Abstract
Stainless steels employed for manufacturing automotive exhaust systems must withstand severe thermal cycles, corrosive environment due to urea decomposition, and welding operations. AISI 409 ferritic stainless steel can be considered a low-cost alternative for this application. However, depending on the manufacturing conditions during welding cycles, this material can be sensitized due to the precipitation of chromium carbides at grain boundaries. In this work, the intergranular corrosion resistances of the AISI 409 ferritic stainless steel were evaluated after annealing at 300, 500, and 700 °C for 2, 4, and 6 h. Solution-annealed samples were also tested for comparison purposes. Two methodologies were used to assess the sensitization behavior of the 409 stainless steel samples: the first one was based on the ASTM A763 (practice W), while the second one was based on the double-loop electrochemical potentiodynamic reactivation test. It was possible to identify that the annealing treatment performed at 500 °C was more critical to the occurrence of intergranular corrosion.
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X.-M. You, Z.-H. Jiang, and H.-B. Li, Ultra-Pure Ferritic Stainless Steels—Grade, Refining, Operation, and Application, J. Iron Steel Res. Int., 2007, 14, p 24–30
C.J. Niekerk and M. du Toit, Sensitization Behavior of 11-12% Cr AISI, 409 Stainless Steel During Low Heat Input Welding, J. South Afr. Inst. Min. Metall., 2011, 111, p 243–256
M.C. Li, S.D. Wang, R.Y. Ma, P.H. Han, and H.Y. Bi, Effect of Cyclic Oxidation on Electrochemical Corrosion of Type 409 Stainless Steel in the Simulated Muffler Condensates, J. Solid State Electrochem., 2012, 16, p 3059–3067
J.K. Kim, Y.H. Kim, B.H. Lee, and K.Y. Kim, New Findings on Intergranular Corrosion Mechanism of Stabilized Stainless Steels, Electrochim. Acta, 2011, 56, p 1701–1710
M.-Z. Joe and D.-R. Kim, Characterisation of Sensitization of Type 409 Stainless Steel, Br. Corros. J., 1999, 34, p 210–213
ASTM International: Standard Practices for Detecting Susceptibility to Intergranular Attack in Ferritic Stainless Steels, Designation: A763, 2009
P.L. Neto, J.P. Farias, L.F.G. Herculano, H.C. de Miranda, W.S. Araújo, J.-B. Jorcin, and N. Pébère, Determination of the Sensitized Zone Extension in Welded AISI, 304 Stainless Steel Using Non-Destructive Electrochemical Techniques, Corros. Sci., 2008, 50, p 1149–1155
G.H. Aydogdu and M.K. Aydinol, Determination of Susceptibility to Intergranular Corrosion and Electrochemical Reactivation Behavior of AISI, 316L Type Stainless Steel, Corros. Sci., 2006, 48, p 3565–3583
J. Hong, D. Han, H. Tan, J. Li, and Y. Jiang, Evaluation of Aged Duplex Stainless Steel UNS S32750 Susceptibility to Intergranular Corrosion by Optimized Double Loop Electrochemical Potentiokinetic Reactivation Method, Corros. Sci., 2013, 68, p 249–255
V. Cihal and R. Stefec, On the Development of the Electrochemical Potentiokinetic Method, Electrochim. Acta, 2001, 46, p 3867–3877
C.T. Kwok, K.H. Lo, W.K. Chan, F.T. Cheng, and H.C. Man, Effect of Laser Surface Melting on Intergranular Corrosion Behavior of Aged Austenitic and Duplex Stainless Steels, Corros. Sci., 2011, 53, p 1581–1591
P. Ganesh, A.V. Kumar, C. Thinaharan, N.G. Krishna, R.P. George, N. Parvathavarthini, S.K. Rai, R. Kaul, U.K. Mudali, and L.M. Kukreja, Enhancement of Intergranular Corrosion Resistance of Type 304 Stainless Steel Through A Novel Surface Thermo-Mechanical Treatment, Surf. Coat. Technol., 2013, 232, p 920–927
M. Momeni, M.H. Moayed, and A. Davoodi, Turning DOS Measuring Parameters Based on Double-Loop EPR in H2SO4 Containing KSCN by Taguchi Method, Corros. Sci., 2010, 52, p 2653–2660
M.A. Streicher, Chapter 21: Intergranular, Corrosion Tests and Standards: Application and Interpretation, R. Baboian, Ed., ASTM International, West Conshohocken, 2005,
P. Novak, R. Stefec, and F. Franz, Testing the Susceptibility of Stainless Steel to Intergranular Corrosion by a Reactivation Method, Corrosion, 1975, 31, p 344–347
A.K. Lakshminarayanan and V. Balasubramanian, Sensitization Resistance of Friction Stir Welded AISI, 409M Grade Ferritic Stainless Steel, Int. J. Adv. Manuf. Technol., 2012, 59, p 961–967
R.G. Nooning Jr., Effect of Stabilizing Elements on the Precipitation Behavior and Phase Stability of Type 409 Ferritic Stainless Steel, Thesis, University of Pittsburgh, 2002
J.K. Kim, Y.H. Kim, S.H. Uhm, J.S. Lee, and K.Y. Kim, Intergranular Corrosion of Ti-Stabilized 11 wt% Cr Ferritic Stainless Steel for Automotive Exhaust Systems, Corros. Sci., 2009, 51, p 2716–2723
V. Cihal, S. Lasek, M. Blahetova, E. Kalabisova, and Z. Krhutova, Trends in the Electrochemical Polarization Potentiodynamic Reactivation Method-EPR, Chem. Biochem. Eng. Q., 2007, 21, p 47–54
H.E. Buhler, L. Gerlach, O. Greven, and W. Bleck, The Electrochemical Reactivation Test (ERT) to Detect the Susceptibility to Intergranular Corrosion, Corros. Sci., 2003, 45, p 2325–2336
A.P. Majidi and M.A. Streicher, The Double Loop Reactivation Method for Detecting Sensitization in AISI, 304 Stainless Steels, Corrosion, 1984, 40, p 584–593
C.S. Brossia and K.L. Martin, Intergranular Corrosion of Type 409 Stainless Steel Used in Automotive Exhaust Applications, Corrosion 98 (Houston), NACE Conference Paper, Paper No. 542, 1998, p 1–18
S. Frangini and A. Mignone, Modified Electrochemical Potentiokinetic Reactivation Method for Detecting Sensitization in 12 wt.% Cr Ferritic Stainless Steels, Corrosion, 1992, 48, p 715–726
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The authors are grateful to Suprens (Brazil) for the kind gesture in providing the AISI 409 sheet used in this work.
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Scalise, T.C., de Oliveira, M.C.L., Sayeg, I.J. et al. Sensitization Behavior of Type 409 Ferritic Stainless Steel: Confronting DL-EPR Test and Practice W of ASTM A763. J. of Materi Eng and Perform 23, 2164–2173 (2014). https://doi.org/10.1007/s11665-014-1010-z
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DOI: https://doi.org/10.1007/s11665-014-1010-z