Abstract
The effects of tungsten addition on the microstructure and mechanical properties of near-eutectic AlCoCrFeNi2 high-entropy alloy were investigated in this paper. The AlCoCrFeNi2W x alloys comprised the primary BCC phase plus eutectic FCC/BCC phases. It was found that W element can both promote the formation of the primary BCC phase and act as a solid solution strengthening element. The hardness of the AlCoCrFeNi2W x alloys increased from HV 293 to HV 356.2 with the increase in W content. The addition of W element improved the strength of alloys but reduced ductility. Thereinto, the AlCoCrFeNi2W0.2 alloy showed the most excellent compressive properties with the fracture strength of 2785.9 MPa and the plastic strain of 0.42, respectively, which implied the potential industrial application values.
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J.W. Yeh, S.K. Chen, S.J. Lin, J.Y. Gan, T.S. Chin, T.T. Shun, C.H. Tsau, and S.Y. Chang, Nanostructured High-Entropy Alloys with Multi-Principal Elements: Novel Alloy Design Concepts and Outcomes, Adv. Eng. Mater., 2004, 6(5), p 299–303
B. Cantor, I.T.H. Chang, P. Knight, and A.J.B. Vincent, Microstructural Development in Equiatomic Multicomponent Alloys, Mater. Sci. Eng. A., 2004, 375–377, p 213–218
Y.P. Lu, Y. Dong, S. Guo, L. Jiang, H.J. Kang, T.M. Wang, B. Wen, Z.J. Wang, J.C. Jie, Z.Q. Cao, H.H. Ruan, and T.J. Li, A Promising New Class of High-Temperature Alloys: Eutectic High-Entropy Alloys, Sci. Rep., 2014, 4, p 6200
B. Gludovatz, A. Hohenwarter, D. Catoor, E.H. Chang, E.P. George, and R.O. Ritchie, A Fracture-Resistent High-Entropy Alloy for Cryogenic Applications, Science, 2014, 345, p 1153–1158
M.H. Chuang, M.H. Tsai, W.R. Wang, S.J. Lin, and J.W. Yeh, Microstructure and Wear Behavior of Al x Co1.5CrFeNi1.5Ti y High-Entropy Alloys, Acta. Mater., 2011, 59, p 6308–6317
M.A. Hemphill, T. Yuan, G.Y. Wang, J.W. Yeh, C.W. Tsai, A. Chuang, and P.K. Liaw, Fatigue Behavior of Al0.5CoCrCuFeNi High Entropy Alloys, Acta. Mater., 2012, 60, p 5723–5734
P. Kozelj, S. Vrtnik, A. Jelen, S. Jazbec, Z. Jaglicic, S. Maiti, M. Feuerbacher, W. Steurer, and J. Dolinsek, Discovery of a Superconducting High-Entropy Alloy, Phys. Rev. Lett., 2014, 113, p 107001
Y. Zhang, T.T. Zuo, Y.Q. Cheng, and P.K. Liaw, High-Entropy Alloys with High Saturation Magnetization, Electrical Resistivity, and Malleability, Sci. Rep., 2013, 3, p 1455
X.D. Xu, P. Liu, S. Guo, A. Hirata, T. Fujita, T.G. Nieh, C.T. Liu, and M.W. Chen, Nanoscale Phase Separation in a FCC-Based CoCrCuFeNiAl0.5 High-Entropy Alloy, Acta. Mater., 2015, 84, p 145–152
M.H. Tsai, K.Y. Tsai, C.W. Tsai, C. Lee, C.C. Juan, and J.W. Yeh, Criterion for Sigma Phase Formation in Cr- and V-Containing High-Entropy Alloys, Mater. Res. Lett., 2013, 1(4), p 207–212
A. Takeuchi, K. Amiya, T. Wada, K. Yubuta, and W. Zhang, High-Entropy Alloys with a Hexagonal Close-Packed Structure Designed by Equi-Atomic Alloy Strategy and Binary Phase, JOM, 2014, 66(10), p 1984–1992
A. Takeuchi, N. Chen, T. Wada, Y. YoKoyama, H. Kato, A. Inoue, and J.W. Yeh, Pd20Pt20Cu20Ni20P20 High-Entropy Alloy as a Bulk Metallic Glass in the Centimeter, Intermetallics, 2011, 19, p 1546–1554
Y.P. Wang, Ph.D. Thesis (School of Materials Science and Engineering, HIT, China, 2009)
Y. Dong, Y.P. Lu, J.R. Kong, J.J. Zhang, and T.J. Li, Microstructure and Mechanical Properties of Multi-Component AlCrFeNiMo x High-Entropy Alloy, J. Alloys Compd., 2013, 573, p 96–101
S. Guo, N. Chun, and C.T. Liu, Sunflower-Like Solidification Microstructure in a Near-Eutectic High-Entropy Alloy, Mater. Res. Lett., 2013, 1(4), p 228–232
S. Guo, N. Chun, and C.T. Liu, Anomalous Solidification Microstructure in Co-Free Al x CrCuFeNi2 High-Entropy Alloys, J. Alloys Compd., 2013, 557, p 77–81
L. Jiang, Y.P. Lu, Y. Dong, T.M. Wang, Z.Q. Cao, and T.J. Li, Effects of Nb Addition on Structural Evolution and Properties of the CoFeNi2V0.5 High-Entropy Alloy, Appl. Phys. A, 2015, 119, p 291–297
