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Preparation of TiO2(B) Nanosheets by a Hydrothermal Process and Their Application as an Anode for Lithium-Ion Batteries

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Abstract

TiO2 nanosheets with single monoclinic phase have been synthesized by a hydrothermal method using 6 M NaOH aqueous solution at 180°C. TiO2 nanosheets exhibited surface area of 100 m2 g−1, which is larger than those obtained by solid-state reaction. The capability of lithium-ion batteries could be strongly enhanced by TiO2(B) nanosheets to yield discharge capacity higher than 200 mAh g−1, even upon 25 cycles of 0.1-C-rate discharge–charge operations, showing highly reversible capacity and good cycling stability with excellent capacity retention of 96% with water-based binder. The results suggest that TiO2(B) nanosheets could be a promising negative electrode material for use in lithium-ion batteries.

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Authors and Affiliations

  1. Department of Materials Science and Engineering, National Cheng Kung University, Tainan, 701, Taiwan

    Hsin-Yi Wu, Min-Hsiung Hon & Chi-Yun Kuan

  2. Research Center for Energy Technology and Strategy, National Cheng Kung University, Tainan, 701, Taiwan

    Min-Hsiung Hon

  3. Department of Materials Science, National University of Tainan, Tainan, 701, Taiwan

    Ing-Chi Leu

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  1. Hsin-Yi Wu
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  2. Min-Hsiung Hon
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  3. Chi-Yun Kuan
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  4. Ing-Chi Leu
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Correspondence to Ing-Chi Leu.

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Wu, HY., Hon, MH., Kuan, CY. et al. Preparation of TiO2(B) Nanosheets by a Hydrothermal Process and Their Application as an Anode for Lithium-Ion Batteries. J. Electron. Mater. 43, 1048–1054 (2014). https://doi.org/10.1007/s11664-013-2951-y

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  • DOI: https://doi.org/10.1007/s11664-013-2951-y

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