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Preparation of TiAl3-Al Composite Coating by Cold Spray and Its High Temperature Oxidation Behavior

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Abstract

A novel TiAl3-Al coating was prepared by cold spray for high temperature protection of titanium aluminum-based alloy. The substrate alloy was orthorhombic-Ti-22Al-26Nb (at.%). The composite coating was mainly composed of TiAl3 embedded in the matrix of residual aluminum. An interlayer about 10 μm was formed between the coating and the substrate. The oxidation test indicated that this composite coating was very effective in improving the high-temperature oxidation resistance of the substrate alloy at 950 °C in the tested 150 cycles without any sign of degradation. The microstructure analysis of the oxidized composite coating showed that an Al2O3 scale with a complex structure can be formed outside the interlayer during oxidation and no oxides beneath the interlayer were detected, which indicated that the complex continuous Al2O3 and the interlayer provide the protection of the substrate at high-temperature oxidation condition.

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References

  1. V.K. Champagne, The Cold Spray Materials Deposition Process, WP, Cambridge, England, 2007, p 1-7

  2. A. Papyrin, Cold Spray Technology, Adv. Mater. Proc., 2001, 160(3), p 49-51

    Google Scholar 

  3. T. Stoltenhoff, H. Kreye, and H. Richter, An Analysis of the Cold Spray Process and Its Coatings, J. Therm. Spray Technol., 2002, 11(4), p 542-550

    Article  CAS  ADS  Google Scholar 

  4. M.F. Smith, Comparing Cold Spray with Thermal Spray Coating Technologies, The Cold Spray Materials Deposition Process 2007, V.K. Champagne, Ed., WP, Cambridge, England, 2007, p 43-61

  5. A. Papyrin, Cold Spray Technology, Elsevier Science, Albuquerque, NM, 2006

  6. T.H.V. Steenkiste, J.R. Smith, and R.E. Teets, Aluminum Coatings Via Kinetic Spray with Relatively Large Powder Particles, Surf. Coat. Technol., 2002, 154, p 237-252

    Article  Google Scholar 

  7. C.J. Li and W.Y. Li, Deposition Characteristics of Titanium Coating in Cold Spraying, Surf. Coat. Technol., 2003, 167, p 278-283

    Article  CAS  ADS  Google Scholar 

  8. R.C. Mccune, A.N. Papyrin, J.N. Hall, W.L. Riggs, and P.H. Zajchowski, An Exploration of the Cold Gas-Dynamic Spray Method for Several Metals Materials Systems, Thermal Spray Science and Technology, C.C. Berndt and S. Sampath, Ed., ASM International, 1995, p 1-5

  9. D.E. Wolfe, T.J. Eden, J.K. Potter, and A.P. Jaroh, Investigation and Characterization of Cr3C2-Based Wear-Resistant Coatings Applied by the Cold Spray Process, J. Therm. Spray Technol., 2006, 15(3), p 400-412

    Article  CAS  ADS  Google Scholar 

  10. Y.S. Tao, T.Y. Xiong, C. Sun, H.Z. Jin, H. Du, T.F. Li. Effect of α-Al2O3 on the Properties of Cold Sprayed Al/α-Al2O3 Composite Coatings on AZ91D Magnesium Alloy, Appl. Surf. Sci., 2009, 256, p 261-266

    Google Scholar 

  11. D.J. Helfritch, Electromagnetic Interference Shielding by Cold Spray Particle Deposition, The Cold Spray Materials Deposition Process 2007, V.K. Champagne, Ed., WP, Cambridge, England, 2007, p 316-326

  12. L. Shen, L.Y. Kong, T.Y. Xiong, H. Du, and T.F. Li, Preparation of TiAl3-Al Composite Coating by Cold Spraying, Trans. Nonferrous Met. Soc. China, 2009, 19, p 879-882

    Article  CAS  Google Scholar 

  13. T. Novoselova, S. Celotto, R. Morgan, P. Fox, and W. O’Neill, Formation of TiAl Intermetallics by Heat Treatment of Cold-Sprayed Precursor Deposits, J. Alloy. Comp., 2007, 436(1-2), p 69-77

    Article  CAS  Google Scholar 

  14. S. Deshpande, A. Kulkarni, S. Sampath, and H. Herman, Application of Image Analysis for Characterization of Porosity in Scattering, Surf. Coat. Technol., 2004, 187(6), p 6-16

    Article  CAS  Google Scholar 

  15. E.K.Y. Fu, R.D. Rawlings, and H.B. Mcshane, Reaction Synthesis of Titanium Aluminides, J. Mater. Sci., 2001, 36, p 5537-5542

    Article  CAS  Google Scholar 

  16. J.L. Smialek and D.L. Humphrey, Oxidation Kinetics of Cast TiAl3, Scripta Metall. Mater., 1993, 26, p 1763-1768

    Article  Google Scholar 

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Acknowledgment

The financial support of National Natural Science Foundation of China (No. 50971127) is gratefully acknowledged.

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Correspondence to T. Y. Xiong.

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Kong, L.Y., Shen, L., Lu, B. et al. Preparation of TiAl3-Al Composite Coating by Cold Spray and Its High Temperature Oxidation Behavior. J Therm Spray Tech 19, 1206–1210 (2010). https://doi.org/10.1007/s11666-010-9516-x

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  • DOI: https://doi.org/10.1007/s11666-010-9516-x

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