Skip to main content
Log in

Laser Cladding of Composite Bioceramic Coatings on Titanium Alloy

  • Published:
Journal of Materials Engineering and Performance Aims and scope Submit manuscript

Abstract

In this study, silicon nitride (Si3N4) and calcium phosphate tribasic (TCP) composite bioceramic coatings were fabricated on a Ti6Al4V (TC4) alloy using Nd:YAG pulsed laser, CO2 CW laser, and Semiconductor CW laser. The surface morphology, cross-sectional microstructure, mechanical properties, and biological behavior were carefully investigated. These investigations were conducted employing scanning electron microscope, energy-dispersive x-ray spectroscopy, and other methodologies. The results showed that both Si3N4 and Si3N4/TCP composite coatings were able to form a compact bonding interface between the coating and the substrate by using appropriate laser parameters. The coating layers were dense, demonstrating a good surface appearance. The bioceramic coatings produced by laser cladding have good mechanical properties. Compared with that of the bulk material, microhardness of composite ceramic coatings on the surface significantly increased. In addition, good biological activity could be obtained by adding TCP into the composite coating.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13

Similar content being viewed by others

References

  1. B.V. Krishna, S. Bose, and A. Bandyopadhyay, Low Stiffness Porous Ti Structures for Load-Bearing Implants, Acta Biomater., 2007, 3(6), p 997–1006

    Article  Google Scholar 

  2. D. Kuroda, M. Niinomi, M. Morinaga, Y. Kato, and T. Yashiro, Design and Mechanical Properties of New i Type Titanium Alloys for Implant Materials, Mater. Sci. Eng. A, 1998, 243(1), p 244–249

    Article  Google Scholar 

  3. J.H. Ouyang et al., Characterization of Laser Clad Yttria Partially-Stabilized ZrO2 Ceramic Layers on Steel 16MnCr5, Surf. Coat. Technol., 2001, 137(1), p 12–20

    Article  Google Scholar 

  4. I.R. Pashby, S. Barnes, and B.G. Bryden, Surface Hardening of Steel Using a High Power Diode Laser, J. Mater. Process. Technol., 2003, 139(1-3), p 585–588

    Article  Google Scholar 

  5. A. Bandyopadhyay et al., Influence of Porosity on Mechanical Properties and In Vivo Response of Ti6Al4V Implants, Acta Biomater., 2010, 6(4), p 1640–1648

    Article  Google Scholar 

  6. V.K. Balla et al., Direct Laser Processing of a Tantalum Coating on Titanium for Bone Replacement Structures, Acta Biomater., 2010, 6(6), p 2329–2334

    Article  Google Scholar 

  7. D.K. Pattanayak et al., Bioactive Ti Metal Analogous to Human Cancellous Bone: Fabrication by Selective Laser Melting and Chemical Treatments, Acta Biomater., 2011, 7(3), p 1398–1406

    Article  Google Scholar 

  8. P. Lipinski, A. Barbas, and A.S. Bonnet, Fatigue Behavior of Thin-Walled Grade 2 Titanium Samples Processed by Selective Laser Melting. Application to Life Prediction of Porous Titanium Implants, J. Mech. Behav. Biomed. Mater., 2013, 28, p 274–290

    Article  Google Scholar 

  9. J. Sun, Y. Yang, and D. Wang, Mechanical Properties of a Ti6Al4V Porous Structure Produced by Selective Laser Melting, Mater. Des., 2013, 49, p 545–552

    Article  Google Scholar 

  10. F. Weng, C. Chen, and H. Yu, Research Status of Laser Cladding on Titanium and its Alloys: A Review, Mater. Des., 2014, 58, p 412–425

    Article  Google Scholar 

  11. G.P. Dinda, J. Shin, and J. Mazumder, Pulsed Laser Deposition of Hydroxyapatite Thin Films on Ti-6Al-4V: Effect of Heat Treatment on Structure and Properties, Acta Biomater., 2009, 5(5), p 1821–1830

    Article  Google Scholar 

  12. 侧向送丝激光熔覆成型技术的工艺研究及其数值模拟_孙进.

  13. L. Li, The Advances and Characteristics of High-Power Diode Laser Materials Processing, Optics Lasers Eng, 2000, 34(4), p 231–253

    Article  Google Scholar 

  14. Z. Shi et al., Silicon Nitride Films for the Protective Functional Coating: Blood Compatibility and Biomechanical Property Study, J. Mech. Behav. Biomed. Mater., 2012, 16, p 9–20

    Article  Google Scholar 

  15. B.S. Bal and M.N. Rahaman, Orthopedic Applications of Silicon Nitride Ceramics, Acta Biomater., 2012, 8(8), p 2889–2898

    Article  Google Scholar 

  16. T.J. Webster et al., Anti-Infective and Osteointegration Properties of Silicon Nitride, Poly(Ether Ether Ketone), Titanium Implants, Acta Biomater., 2012, 8(12), p 4447–4454

    Article  Google Scholar 

  17. M. Mazzocchi and A. Bellosi, On the Possibility of Silicon Nitride as a Ceramic for Structural Orthopaedic Implants. Part I: Processing, Microstructure, Mechanical Properties, Cytotoxicity, J. Mater. Sci., 2008, 19(8), p 2881–2887

    Google Scholar 

  18. R.A. Surmenev, M.A. Surmeneva, and A.A. Ivanova, Significance of Calcium Phosphate Coatings for the Enhancement of New Bone Osteogenesis—A Review, Acta Biomater., 2014, 10(2), p 557–579

    Article  Google Scholar 

  19. M. Roy et al., Laser Processing of Bioactive Tricalcium Phosphate Coating on Titanium for Load-Bearing Implants, Acta Biomater., 2008, 4(2), p 324–333

    Article  Google Scholar 

  20. J.J. Candel and V. Amigó, Recent Advances in Laser Surface Treatment of Titanium Alloys, J. Laser Appl., 2011, 23(2), p 022005

    Article  Google Scholar 

  21. H.M. Wang and Y.F. Liu, Microstructure and Wear Resistance of Laser Clad Ti5Si3/NiTi2 Intermetallic Composite Coating on Titanium Alloy, Mater. Sci. Eng., A, 2002, 338(1-2), p 126–132

    Article  Google Scholar 

  22. T. Kokubo and H. Takadama, How useful is SBF in predicting in vivo bone bioactivity? Biomaterials, 2006, 27(15), p 2907–2915

    Article  Google Scholar 

  23. J.L. Murray, Binary Alloy Phase Diagrams, ASM International, Materials Park, 1987

    Google Scholar 

  24. K. Kieswetter, Z. Schwartz, D.D. Dean, and B.D. Boyan, The Role of Implant Surface Characteristics in the Healing of Bone, Crit. Rev. Oral Biol. Med., 1996, 7, p 329–345

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Anguo Huang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Xu, X., Han, J., Wang, C. et al. Laser Cladding of Composite Bioceramic Coatings on Titanium Alloy. J. of Materi Eng and Perform 25, 656–667 (2016). https://doi.org/10.1007/s11665-015-1868-4

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11665-015-1868-4

Keywords

Navigation