Skip to main content
Log in

Diffusion-Reaction in the Au-Rich Ternary Au-Pt-Sn System as a Basis for Ternary Diffusion Soldering

  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

Abstract

Basic thermodynamic considerations indicate nonequilibrium between gold-tin intermetallic phases and platinum. Therefore, diffusion and reactions in the Au-Pt-Sn(-Ti) thin-film system have been investigated, and a mechanism of reaction is proposed based on experimental results and thermodynamic considerations. The present paper may also help researchers understand previous results that could be interpreted differently based on the new results of this work and basic thermodynamic considerations. A ternary diffusion soldering concept has been proposed, and its application on up to 4-inch wafer-scale bonding was successful. Generalizations of the present approach to other bonding systems appears promising.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. European Commission > Environment > Waste > Waste Electrical and Electronic Equipment, 13 December 2007, http://ec.europa.eu/environment/waste/weee_index.htm

  2. G. Humpston, D.M. Jacobson, (1993) Principles of Soldering and Brazing. ASM International, Materials Park, OH

    Google Scholar 

  3. G. Elger, M. Hutter, H. Oppermann, R. Aschenbrenner, H. Reichl, E. Jäger, (2002) Microsyst. Technol. 7, 239

    Article  Google Scholar 

  4. N. Duan, J. Scheer, J. Bielen, M. van Kleef, (2003) Microelectron. Reliab. 43, 1317

    Article  CAS  Google Scholar 

  5. R.R. Chromik, D.N. Wang, D. Shugar, L. Limata, M.R. Notis, R.P. Vinci, (2005) J. Mater. Res. 20, 2161

    Article  CAS  Google Scholar 

  6. D.M. Jacobson, S.P.S. Sangha, (1996) Solder. Surf. Mt. Tech., 23, 12

    CAS  Google Scholar 

  7. A. Katz, K.W. Wang, F.A. Baiocchi, W.C. Dautremont-Smith, E. Lane, C.H. Lee, Y.M. Wong, K.L. Tai, D.D. Bacon, H.S. Luftman, H. Curnan, R.R. Varna, (1992) Mat. Res. Soc. Symp. Proc. 260, 889

    CAS  Google Scholar 

  8. W. Pittroff, G. Erbert, G. Beister, F. Bugge, A. Klein, A. Knauer, J. Maege, P. Ressel, J. Sebastian, R. Staske, G. Traenkle, (2001) IEEE Trans. Adv. Pack. 24, 434

    Article  CAS  Google Scholar 

  9. X. Liu, K. Song, R.W. Davis, L.C. Hughes, M.H. Hu, C.-E. Zah, (2006) IEEE Trans. Adv. Pack. 29, 533

    Article  CAS  Google Scholar 

  10. K.T. Turner, R. Mlcak, D.C. Roberts, S.M. Spearing, (2002) Mat. Res. Soc. Symp. Proc. 687, 49

    CAS  Google Scholar 

  11. O. Wada, T. Kumai, (1991) Appl. Phys. Lett. 58, 908

    Article  CAS  Google Scholar 

  12. S. lllek, I. Pietzonka, A. Plössl, P. Stauss, W. Wegleiter, R.␣Windisch, R. Wirth, H. Zull, and K. Streubel, Proceedings of SPIE, 4996: Light-emitting Diodes: Research, Manufacturing and Applications VII, ed. E.F. Schubert, H.W. Yao, K.J. Linden, and D.J. McGraw (Bellingham, WA, USA: SPIE, 2003), pp. l8–25

  13. V. Härle, B. Hahn, S. Kaiser, A. Weimar, D. Eisert, S.␣Bader, A.Plössl, and F. Eberhard, Proceedings of SPIE, 4996: Light-emitting Diodes: Research, Manufacturing and Applications VII, ed. E.F. Schubert, H.W. Yao, K.J. Linden, and D.J. McGraw (Bellingham, WA, USA: SPIE, 2003), pp.␣133–138

