Abstract
The production of magnesium alloys by the powder metallurgy (P/M) method is difficult and troublesome. An alternative production method with easy usability is therefore required, and the properties of new Mg alloys should be examined after production. A type of P/M method (the hot press method) can be applied to produce new Mg alloys with superior properties. In this study, the effect of Al addition and the use of the hot press method on the microstructure and mechanical properties of magnesium alloy were investigated. TZA series magnesium alloys (Mg5Sn4Zn-xAl) were developed, and these alloys were produced in this way for the first time. The paraffin coating technique was applied to prevent the risk of ignition or oxidation of the Mg powders during the mixing process. The experimental results showed that new non-porous Mg alloys with a relative density above 99% were successfully produced using the hot press method. Intermetallic phases were homogeneously distributed at the grain boundaries due to the use of the hot press process. The amount of Mg17Al12 phase in the microstructure increased with the addition of more Al, and this improved the mechanical properties. TZA544 magnesium alloy exhibits mechanical properties that are superior to those of many magnesium alloys in current use.
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References
Y. Nishikawa and A. Takara, Current Status and Manufacturing Technologies of Magnesium Alloy Parts in Japanese Home Electronics, Mater. Sci. Forum, 2003, 426, p 569–574. https://doi.org/10.4028/www.scientific.net/MSF.426-432.569
Q. Zhu, A. Rassili, SP. Midson, and XG. Hu, The Status of Magnesium Injection Molding in China, Sol. St. Phen., 2019, 285, p 436–440.https://doi.org/10.4028/www.scientific.net/SSP.285.436
U. Koklu and H. Coban, Effect of Dipped Cryogenic Approach on Thrust Force, Temperature, Tool Wear and Chip Formation in Drilling of AZ31 Magnesium Alloy, J. Mater. Res. Technol., 2020, 9, p 2870–2880. https://doi.org/10.1016/j.jmrt.2020.01.038
J. Wang, S. Gao, P. Song, X. Huang, Z. Shi, and F. Pan, Effects of Phase Composition on the Mechanical Properties and Damping Capacities of As-Extruded Mg-Zn-Y-Zr Alloys, J. Alloys Compd., 2011, 509, p 8567–8572. https://doi.org/10.1016/j.jallcom.2011.06.017
D.Q. Wan, H.B. Wang, S.T. Ye, Y.L. Hu, and J.J. Hu, High Damping and Good Mechanical Properties Combined in As-Cast Mg-0.6%Zr-Zn Tenary Alloys, Int. J. Cast. Metal. Res., 2019, 32, p 262–265. https://doi.org/10.1080/13640461.2019.1690416
G. Prakash, N.K. Singh, D. Kumar, and P. Chandel, Dynamic Tensile Behaviour of Magnesium Alloy AZ41 at Different Strain Rates and Temperatures, UPB Sci. Bull. Ser. D, 2020, 82, p 177–186.
S.Y. Betsofen, O.E. Osintsev, I.A. Grushin, A.A. Petrov, and K.A. Speranskii, Influence of Alloying Elements on the Deformation Mechanism and the Texture of Magnesium Alloys, Russ. Metall., 2019, 2019, p 346–360. https://doi.org/10.1134/S0036029519040049
D.F. Zhang, H.J. Hu, F.S. Pan, M.B. Yang, and J.P. Zhang, Numerical and Physical Simulation of New SPD Method Combining Extrusion and Equal Channel Angular Pressing for AZ31 Magnesium Alloy, T. Nonferr. Metal. Soc., 2010, 20, p 478–483. https://doi.org/10.1016/S1003-6326(09)60165-5
R.Z. Wu, Z.K. Qu, and M.L. Zhang, Reviews on the Influences of Alloying Elements on the Microstructure and Mechanical Properties of Mg-Li Base Alloys, Rev. Adv. Mater. Sci., 2010, 24, p 35–43.
