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Metal-Perylene-3,4,9,10-Tetracarboxylate as a Promising Anode Material for Sodium Ion Batteries

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Abstract

Sodium ion batteries (SIBs) have recently attracted increasing attention as promising alternatives to lithium ion batteries. Therefore, there is an urgent need to develop suitable electrode materials with high energy efficiency and good cyclic stability for SIBs. In this work, a series of metal–organic complexes (M-PTC, metal = Li, Ni, Co, Mn) based on 3,4,9,10-perylene-tetracaboxylicacid-dianhydride have been prepared by a simple rheological phase method. The structure, morphology, thermal stability and electrochemical properties of the obtained M-PTC have been systematically investigated. As anodes for SIBs, Ni-PTC electrodes deliver high initial capacity but poor cycling stability, while Co-PTC electrodes present good cycling stability but low capacity. Remarkably, Li-PTC and Mn-PTC electrodes show both high capacity and good cycling stability. Electrochemical impedance spectroscopy demonstrates that Li-PTC and Mn-PTC electrodes have a smaller impedance than that of Ni-PTC and Co-PTC electrodes. The superior electrochemical performance of Li-PTC and Mn-PTC electrodes can be ascribed to their regular morphology, appropriate particle size, and monodispersed structure. The results indicate that these metal–organic complexes are promising anode materials for SIBs.

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Acknowledgment

This work was supported by the National Natural Science Foundation of China (No. 21503282).

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Authors and Affiliations

  1. Key Laboratory of Resources Green Conversion and Utilization of the State Ethnic Affairs Commission and Ministry of Education, South-Central University for Nationalities, Wuhan, 430074, China

    Xiaoyan Han, Qing Zhang & Haowen Liu

  2. College of Chemistry and Molecular Science, Wuhan University, Wuhan, 430072, China

    Jutang Sun

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  1. Xiaoyan Han
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  2. Qing Zhang
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  4. Jutang Sun
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Han, X., Zhang, Q., Liu, H. et al. Metal-Perylene-3,4,9,10-Tetracarboxylate as a Promising Anode Material for Sodium Ion Batteries. J. Electron. Mater. 48, 5055–5061 (2019). https://doi.org/10.1007/s11664-019-07308-1

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