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Electropolishing of Re-melted SLM Stainless Steel 316L Parts Using Deep Eutectic Solvents: 3 × 3 Full Factorial Design

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Abstract

This three-level three-factor full factorial study describes the effects of electropolishing using deep eutectic solvents on the surface roughness of re-melted 316L stainless steel samples produced by the selective laser melting (SLM) powder bed fusion additive manufacturing method. An improvement in the surface finish of re-melted stainless steel 316L parts was achieved by optimizing the processing parameters for a relatively environmentally friendly (‘green’) electropolishing process using a Choline Chloride ionic electrolyte. The results show that further improvement of the response value-average surface roughness (Ra) can be obtained by electropolishing after re-melting to yield a 75% improvement compared to the as-built Ra. The best Ra value was less than 0.5 μm, obtained with a potential of 4 V, maintained for 30 min at 40 °C. Electropolishing has been shown to be effective at removing the residual oxide film formed during the re-melting process. The material dissolution during the process is not homogenous and is directed preferentially toward the iron and nickel, leaving the surface rich in chromium with potentially enhanced properties. The re-melted and polished surface of the samples gave an approximately 20% improvement in fatigue life at low stresses (approximately 570 MPa). The results of the study demonstrate that a combination of re-melting and electropolishing provides a flexible method for surface texture improvement which is capable of delivering a significant improvement in surface finish while holding the dimensional accuracy of parts within an acceptable range.

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References

  1. R. Sautebin, H. Froidevaux, and D. Landolt, Theoretical and Experimental Modeling of Surface Leveling in ECM Under Primary Current Distribution Conditions, J. Electrochem. Soc., 1980, 27(5), p 1096–1100

    Article  Google Scholar 

  2. C. Clerc, M. Datta, and D. Landolt, On the Theory of Anodic Levelling: Model Experiments with Triangular Nickel Profiles in Chloride Solution, Electrochim. Acta, 1984, 29(10), p 1477–1486

    Article  Google Scholar 

  3. D. Landolt, Fundamental Aspects of Electropolishing, Electrochim. Acta Electrochim. Acta, 1987, 32(1), p 1–11

    Article  Google Scholar 

  4. M. Datta and D. Landolt, Surface Brightening During High Rate Nickel Dissolution in Nitrate Electrolytes, J. Electrochem. Soc., 1975, 122(11), p 1466–1472

    Article  Google Scholar 

  5. M. Datta and D. Landolt, On the Role of Mass Transport in High Rate Dissolution of Iron and Nickel in ECM Electrolytes—I. Chloride Solutions, Electrochim. Acta, 1980, 25(10), p 1255–1262

    Article  Google Scholar 

  6. A.P. Abbott, I. Dalrymple, F. Endres, D.R. Macfarlane, “Why use Ionic Liquids for Electrodeposition?,” vol. 01, 2008

  7. A.C. Fisher, Electrode Dynamics, Oxford University Press, Oxford, 1996

    Google Scholar 

  8. P.H. Rieger, Electrochemistry, 2nd ed., Chapman & Hall, New York, 1994

    Book  Google Scholar 

  9. D. Pletcher, A First Course in Electrode Processes: Texte imprimé, Electrochem. Consul., Hants, 1991

    Google Scholar 

  10. P.T. Kissinger and W.R. Heineman, Laboratory Techniques in Electroanalytical Chemistry, Marcel Dekker Inc., New York, 1996

    Google Scholar 

  11. H. Jacquet, Figous P, and A, “in French Patent, F. patent, Editor,” 1930

  12. T. Welton, Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis, Chem. Rev., 1999, 99(8), p 2071–2083

    Article  Google Scholar 

  13. A.P. Abbott, G. Capper, K.J. McKenzie, and K.S. Ryder, Voltammetric and Impedance Studies of the Electropolishing of type 316 Stainless Steel in a Choline Chloride Based Ionic Liquid, Electrochim. Acta, 2006, 51(21), p 4420–4425

    Article  Google Scholar 

  14. A.P. Abbott, G. Capper, K.J. McKenzie, A. Glidle, and K.S. Ryder, Electropolishing of Stainless Steels in a Choline Chloride Based Ionic Liquid: An Electrochemical Study with Surface Characterisation Using SEM and Atomic Force Microscopy, Phys. Chem. Chem. Phys., 2006, 8(36), p 4214–4221

    Article  Google Scholar 

  15. J.A. Whitehead, G.A. Lawrance, and A. McCluskey, Green? Leaching: Recyclable and Selective Leaching of Gold-Bearing Ore in an Ionic Liquid, Green Chem., 2004, 6(7), p 313