Y. Chen, L. Jin, Y. Song, H. Liu, and R. Ye, Effect of Zn on Microstructure and Mechanical Property of Mg-3Sn-1Al Alloys, Mater. Sci. Eng. A, 2014, 612, p 96–101. https://doi.org/10.1016/j.msea.2014.06.022
E. Willbold, X. Gu, D. Albert, K. Kalla, K. Bobe, M. Brauneis, C. Janning, J. Nellesen, W. Czayka, W. Tillmann, Y. Zheng, and F. Witte, Effect of the Addition of Low Rare Earth Elements (Lanthanum, Neodymium, Cerium) on the Biodegradation and Biocompatibility of Magnesium, Acta Biomater., 2015, 11, p 554–562. https://doi.org/10.1016/j.actbio.2014.09.041
Y. Huang, H. Dieringa, N. Hort, T.A. Leil, K.U. Kainer, and Y. Liu, Effects of Segregation of Primary Alloying Elements on the Creep Response in Magnesium Alloys, Scripta Mater., 2008, 58, p 894–897. https://doi.org/10.1016/j.scriptamat.2008.01.011
Y. Turen, H. Zengin, Y. Sun, H. Ahlatci, and M. Unal, Effects of 1wt.% Ti, In, and Sn Additions on the Microstructure, Mechanical and Corrosion Properties of the As-Cast and Hot-Rolled AM60 Magnesium Alloys, Met. Sci. Heat. Treat., 2019, 61, p 318–324. https://doi.org/10.1007/s11041-019-00423-0
A. Viswanath, H. Dieringa, K.A. Kumar, U.T.S. Pillai, and B.C. Pai, Investigation on Mechanical Properties and Creep Behavior of Stir Cast AZ91-SiCp Composites, J. Magnes. Alloy, 2015, 3, p 16–22. https://doi.org/10.1016/j.jma.2015.01.001
H. Liu, Y. Chen, Y. Tang, S. Wei, and G. Niu, The Microstructure, Tensile Properties, and Creep Behavior of As-Cast Mg–(1–10) % Sn Alloys, J. Alloys Compd., 2007, 440, p 122–126. https://doi.org/10.1016/j.jallcom.2006.09.024
M. Razzaghi, H. Mirzadeh, and M. Emamy, Unraveling the Effects of Zn Addition and Hot Extrusion Process on the Microstructure and Mechanical Properties of As-Cast Mg-2Al Magnesium Alloy, Vacuum, 2019, 167, p 214–222. https://doi.org/10.1016/j.vacuum.2019.06.013
N. Mahallawy, A.A. Diaa, M. Akdesir, and H. Palkowski, Microstructure and Mechanical Properties of Mg-6Sn And Mg-6Zn Alloys Prepared by Different Processing Techniques: A Comparative Study, Mater. Sci. Eng. Technol., 2016, 47, p 1–63. https://doi.org/10.1002/mawe.201500468
V.V. Ramalingam, P. Ramasamy, M.D. Kovukkal, and G. Myilsamy, Research and Development in Magnesium Alloys for Industrial and Biomedical Applications: A Review, Met. Mater. Int., 2020, 26, p 409–430. https://doi.org/10.1007/s12540-019-00346-8
A. Ercetin, Ö. Özgün, K. Aslantas, and G. Aykutoğlu, The Microstructure, degradation behavior and cytotoxicity effect of Mg-Sn-Zn alloys in vitro tests, SN Appl. Sci., 2020, 2, p 173. https://doi.org/10.1007/s42452-020-1988-9
F. Qi, D. Zhang, X. Zhang, and X. Xu, Effect of Sn Addition on the Microstructure and Mechanical Properties of Mg-6Zn-1Mn (wt.%) Alloy, J. Alloys Compd., 2014, 585, p 656–666. https://doi.org/10.1016/j.jallcom.2013.09.156
L.L. Chang, H. Tang, and J. Guo, Strengthening Effect of Nano and Micro-Sized Precipitates in the Hot-Extruded Mg-5Sn-3Zn Alloys with Ca Addition, J. Alloys Compd., 2017, 703, p 552–559. https://doi.org/10.1016/j.jallcom.2017.01.274
M.E. Turan, Y. Sun, Y. Akgul, Y. Turen, and H. Ahlatci, The Effect of GNPs on Wear and Corrosion Behaviors of Pure Magnesium, J. Alloys Compd., 2017, 724, p 14–23. https://doi.org/10.1016/j.jallcom.2017.07.022
P. Emadi and C. Ravindran, The Influence of High Temperature Ultrasonic Processing Time on the Microstructure and Mechanical Properties AZ91E Magnesium Alloy, J. Mater. Eng. Perform., 2021, 30, p 1188–1199.