  14. A. Plößl, Wafer Bonding: Application and Technology, ed. M. Alexe and U. Gösele (Berlin, Heidelberg, New-York: Springer Verlag, 2004) pp. 327–357

  15. B.F. Dyson, (1966) J. Appl. Phys. 37, 2375

    Article  CAS  Google Scholar 

  16. M. Creydt, R. Richter, (1971) Metall (Berlin) 25, 1124

    CAS  Google Scholar 

  17. C. Herzig, T. Heumann, (1972) Z. Naturforsch. Teil A 27, 1109

    CAS  Google Scholar 

  18. C. Herzig, W. Wiemann, (1974) Phys. Status Solidi A, 26, 459

    Article  CAS  Google Scholar 

  19. S. Terashima, T. Uno, E. Hashino, K. Tatsumi, (2001) Mater. Trans. 42, 803

    Article  CAS  Google Scholar 

  20. T. Yamada, K. Miura, M. Kajihara, N. Kurokawa, K. Sakamoto, (2004) J. Mater. Sci. 39, 2327

    Article  CAS  Google Scholar 

  21. A. Paul, A.A. Kodentsov, F.J.J. van Loo, (2004) Z. Metallkde. 95, 913

    CAS  Google Scholar 

  22. T. Yamada, K. Miura, M. Kajihara, N. Kurokawa, K. Sakamoto, (2005) Mat. Sci. Eng. A 390, 118

    Article  CAS  Google Scholar 

  23. M. Kajihara, T. Takenaka, (2007) Mater. Sci. Forum 539–543, 2473

    Google Scholar 

  24. K.N. Tu and R. Rosenberg, Proc. 6th Int. Vacuum Congress 1974, Jpn. J. Appl. Phys. Suppl 2, 633 (1974)

  25. L. Buene, (1977) Thin Solid Films, 47, 159

    Article  CAS  Google Scholar 

  26. V. Simić, Ž. Marinković, (1977) J. Less-Common Met. 51, 177

    Article  Google Scholar 

  27. L. Buene, S.-T. Jacobsen, (1978) Phys. Scr. 18, 397

    Article  CAS  Google Scholar 

  28. L. Buene, H. Falkenberg-Arell, J. Gjønnes, J. Taftø, (1980) Thin Solid Films 67, 95

    Article  CAS  Google Scholar 

  29. S. Nakahara, R.J. McCoy, (1990) Appl. Phys. Lett. 37, 42

    Article  Google Scholar 

  30. M.-G. Barthès, C. Pariset, (1981) Thin Solid Films 77, 305

    Article  Google Scholar 

  31. D. Gregersen, L. Buene, T. Finstag, O. Lønsjø, T. Olsen, (1981) Thin Solid Films 78, 95

    Article  CAS  Google Scholar 

  32. S. Nakahara, R.J. McCoy, L. Buene, J.M. Vandenberg, (1981) Thin Solid Films, 84, 185

    Article  CAS  Google Scholar 

  33. C. Chang, T.A. Callcott, E.T. Arakawa, (1982) J. Appl. Phys. 53, 7362

    Article  CAS  Google Scholar 

  34. B. Hugsted, L. Buene, T. Finstad, O. Lønsjø, T. Olsen, (1982) Thin Solid Films 98, 81

    Article  CAS  Google Scholar 

  35. D.C. Dufner, L. Eyring, (1986) J. Solid State Chem. 62, 112

    Article  CAS  Google Scholar 

  36. S.K. Sharma, M.P. Singh, G.L. Malhotra, (1991) Phys. Stat. Sold. A 128, 407

    Article  CAS  Google Scholar 

  37. J.-G. Wang, M.-L. Tian, T.E. Mallouk, M.H.W. Chan, (2004) Nano Lett. 4, 1313

    Article  CAS  Google Scholar 

  38. T. Laurila, V. Vuorinen, J. Kivilahti, (2005) Mat. Sci. Eng. R49, 1

    CAS  Google Scholar 

  39. O. Wada, T. Kumai, (1991) Jpn. J. Appl. Phys. 30, 1056

    Article  Google Scholar 

  40. O. Wada, (1992) Mat. Res. Soc. Symp. Proc. 260, 713

    CAS  Google Scholar 

  41. A. Katz, K.W. Wang, F.A. Baiocchi, W.C. Dautremont-Smith, E. Lane, H.S. Luftman, R.R. Varna, H. Curnan, (1993) Mater. Chem. Phys., 33, 281

