Skip to main content
Log in

Initial Wetting Phenomena of MgO–SiO2 Liquid Slag on MgO–C Refractories

  • Brief Communication
  • Published:
Metallurgical and Materials Transactions B Aims and scope Submit manuscript

Abstract

The initial wetting phenomena of MgO–SiO2 slag on MgO–C refractories were studied using the dispensed drop technique at 1873 K. As the carbon content increased, the apparent contact angle and height increased, whereas the apparent radius decreased. The change in the apparent contact angle according to the carbon content was applied to the Cassie model. Reduced Si was observed at the boundary between the slag and the refractories.it was seen that SiO2(l) + 2C(s) = Si(l) + 2CO(g) was the main reaction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

References

  1. C.M. Diaz, C.A. Landolt, A. Vahed, A.E.M. Warner, and J.C. Taylor: J. Met., 1988, vol. 40, pp. 28–33.

    CAS  Google Scholar 

  2. K. Yang, L. Whitbourn, P. Mason, and J. Huntington: Econ. Geol., 2013, vol. 108, pp. 1285–99.

    Article  CAS  Google Scholar 

  3. G.S. Back, H.S. Park, S.M. Seo, and W.G. Jung: Met. Mater. Int., 2015, vol. 21, pp. 1061–67.

    Article  CAS  Google Scholar 

  4. A.E.M. Warner, C.M. Diaz, A.D. Dalvi, P.J. Mackey, and A.V. Tarasov: J. Met., 2006, vol. 58, pp. 11–20.

    Google Scholar 

  5. C. Wagner, C. Wenzl, D. Gregurek, D. Kreuzer, S. Luidold, and H. Schnideritsch: Metall. Mater. Trans. B, 2017, vol. 48B, pp. 119–31.

    Article  Google Scholar 

  6. L. Rodd, N. Voermann, F. Stober, B. Wasmund, S.H. Lee, K.Y. Lim, J.-H. Yoo, S.-J. Roh, and J.-H. Park: The 12th International Ferroalloys Congress, 2010, pp. 698–700

  7. C. Schacht: Refractories Handbook, 1st ed. Marcel Dekker Inc, New York, 2004, pp. 8–9.

    Book  Google Scholar 

  8. C. Sagadin, S. Luidold, C. Wagner, C. Pichler, D. Kreuzer, A. Spanring, and K. Clarke: Metall. Mater. Trans. B, 2021, vol. 52B, pp. 1052–60.

    Article  Google Scholar 

  9. W. Zhang, A. Huang, Y. Zou, H. Gu, L. Fu, and G. Li: J. Am. Ceram. Soc., 2020, vol. 103, pp. 2128–36.

    Article  CAS  Google Scholar 

  10. R.Q. Bai, S.Y. Liu, F.X. Mao, Y.Y. Zhang, X. Yang, and Z.J. He: J. Iron Steel Res. Int., 2022, vol. 29, pp. 1073–79.

    Article  CAS  Google Scholar 

  11. S. Biswas and D. Sarkar: Introduction to Refractories for Iron- and Steelmaking, 1st ed. Springer, New York, 2020, pp. 47–49.

    Book  Google Scholar 

  12. J.W. Park, K.Y. Lee, J.J. Pak, and Y.S. Chung: ISIJ Int., 2014, vol. 54, pp. 2059–63.

    Article  CAS  Google Scholar 

  13. C.Y. Yoo, J.Y. Myung, and Y.S. Chung: ISIJ Int., 2021, vol. 61, pp. 2923–28.

    Article  CAS  Google Scholar 

  14. S.J. Kim, K.Y. Lee, and Y.S. Chung: Metall. Mater. Trans. B., 2016, vol. 47B, pp. 1209–16.

    Article  Google Scholar 

  15. S.H. Heo, K.Y. Lee, and Y.S. Chung: Trans. Nonferrous Met. Soc. China, 2012, vol. 22, pp. 870–75.

    Article  Google Scholar 

  16. Z. Liu, L. Yuan, E. Jin, X. Yang, and J. Yu: Ceram. Int., 2019, vol. 45, pp. 718–24.

    Article  CAS  Google Scholar 

  17. S. Jansson, V. Brabie, and P. Jönsson: Scand. J. Metall., 2005, vol. 34, pp. 283–92.

    Article  CAS  Google Scholar 

  18. Y. Yuan, T.R. Lee: Surface Science Techniques, 1st ed., Springer, Berlin, 2013, pp. 3–34

  19. J.H. Lee, J.W. Myung, and Y.S. Chung: Metall. Mater. Trans. B., 2021, vol. 52B, pp. 1179–85.

    Article  Google Scholar 

  20. C.L. Pássera, L.B. Manfredi, and A.G. Tomba Martínez: Metall. Mater. Trans. B, 2021, vol. 52B, pp. 1681–94.

    Article  Google Scholar 

  21. J.S. Park, J.M. Jeon, K.Y. Lee, J.H. Park, and Y.S. Chung: Metall. Mater. Trans. B., 2016, vol. 47, pp. 1832–38.

    Article  CAS  Google Scholar 

  22. N. Eustathopoulos, M.G. Nicholas, and B. Drevet: Wettability at High Temperatures, vol. 3, pp. 62–75, Pergamon Materials Series., Pergamon, Oxford, 1999.

  23. B.D. Cassie: Faraday Discuss. R. Soc. Chem., 1948, vol. 3, pp. 11–16.

    Article  Google Scholar 

  24. S.K. Sadrnezhaad, S. Mahshid, B. Hashemi, and Z.A. Nemati: J. Am. Ceram. Soc., 2006, vol. 89, pp. 1308–16.

    Article  CAS  Google Scholar 

  25. J.F. White, J. Lee, O. Hessling, and B. Glaser: Metall. Mater. Trans. B, 2017, vol. 48B, pp. 506–15.

    Article  Google Scholar 

  26. M. Nagamori, I. Malinsky, and A. Claveau: Metall. Mater. Trans. B, 1986, vol. 17, pp. 503–14.

    Article  CAS  Google Scholar 

  27. D.H. Filsinger and D.B. Bourrie: J. Am. Ceram. Soc., 1990, vol. 73, pp. 1726–32.

    Article  CAS  Google Scholar 

  28. A.I. Zaitsev, N.A. Arutyunyan, N.G. Shaposhnikov, N.E. Zaitseva, and V.T. Burtsev: Russ. J. Phys. Chem., 2006, vol. 80, pp. 335–44.

    Article  CAS  Google Scholar 

  29. S. Kambayashi and E. Kato: J. Chem. Thermodyn., 1983, vol. 15, pp. 701–07.

    Article  CAS  Google Scholar 

  30. L.K. Jakobsson and M. Tangstad: Metall. Mater. Trans. B, 2015, vol. 46B, pp. 595–605.

    Article  Google Scholar 

Download references

Acknowledgments

This work was partly supported by Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant (Grant number 20212010100060), and by Korea Institute for Advancement of Technology (KIAT) grant (Grant number P008425) funded by the Ministry of Trade, Industry & Energy (MOTIE), and by the 2020 sabbatical year research grant of the Tech University of Korea.

Conflict of interest

On behalf of all authors, the corresponding author states that there is no conflict of interest.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yongsug Chung.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jeon, S., Myung, J. & Chung, Y. Initial Wetting Phenomena of MgO–SiO2 Liquid Slag on MgO–C Refractories. Metall Mater Trans B 54, 34–42 (2023). https://doi.org/10.1007/s11663-022-02684-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11663-022-02684-2

Navigation