Skip to main content
Log in

Sputter-Deposited AlTiO Thin Films for Semi-Transparent Silicon Thin Film Solar Cells

  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

Abstract

This paper reports on sputter-deposited AlTiO (ATO) thin films and their effects on the performance of semi-transparent silicon thin film solar cells. The electrical resistivity and the transparency of the ATO films depend significantly on the flow ratio of oxygen to argon during the reactive sputtering process. With highly transparent ATO films, transmittances of over 80% were obtained by increasing this flow ratio. When the ATO films were used on silicon substrates, they exhibited an anti-reflection property, where the minimum reflectance at visible light wavelength was decreased to 1.2%. The introduction of ATO thin film layers into solar cells resulted in a 24% increase in transmittance at wavelengths of around 700 nm, due to the film’s anti-reflection characteristic. In addition, the color of the cells changed from green to bright red as the ATO layers were adopted. These beneficial effects of the sputter-deposited ATO films suggest an effective pathway towards the semi-transparent silicon thin film solar cells for building-integrated photovoltaic system applications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A.V. Shah, J. Meier, E. Vallat-Sauvain, N. Wyrsch, U. Kroll, C. Droz, and U. Graf, Sol. Energ. Mat. Sol. C. 78, 469 (2003).

    Article  Google Scholar 

  2. M.H. Liao and C.H. Chen, IEEE Trans. Nanotechnol. 10, 770 (2011).

    Article  Google Scholar 

  3. L. Zhang, H. Shen, and J. You, J. Electron. Mater. 42, 2464 (2013).

    Article  Google Scholar 

  4. S. Ito, T.N. Murakami, P. Comte, P. Liska, C. Grätzel, M.K. Nazeeruddin, and M. Grätzel, Thin Solid Films 516, 4613 (2008).

    Article  Google Scholar 

  5. H. Maurus, M. Schmid, B. Blersch, P. Lechner, and H. Schade, Re-focus 5, 22 (2004).

    Google Scholar 

  6. M. Hiraishi, N. Nakanishi, US Patent 7098395 B2 (2006).

  7. See Thru Building Integrated Glazing System Suntech, www.suntech-power.com (2009).

  8. X. Zhang, M. Saemann, J. Hu, A. Kunrath, A. Berger, and A. Madan, in 2006 IEEE 4th World Conference on Photovoltaic Energy Conversion, vol. 2 (2006), p. 1517.

  9. E. Fathi and A. Sazonov, in 2010 35th IEEE IEEE Photovoltaic Specialists Conference (PVSC) (2010), p. 1500.

  10. J.W. Lim, D.J. Lee, and S.J. Yun, Electrochem. Solid-State Lett. 2, Q47 (2013).

    Article  Google Scholar 

  11. S.H. Lee, S.J. Yun, M. Shin, and J.W. Lim, Sol. Energ. Mat. Sol. C. 117, 519 (2013).

    Article  Google Scholar 

  12. N. Yamaguchi, K. Tadanaga, A. Matsuda, T. Minami, and M. Tatsumisago, Surf. Coat. Tech. 201, 3653 (2006).

    Article  Google Scholar 

  13. L.M. Doeswijk, H.H.C. de Moor, D.H.A. Blank, and H. Rogalla, Appl. Phys. A69, S409 (1999).

    Article  Google Scholar 

  14. P. Vitanov, A. Harizanova, Chr. Angelov, I. Petrov, Z. Alexieva, and P. Stefanov, Vacuum 76, 215 (2004).

    Article  Google Scholar 

  15. J.W. Lim, S.J. Yun, and H.T. Kim, Jpn. J. Appl. Phys. 47, 6934 (2008).

    Article  Google Scholar 

  16. J.W. Lim, S.H. Lee, J.K. Kim, and S.J. Yun, Electrochem. Solid-State Lett. 13, G17 (2010).

    Article  Google Scholar 

  17. D.A. Glocker and S.I. Shah, Handbook of Thin Film Process Technology (London: Institute of Physics, 1995), p. A3.0.14.

    Google Scholar 

  18. K. Takamura, Y. Abe, and K. Sasaki, Vacuum 74, 397 (2004).

    Article  Google Scholar 

  19. J. Rodriguez, M. Gomez, J. Ederth, G.A. Niklasson, and C.G. Granqvist, Thin Solid Films 365, 119 (2000).

    Article  Google Scholar 

  20. J.W. Lim, S.J. Yun, and H.T. Kim, J. Electrochem. Soc. 154, G239 (2007).

    Article  Google Scholar 

  21. J. Ushida, M. Tokushima, M. Shirane, and H. Yamada, Appl. Phys. Lett. 82, 7 (2003).

    Article  Google Scholar 

  22. P. Campbell and M.A. Green, J. Appl. Phys. 62, 243 (1987).

    Article  Google Scholar 

  23. S.-Y. Lee, S.U. Jeong, K.S. Bang, and J.W. Lim, in Proceedings in SPIE 8438, Photonics for Solar Energy Systems IV (2012), p. 84381P.

Download references

Acknowledgement

This research was supported by the Basic Science Research Program through the National Research Foundation of Korea, funded by the Ministry of Education NRF-2013R1A1A2058709.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Seung-Yun Lee.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lee, SY., Bang, K.S. & Lim, J.W. Sputter-Deposited AlTiO Thin Films for Semi-Transparent Silicon Thin Film Solar Cells. J. Electron. Mater. 43, 3204–3210 (2014). https://doi.org/10.1007/s11664-014-3286-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11664-014-3286-z

Keywords

Navigation