Mater., 2007, 55, p 4741-4751

    Article  Google Scholar 

  45. X. Zhang, H. Xu, J. Wang, X. Ye, W. Lei, M. Xue, H. Tang, and C.S. Li, Synthesis of Ultrathin WS2 Nanosheets and Their Tribological Properties as Lubricant Additives, Nanoscale Res. Lett., 2016, 11, p 442

    Article  Google Scholar 

  46. S. Rengifo, C. Zhang, S. Harimkar, B. Boesl, and A. Agarwal, Effect of WS2 Addition on Tribological Behavior of Aluminum at Room and Elevated Temperatures, Tribol. Lett., 2017, 65, p 76

    Article  Google Scholar 

Download references

Acknowledgments

Authors thank the Advanced Materials Engineering Research Institute (AMERI) at Florida International University for the characterization facilities.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Arvind Agarwal.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 1242 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Loganathan, A., Rengifo, S., Hernandez, A.F. et al. Effect of 2D WS2 Addition on Cold-Sprayed Aluminum Coating. J Therm Spray Tech 26, 1585–1597 (2017). https://doi.org/10.1007/s11666-017-0608-8

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11666-017-0608-8

Keywords

Navigation