Skip to main content
Log in

Preparation and Thermoelectric Properties of La-Doped SrTiO3 Ceramics

  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

Abstract

Single-phase polycrystalline La x Sr1−x TiO3 (x = 0, 0.04, 0.06, 0.08, and 0.12) ceramics were prepared by the conventional solid-state reaction method using high-activity hydroxides as the raw materials. The electrical conductivity of all the samples increased with increasing x value and decreased with measurement temperature, while the thermal conductivity decreased with increasing x value and measurement temperature. The La0.12Sr0.88TiO3 sample showed the lowest thermal conductivity of 2.45 W m−1 K−1 at 873 K and the largest ZT of 0.28 at 773 K. The present work revealed that hydroxides with high activity as raw materials are beneficial to improve the thermoelectric properties, especially to decrease the thermal conductivity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. B. Raton, CRC Handbook of Thermoelectrics (Florida, USA: CRC, 1995).

    Google Scholar 

  2. G. Chen, M.S. Dresselhaus, G. Dresselhaus, J.P. Fleurial, and T. Caillat, Int. Mater. Rev. 48, 45 (2003).

    Article  CAS  Google Scholar 

  3. B. Poudel, Q. Hao, Y. Ma, Y.C. Lan, A. Minnich, B. Yu, X. Yan, D.Z. Wang, A. Muto, D. Vashaee, X.Y. Chen, J.M. Liu, M.S. Dresselhaus, G. Chen, and Z.F. Ren, Science 320, 634 (2008).

    Article  CAS  Google Scholar 

  4. X.F. Tang, W.J. Xie, H. Li, W.Y. Zhao, Q.J. Zhang, and M. Niino, Appl. Phys. Lett. 90, 012102 (2007).

    Article  Google Scholar 

  5. G.S. Nolas, M. Kaeser, R.T. Littleton IV, and T.M. Tritt, Appl. Phys. Lett. 77, 1855 (2000).

    Article  CAS  Google Scholar 

  6. X.F. Tang, L.D. Chen, T. Goto, and T. Hirai, J. Mater. Res. 16, 837 (2001).

    Article  CAS  Google Scholar 

  7. S. Sakurada and N. Shutoh, Appl. Phys. Lett. 86, 082105 (2005).

    Article  Google Scholar 

  8. H. Ohta, K. Sugiure, and K. Koumoto, Inorg. Chem. 47, 8429 (2008).

    Article  CAS  Google Scholar 

  9. I. Terasaki, Y. Sasago, and K. Uchinokura, Phys. Rev. B 56, R12685 (1997).

    Article  CAS  Google Scholar 

  10. K. Fujita, T. Mochida, and K. Nakamura, Jpn. J. Appl. Phys. 40, 4644 (2001).

    Article  CAS  Google Scholar 

  11. T. Okuda, K. Nakanishi, S. Miyasaka, and Y. Tokura, Phys. Rev. B. 63, 113104 (2001).

    Article  Google Scholar 

  12. H. Muta, K. Kurosaki, and S. Yamanaka, J. Alloys Compd. 350, 292 (2003).

    Article  CAS  Google Scholar 

  13. H.C. Wang, C.L. Wang, W.B. Su, J. Liu, Y. Zhao, H. Peng, J.L. Zhang, M.L. Zhao, J.C. Li, N. Yin, and L.M. Mei, Mater. Res. Bull. 45, 809 (2010).

    Article  CAS  Google Scholar 

  14. L.H. Zhang, T. Tosho, N. Okinaka, and T. Akiyama, Mater. Trans. 48, 1079 (2007).

    Article  CAS  Google Scholar 

  15. P.P. Shang, B.P. Zhang, J.F. Li, and N. Ma, Solid State Sci. 12, 1341 (2010).

    Article  CAS  Google Scholar 

  16. W.H. Gong, H. Yun, Y.B. Ning, J.E. Greedan, W.R. Datars, and C.V. Stager, J. Solid State Chem. 90, 320 (1991).

    Article  CAS  Google Scholar 

  17. J. Liu, C.L. Wang, W.B. Su, H.C. Wang, P. Zheng, J.C. Li, J.L. Zhang, and L.M. Mei, Appl. Phys. Lett. 95, 162110 (2009).

    Article  Google Scholar 

  18. L.H. Zhang, T. Tosho, N. Okinaka, and T. Akiyama, Mater. Trans. 48, 2088 (2007).

    Article  CAS  Google Scholar 

  19. R.R. Heikes and R.W. Ure Jr, Thermoelectricity: Science and Engineering (New York: Interscience, 1961).

    Google Scholar 

  20. A.M. Ioffe, Semiconductor Thermoelements and Thermoelectric Cooling (London: Infosearch Ltd., 1957).

    Google Scholar 

  21. X.D. Liu and Y.H. Park, Mater. Trans. 43, 681 (2002).

    Article  CAS  Google Scholar 

  22. H. Obara, A. Yamamoto, C.H. Lee, K. Kobayashi, A. Matsumoto, and R. Funahashi, Jap. J. Appl. Phys. 43, L540 (2004).

    Article  CAS  Google Scholar 

  23. S. Ohta, T. Nomura, H. Ohta, M. Hirano, H. Hosono, and K. Koumoto, Appl. Phys. Lett. 87, 092108 (2005).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Bo-Ping Zhang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shang, PP., Zhang, BP., Liu, Y. et al. Preparation and Thermoelectric Properties of La-Doped SrTiO3 Ceramics. J. Electron. Mater. 40, 926–931 (2011). https://doi.org/10.1007/s11664-010-1452-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11664-010-1452-5

Keywords

Navigation