    Article  CAS  Google Scholar 

  42. A. Katz, C.H. Lee, K.L. Tai, (1994) Mater. Chem. Phys., 37, 303

    Article  CAS  Google Scholar 

  43. C.H. Lee, Y.M. Won, C. Doherty, K.L. Tai, E. Lane, D.D. Bacon, F. Baiocchi, A. Katz, J. Appl. Phys. 72, 3308 (1992)

    Google Scholar 

  44. C.H. Lee, K.L. Tai, D.D. Bacon, C. Doherty, A. Katz, Y.M. Wong, E. Lane, (1994) Semicond. Sci. Technol. 9, 379

    Article  CAS  Google Scholar 

  45. A. Klein, W. Pittroff, I. Sieber, Int. Phys. Conf. Ser. No. 160, DRIP 97, 495 (1997)

    Google Scholar 

  46. S. Anhöck, H. Oppermann, C. Kallmayer, R. Aschenbrenner, L. Thomas, and H. Reichl, EuPac 98, 3rd European Conference on Electronic Packaging Technology and 9th International Conference on Interconnection Technology in Electronics (Nürnberg, June 15–17, 1998), pp. 43–46

  47. S. Anhöck, H. Oppermann, C. Kallmayer, R. Aschenbrenner, H. Reichl, and L. Thomas, available online: http://www.pb.izm.fhg.de/avt/030_public/1998/addon/Investigations_AuSn_diff_end_metall.pdf (1998)

  48. S. Anhöck, H. Oppermann, C. Kallmayer, R. Aschenbrenner, H. Reichl, and L. Thomas, 22nd IEEE/CPMT International Electronics Manufacturing Technology Symposium. IEMT-Europe 1998. Electronics Manufacturing and Development for Automotives (Berlin, Germany, New-York, April 27–29, 1998), pp. 156–165

  49. D.G. Ivey, (1998) Micron 29, 281

    Article  CAS  Google Scholar 

  50. J.-H. Park, J.H. Lee, Y.-H. Lee, Y.-S. Kim, (2002) J. Electron. Mater.31, 1175

    Article  CAS  Google Scholar 

  51. J.S. Kirkaldy, L.C. Brown, (1963) Can. Metall. Q., 2, 89

    CAS  Google Scholar 

  52. J.B. Clark, (1963) Trans. Met. Soc. AIME 227, 1250

    CAS  Google Scholar 

  53. F.J.J. van Loo, (1990) Prog. Solid St. Chem., 20, 47

    Article  Google Scholar 

  54. T. Laurila (PhD thesis, Helsinki University of Technology, 2001)

  55. V. Grolier, R. Schmid-Fetzer, (2008) J. Electron. Mater. 37, 267

    Google Scholar 

  56. S.-L. Chen, S. Daniel, F. Zhang, Y. A. Chang, X.-Y. Yan, F.-Y. Xie, R. Schmid-Fetzer, W. A. Oates, (2002) Calphad, 26, 175

    Article  CAS  Google Scholar 

  57. V. Grolier, R. Schmid-Fetzer, (2007) Int. J. Mater. Res. (formerly Z. Metallkde.) 98, 797

    CAS  Google Scholar 

  58. V. Grolier, R. Schmid-Fetzer, (2008) J. Alloys Compd. 450, 264

    Article  CAS  Google Scholar 

  59. V. Grolier and R. Schmid-Fetzer, Landolt-Boernstein, Numerical Data and Functional Relationships in Science and Technology (New Series). Group IV: Physical Chemistry, ed. W. Martiensen; Ternary Alloy Systems. Phase Diagrams, Crystallographic and Thermodynamic Data, vol. 11B, ed. G.␣Effenberg and S. Ilyenko (Berlin, Heidelberg: Springer-Verlag, 2006), pp. 309–313

