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Electrodeposition of MWNT/Bi2Te3 Composite Thermoelectric Films

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Abstract

The effect of multiwalled carbon nanotubes (MWNTs) on the electrochemical behavior of the Bi-Te binary system in nitric acid baths was investigated by means of cyclic voltammetry and electrochemical impedance spectroscopy. Based on the results, MWNT/Bi2Te3 composite thermoelectric films were prepared by potentiostatic electrodeposition at room temperature. The morphology, composition, and structure of the MWNT/Bi2Te3 composite films were analyzed by environmental scanning electron microscopy, energy-dispersive spectroscopy, and x-ray diffraction. The results show that addition of MWNTs to the electrolyte did not change the electrochemical reduction mechanisms of Bi3+, HTeO +2 or their mixture, but the reduction processes of Bi3+, HTeO +2 , and their mixture become easier. MWNT/Bi2Te3 composite thermoelectric films can be obtained by potentiostatic electrodeposition at a wide range of potentials with subsequent annealing. The MWNTs in the films act as nucleation sites for Bi2Te3 compound and thereby elevate the film deposition rate. The content of Bi element and MWNTs in the films increased as the potential was shifted negatively. In addition, the MWNTs can enhance the crystallization of Bi2Te3 film.

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References

  1. D.M. Rowe, CRC Handbook of Thermoelectrics (Boca Raton, FL: CRC Press, 1994), p. 1.

    Google Scholar 

  2. L.S. Su and Y.X. Gan, Electrochim. Acta 56, 16 (2011).

    Google Scholar 

  3. A. Giani, A. Al Bayaz, and A. Foucaran, J. Cryst. Growth 236, 217 (2002).

    Article  CAS  Google Scholar 

  4. Y.B. Liu, S.M. Zhou, X.Y. Yuan, S.Y. Lou, T. Gao, X.J. Shi, and X.P. Wu, Mater. Lett. 84, 1 (2012).

    Article  Google Scholar 

  5. T.E. Huber and R. Calcao, Proceedings of the 16th International Conference on Thermoelectrics (IEEE, 1997), p. 404.

  6. Y.X. Gan, J. Sweetman, and J.G. Lawrence, Mater. Lett. 64, 3 (2010).

    Google Scholar 

  7. D.D. Frari, S. Diliberto, N. Stein, C. Boulanger, and J.M. Lecuire, J. Appl. Electrochem. 36, 449 (2006).

    Article  Google Scholar 

  8. T.J. Yoon, Y.H. Park, and T.S. Oh, Mater. Sci. Forum 544, 917 (2007).

    Article  Google Scholar 

  9. L.X. Bu, W. Wang, and H. Wang, Mater. Res. Bull. 43, 1808 (2008).

    Article  CAS  Google Scholar 

  10. L. Li, G.H. Li, Y. Zhang, Y.W. Yang, and L.D. Zhang, J. Phys. Chem. B. 108, 19380 (2004).

    Article  CAS  Google Scholar 

  11. D. Delfrari, S. Diliberto, N. Stein, C. Boulanger, and J. Lecuire, Thin Solid Films 483, 44 (2005).

    Article  CAS  Google Scholar 

  12. P. Heo, K. Hagiwara, R. Ichino, and M. Okido, J. Electrochem. Soc. 153, C213 (2006).

    Article  CAS  Google Scholar 

  13. H. Ebe, M. Ueda, and T. Ohtsuka, Electrochim. Acta 53, 100 (2007).

    Article  CAS  Google Scholar 

  14. F.H. Li and W. Wang, Electrochim. Acta 17, 5000 (2010).

    Article  Google Scholar 

  15. B. Liu, Z.X. Zeng, and Y.M. Lin, Surf. Coat. Technol. 203, 3610 (2009).

    Article  CAS  Google Scholar 

  16. Y.L. Yang, Y.D. Wang, and Y. Ren, Mater. Lett. 62, 47 (2008).

    Article  CAS  Google Scholar 

  17. P.E. Lopes, F.V. Hattum, and C.M.C. Pereira, Compos. Struct. 92, 1291 (2010).

    Article  Google Scholar 

  18. A. Sharma, S. Kumar, and B. Tripathi, Int. J. Hydrogen Energy 34, 3977 (2009).

    Article  CAS  Google Scholar 

  19. J.P. Small, L. Shi, and P. Kim, Solid State Commun. 127, 181 (2003).

    Article  CAS  Google Scholar 

  20. C. Yu, Y.S. Kim, and D. Kim, Nano Lett. 8, 4428 (2008).

    Article  CAS  Google Scholar 

  21. D.H. Park, M.Y. Kim, and T.S. Oh, Curr. Appl. Phys. 11, S41 (2011).

    Article  Google Scholar 

  22. F.H. Li, F.L. Jia, and W. Wang, Appl. Surf. Sci. 255, 7394 (2009).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300072, People’s Republic of China

    Han Xu & Wei Wang

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  1. Han Xu
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  2. Wei Wang
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Correspondence to Wei Wang.

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Xu, H., Wang, W. Electrodeposition of MWNT/Bi2Te3 Composite Thermoelectric Films. J. Electron. Mater. 42, 1936–1945 (2013). https://doi.org/10.1007/s11664-013-2479-1

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  • DOI: https://doi.org/10.1007/s11664-013-2479-1

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