    Article  Google Scholar 

  16. S. Zhang and Z. Conrad, Novel properties of ionic liquids in selective sulfur removal from fuels at room temperature, Green Chem., 2002, 4, p 376–379

    Article  Google Scholar 

  17. A.P. Abbott, D. Boothby, G. Capper, D.L. Davies, and R. Rasheed, Deep Eutectic Solvents Formed Between Choline Chloride and Carboxylic Acids, J. Am. Chem. Soc. , 2004, 126, p 9142

    Article  Google Scholar 

  18. Q.H. Zhang, K.D. Vigier, S. Royer, and F. Jerome, Deep Eutectic Solvents; Syntheses, Properties and Applications, Chem. Soc. Rev., 2012, 41, p 7108–7146

    Article  Google Scholar 

  19. A.P. Abbott, G. Capper, D.L. Davies, R. Rasheed, and V. Tambyrajah, Novel Solvent Properties of Choline Chloride/Urea Mixtures, Chem. Commun., 2003, 1, p 70

    Article  Google Scholar 

  20. A.P. Abbott and K.J. McKenzie, “Physical Chemistry Chemical Physics,” vol. 8, 2006, p. 4265–4279

  21. S. Mohan, D. Kanagaraj, R. Sindhuja, S. Vijayalakshmi, and N. Renganathan, Electropolishing of Stainless Steel—A Review, Inst. Met. Finish., 2001, 79, p 140–142

    Google Scholar 

  22. M. Freemantle, “An Introduction to Ionic Liquids,” RSC Publishing, Cambridge, 2010

    Google Scholar 

  23. A.P. Abbott, J.C. Barron, M. Elhadi, G. Frisch, S.J. Gurman, A.R. Hillman, E.L. Smith, M.A. Mohamoud and K.S. Ryder, Electrolytic metal coatings and metal finishing using ionic liquids, ECS Trans., 2009, 16, p 47–63

    Article  Google Scholar 

  24. A. Abbott, K. Ryder, and U. Konig, Electrofinishing of Metals Using Eutectic Based Ionic Liquids, Inst. Met. Finish., 2008, 86, p 196–204

    Article  Google Scholar 

  25. K. Alrbaey, D. Wimpenny, R. Tosi, W. Manning, and A. Moroz, On Optimization of Surface Roughness of Selective Laser Melting Stainless Steel Parts: A Statistical Study, J. Mat. Eng. Perform., 2014, 23(6), p 2139–2148

    Article  Google Scholar 

  26. A.P. Abbott, N. Dsouza, P. Withey, and K.S. Ryder, Electrolytic Processing of Superalloy Aerospace Castings Using Choline-Based Ionic Liquids, Trans. Inst. Met. Finish., 2012, 90(1), p 9–14

    Article  Google Scholar 

  27. E.-S. Lee, Machining Characteristics of the Electropolishing of Stainless Steel (STS316L), Int. J. Adv. Manuf. Technol., 2000, 16(8), p 591–599

    Article  Google Scholar 

  28. G.R. Kamat, Pitting and Its Control During Electropolishing of Stainless Steel, Trans. Indian Inst. Met., 1987, 40(4), p 343–345

    Google Scholar 

  29. C.-C. Shih, C.-M. Shih, Y.-Y. Su, L.H.J. Su, M.-S. Chang, and S.-J. Lin, Effect of Surface Oxide Properties on Corrosion Resistance of 316L Stainless Steel for Biomedical Applications, Corros. Sci., 2004, 46(2), p 427–441

    Article  Google Scholar 

  30. D. Landolt, P. Chauvy, and O. Zinger, Electrochemical Micromachining, Polishing and Surface Structuring of Metals: Fundamental Aspects and New Developments, Electrochim. Acta, 2003, 48(20–22), p 3185–3201

    Article  Google Scholar 

Download references

Acknowledgment

The authors acknowledge Dr. Melanie Petch for linguistic support and the anonymous reviewers for their valuable comments.

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Correspondence to A. Moroz.

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Alrbaey, K., Wimpenny, D.I., Al-Barzinjy, A.A. et al. Electropolishing of Re-melted SLM Stainless Steel 316L Parts Using Deep Eutectic Solvents: 3 × 3 Full Factorial Design. J. of Materi Eng and Perform 25, 2836–2846 (2016). https://doi.org/10.1007/s11665-016-2140-2

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  • DOI: https://doi.org/10.1007/s11665-016-2140-2

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