  60. A.N. Torgersen, L. Offernes, A. Kjekshus, A. Olsen, (2001) J. Alloys Compd., 314, 92

    Article  CAS  Google Scholar 

  61. W. Kraus and G. Nolze, Powder Cell for Windows Version␣2.3, available online: http://www.bam.de/de/service/publikationen/powder_cell.htm, BAM (Bundesanstalt für Materialprüfung und –prüfung) (1999)

  62. P. Villars and L.D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases (Materials Park, OH: ASM, 1991)

  63. H. Bruining, (1942) Die Sekundär-Elektron-Emission fester Körper. Springer-Verlag, Berlin

    Google Scholar 

  64. G.F. Dionne, (1975) J. Appl. Phys., 46, 3347

    Article  CAS  Google Scholar 

  65. S.A. Schwarz, (1990) J. Appl. Phys. 68, 2382

    Article  CAS  Google Scholar 

  66. Private communication with A. Graff, IWMH Fraunhofer, Halle (2006)

  67. M.E. Glicksman, Diffusion in Solids: Field Theory, Solid-State Principles and Applications (John Wiley & Sons, Inc., 2000)

  68. T.B. Massalski, H. Okamoto, P.R. Subramanian, and L.␣Kacprzak, eds., Binary Alloy Phase Diagrams, vol. 1–3, 2nd ed. (Materials Park, OH: ASM International, 1990) 3589 pp

  69. T. Biggs, L.A. Cornish, M.J. Witcomb, M.B. Cortie, (2004) J. Alloys Compd. 375, 120

    Article  CAS  Google Scholar 

  70. C. Kuper, W. Peng, A. Pisch, F. Goesmann, R. Schmid.Fetzer, (1998) Z. Metallkde., 89, 855

    CAS  Google Scholar 

  71. T.C. Tisone, J. Drobek, J. Vac. Sci. Technol., 9 (1971), 271

    Article  Google Scholar 

  72. A. Prince, G.V. Raynor, D.S. Evans, (1990) Phase Diagrams of Ternary Gold Alloys. The Institute of Metals, London

    Google Scholar 

  73. P. Liang, MSIT Ternary EvaluationProgram, in MSIT Workplace, ed. G. Effenberg (Stuttgart: MSI, Materials Science International Services GmbH, 1995); Document ID: 10.30090.1.20

  74. G. Ghosh, (2001) Acta Mater. 49, 2609

    Article  CAS  Google Scholar 

  75. R. Schmid-Fetzer, Design Fundamentals of High Temperature Composites, Intermetallics, and Metal-Ceramics Systems, ed. R.Y. Lin, Y.A. Chang, R.G. Reddy, and C.T. Liu (TMS, 1995), pp. 75–98

  76. J. Ciulik, M.R. Notis, (1993) J. Alloys Compd., 191, 71

    Article  CAS  Google Scholar 

  77. A. Plößl, G. Kräuter, (1999) Mat. Sci. Eng. R25, 1

    Google Scholar 

Download references

Acknowledgements

This work has been supported by Osram Opto Semiconductors GmbH, Regensburg. Special thanks are due to Dr. A. Plößl for his encouragement of this study.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Rainer Schmid-Fetzer.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Grolier, V., Schmid-Fetzer, R. Diffusion-Reaction in the Au-Rich Ternary Au-Pt-Sn System as a Basis for Ternary Diffusion Soldering. J. Electron. Mater. 37, 815–828 (2008). https://doi.org/10.1007/s11664-008-0407-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11664-008-0407-6

Keywords

Navigation