S.G. Ma and Y. Zhang, Effect of Nb Addition on the Microstructure and Properties of AlCoCrFeNi High-Entropy Alloy, Mater. Sci. Eng. A, 2012, 532, p 480–486
X.F. Wang, Y. Zhang, Y. Qiao, and G.L. Chen, Novel Microstructure and Properties of Multicomponent CoCrCuFeNiTi x Alloys, Intermetallics, 2007, 15, p 357–362
A.M. Li, D. Ma, and Q.F. Zheng, Effect of Cr on Microstructure and Properties of a Series of AlTiCr x FeCoNiCu High-Entropy Alloys, J. Mater. Eng. Perform., 2014, 23(4), p 1197–1203
C.Y. Hsu, W.R. Wang, W.Y. Tang, S.K. Chen, and J.W. Yeh, Microstructure and Mechanical Properties of New AlCo x CrFeMo0.5Ni High-Entropy Alloys, Adv. Eng. Mater., 2010, 12(1–2), p 44–49
J.T. Guo, Materials Science and Engineering for Superalloys. www.sciencep.com. 2008, p 95–96
W.R. Wang, W.L. Wang, and J.W. Yeh, Phases, Microstructure and Mechanical Properties of Al x CoCrFeNi High-Entropy Alloys at Elevated Temperatures, J. Alloys Compd., 2014, 589, p 143–152
J.Y. He, W.H. Liu, H. Wang, Y. Wu, X.J. Liu, T.G. Nieh, and Z.P. Lu, Effects of Addition on Structural Evolution and Tensile Properties of the FeCoNiCrMn High-Entropy Alloy System, Acta. Mater., 2014, 62, p 105–113
Y. Dong, K.Y. Zhou, Y.P. Lu, X.X. Gao, T.M. Wang, and T.J. Li, Effect of Vanadium Addition on the Microstructure and Properties of AlCoCrFeNi High Entropy Alloy, Mater. Des., 2014, 57, p 67–72
Y.P. Lu, Y. Dong, L. Jiang, T.M. Wang, T.J. Li, and Y. Zhang, A Criterion for Topological Close-Packed Phase Formation in High Entropy Alloys, Entropy, 2015, 17, p 2355–2366
Y. Zhang, Y.J. Zhou, J.P. Lin, G.L. Chen, and P.K. Liaw, Solid-Solution Phase Formation Rules for Multi-Component Alloys, Adv. Eng. Mater., 2008, 10(6), p 534–538
X. Yang and Y. Zhang, Prediction of High-Entropy Stabilized Solid-Solution in Multi-Component Alloys, Mater. Chem. Phys., 2012, 132, p 233–238
S. Guo, N. Chun, J. Lu, and C.T. Liu, Effect of Valence Electron Concentration on Stability of FCC or BCC Phase in High Entropy Alloys, J. Appl. Phys., 2011, 109, p 103505
M.G. Poletti and L. Battezzati, Electro and Thermodynamic Criteria for the Occurrence of High Entropy Alloys in Metallic Systems, Acta. Mater., 2014, 75, p 297–306
A.K. Singh, N. Kumar, A. Dwivedi, and A. Subramaniam, A Geometrical Parameter for the Formation of Disordered Solid Solutions in Multi-Component Alloys, Intermetallics, 2014, 53, p 112–119
Z.J. Wang, Y.H. Huang, Y. Yang, J.C. Wang, and C.T. Liu, Atomic-Size Effect and Solid Solubility of Multicomponent Alloys, Scripta. Mater., 2015, 94, p 28–31
Y. Dong, Y.P. Lu, L. Jiang, T.M. Wang, and T.J. Li, Effects of Electro-Negativity on the Stability of Topologically Close-Packed Phase in High Entropy Alloys, Intermetallics, 2014, 52, p 105–109
A. Takeuchi and A. Inoue, Quantitative Evaluation of Critical Cooling Rate for Metallic Glasses, Mater. Sci. Eng. A, 2001, 304–306, p 446–451
X. Yang, Y. Zhang, and P.K. Liaw, Microstructure and Compressive Properties of NbTiVTaAl x High Entropy Alloys, Procedia Eng., 2012, 36, p 292–298
Q.C. Fan, B.S. Li, and Y. Zhang, Influence of Al and Cu Elements on the Microstructure and Properties of (FeCrNiCo)Al x Cu y High-Entropy Alloys, J. Alloys Compd., 2014, 614, p 203–210
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This research was supported by the National Natural Science Foundation of China (Grant No. 51671044) and “one-hundred young talents” projects of Guangdong University of Technology (No. 220413575).
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Dong, Y., Lu, Y. Effects of Tungsten Addition on the Microstructure and Mechanical Properties of Near-Eutectic AlCoCrFeNi2 High-Entropy Alloy. J. of Materi Eng and Perform 27, 109–115 (2018). https://doi.org/10.1007/s11665-017-3096-6
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DOI: https://doi.org/10.1007/s11665-017-3096-6