Y. Fu, Y. Li, A. Hu, H. Hu, and X. Nie, Microstructure, Tensile Properties and Fracture Behavior of Squeeze-Cast Mg Alloy AZ91 with Thick Cross Section, J. Mater. Eng. Perform., 2020, 29, p 4130–4141. https://doi.org/10.1007/s11665-020-04910-x
H. Zengin, Y. Turen, and L. Elen, A Comparative Study on Microstructure, Mechanical and Tribological Properties of A4, AE41, AS41 and AJ41 Magnesium Alloy, J. Mater. Eng. Perform., 2019, 28, p 4647–4657. https://doi.org/10.1007/s11665-019-04223-8
L. Guo, R. Fu, J. Pei, J. Wang, H. Zhao, B. Song, and Z. Chen, Microstructure, Texture, and Mechanical Properties of Continuously Extruded and Rolled AZ31 Magnesium Alloy Sheet, J. Mater. Eng. Perform., 2019, 28, p 6692–6703. https://doi.org/10.1007/s11665-019-04394-4
Ö. Özgün, K. Aslantaş, and A. Erçetin, Powder Metallurgy Mg-Sn alloys: Production and Characterization, Sci. Iran, 2020, 27, p 1255–1265. https://doi.org/10.24200/sci.2019.50212.1578
G. Nayyeri and R. Mahmudi, Enhanced Creep Properties of a Cast Mg-5Sn Alloy Subjected to Aging-Treatment, Mater. Sci. Eng. A, 2010, 527, p 4613–4618. https://doi.org/10.1016/j.msea.2010.04.015
M. Wahba and S. Katayama, Laser Welding of AZ31B Magnesium Alloy to Zn-Coated Steel, Mater. Des., 2012, 35, p 701–706. https://doi.org/10.1016/j.matdes.2011.10.031
M.E. Turan, H. Zengin, and Y. Sun, Dry Sliding Wear Behavior of (MWCNT+Gnps) Reinforced AZ91 Magnesium Matrix Hybrid Composites, Met. Mater. Int., 2020, 26, p 541–550. https://doi.org/10.1007/s12540-019-00338-8
H. Zengin, Y. Turen, H. Ahlatci, and Y. Sun, Microstructure, Mechanical Properties and Corrosion Resistance of As-Cast and As-Extruded Mg-4Zn-1La Magnesium Alloy, Rare Met., 2020, 39, p 909–917. https://doi.org/10.1007/s12598-018-1045-7
C. Jihua, C. Zhenhua, Y. Hongge, and F. Zhang, Microstructural Characterization and Mechanical Properties of a Mg-6Zn-3Sn-2Al Alloy, J. Alloys Compd., 2009, 467, p L1–L7. https://doi.org/10.1016/j.jallcom.2007.11.118
Y. Galindez, E. Correa, A.A. Zuleta, A. Valencia-Escobar, D. Calderon, L. Toro, P. Chacon, and F. Echeverria, Improved Mg–Al–Zn Magnesium Alloys Produced by High Energy Milling and Hot Sintering, Met. Mater. Int., 2019 https://doi.org/10.1007/s12540-019-00490-1
D. Gu, J. Peng, J. Wang, and F. Pan, Effect of Mn Modification on Microstructure and Mechanical Properties of Magnesium Alloy with Low Gd Content, Met. Mater. Int., 2020 https://doi.org/10.1007/s12540-019-00588-6
A. Ercetin, Ö. Özgün, and K. Aslantas, Investigation of Mechanical Properties of Mg5Sn-xZn Alloys Produced Through New Method in Powder Metallurgy, J. Test. Eval., 2020 https://doi.org/10.1520/JTE20200020
M. Sun, M. Liu, B. Zhang, Z. Chen, and H. Jiang, Microstructures and Mechanical Propeties of As-Extruded AZ31-xSm Magnesium Alloy, J. Mater. Eng. Perform., 2020, 29, p 5273–5281. https://doi.org/10.1007/s11665-020-05047-7
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The author would like to thank Bingol University, Central Research Laboratory of Bingol University, and Afyon Kocatepe University of Turkey.
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Ercetin, A. Application of the Hot Press Method to Produce New Mg Alloys: Characterization, Mechanical Properties, and Effect of Al Addition. J. of Materi Eng and Perform 30, 4254–4262 (2021). https://doi.org/10.1007/s11665-021-05814-0
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DOI: https://doi.org/10.1007/s11665-021-05814-0