HgCdTe mid-wavelength IR photovoltaic detectors fabricated using plasma induced junction technology

Abstract

Preliminary characterization results are presented for mid-wave infrared (MWIR) mercury cadmium telluride n-on-p photodiodes fabricated using a plasma induced type conversion junction formation technology. The diodes have been fabricated on three different vacancy doped p-type epitaxial starting materials, grown by liquid phase epitaxy (LPE) on CdZnTe, LPE on sapphire, and P/p isotype heterojunction material grown by molecular beam epitaxy (MBE) on CdZnTe. All materials had CdTe mole fraction in the active region of the device of ∼0.3. The process uses a H₂/CH₄ plasma generated in a parallel plate reactive ion etching (RIE) system to type convert the p-type material to n-type. The process is different from previously reported type conversion techniques in that it does not require a high temperature anneal, does not expose the junction at the surface to atmosphere after formation, and requires significantly fewer process steps than other planar processes. Homojunction devices fabricated using this process exhibit R₀A values >10⁷ Ω·cm² at 80 K. The R₀A is diffusion limited for temperatures >∼135 K. Results for responsivity, bias dependence of dynamic resistance — junction area product and 1/f noise show that the resulting diodes are comparable to the best planar diodes reported in the literature.