Skip to main content
SpringerLink
Log in

A Reaction Between High Mn–High Al Steel and CaO-SiO2-Type Molten Mold Flux: Reduction of Additive Oxide Components in Mold Flux by Al in Steel

  • Communication
  • Published:
Metallurgical and Materials Transactions B Aims and scope Submit manuscript

Abstract

The interfacial reaction between high-Mn–high-Al steel and CaO-SiO2-type mold flux was investigated, with particular emphasis on the reduction of additive oxide components by Al. Typical additive oxide components (B2O3, Na2O) could be reduced by Al, thereby losing their initial role in the flux. It is proposed to consider the chemical stability of the additive components in the flux in addition to the physico-chemical properties of the flux when developing the mold flux chemistry.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

References

  1. J. Mahieu, B. C. De Cooman, and J. Maki: Metall. Mater. Trans. A, 2002, vol. 33A, pp. 2573–2580.

    Article  CAS  Google Scholar 

  2. K. Sugimoto, J. Sakaguchi, T. Iida, and T. Kashima: ISIJ Int., 2000, vol. 40, pp. 920–926.

    Article  CAS  Google Scholar 

  3. B.C. De Cooman, K.-G. Chin, and J. Kim: New Trends and Developments in Automotive System Engineering, InTech, Winchester, pp. 101–128, 2011.

    Google Scholar 

  4. S.-H. Kim, H. Kim, and N. J. Kim: Nature, 2015, vol. 518, pp. 77–79.

    Article  CAS  Google Scholar 

  5. K. Blazek, H. Yin, G. Skoczlas, M. McClymonds, and M. Frazee: in Proc. AISTech 2011, Association for Iron and Steel Technology, 2011, pp. 1577–86.

  6. M.-S. Kim, S.-W. Lee, J.-W. Cho, M.-S. Park, H.-G. Lee, and Y.-B. Kang: Metall. Mater. Trans. B, 2013, vol. 44B, pp. 299–308.

    Article  Google Scholar 

  7. M.-S. Kim, M.-S. Park, S.-E. Kang, J.-K. Park, and Y.-B. Kang: ISIJ Int., 2018, vol. 58, pp. 686–695.

    Article  CAS  Google Scholar 

  8. J.-W. Cho, K. Blazek, M. Frazee, H. Yin, J. H. Park, and S.-W. Moon: ISIJ Int., 2013, vol. 53, pp. 62–70.

    Article  Google Scholar 

  9. W. Wang, B. Lu, and D. Xiao: Metall. Mater. Trans. B, 2016, vol. 47B, pp. 384–389.

    Article  Google Scholar 

  10. S. He, Z. Li, Z. Chen, T. Wu, and Q. Wang: Steel Res. Int., 2019, vol. 90, p. 1800424.

    Article  Google Scholar 

  11. X. Fu, G. Wen, Q. Liu, P. Tang, J. Li, and W. Li: Steel Res. Int., 2015, vol. 86, pp. 110–120.

    Article  CAS  Google Scholar 

  12. H. Shao, E.  Gao, W.  Wang, L.  Zhang: J. Am. Ceram. Soc., 2019, vol. 102, pp. 4440-4449.

    Article  CAS  Google Scholar 

  13. E.  Gao, W.  Wang, L. Zhang: J. Non-Cryst. Solids, 2017, vol. 473, pp. 79-86.

    Article  CAS  Google Scholar 

  14. Z. G. Yu, H. .Y. Leng, L. J. Wang, K. C. Chou: Ceram. Int., 2019, vol. 45, pp. 7180-7187.

    Article  CAS  Google Scholar 

  15. J. Liao, Y. Zhang, S. Sridhar, X. Wang, and Z. Zhang: ISIJ Int., 2012, vol. 52, pp. 753–758.

    Article  CAS  Google Scholar 

  16. C.-B. Shi, M.-D. Seo, J.-W. Cho, and S.-H. Kim: Metall. Mater. Trans. B, 2014, vol. 45B, pp. 1081–1097.

    Article  Google Scholar 

  17. S. S. Jung and I. Sohn: Metall. Mater. Trans. B, 2012, vol. 43B, pp. 1530–1539.

    Article  Google Scholar 

  18. M. Hayashi, T. Watanabe, H. Nakada, and K. Nagata: ISIJ Int., 2006, vol. 46, pp. 1805–1809.

    Article  CAS  Google Scholar 

  19. B. Lu, K. Chen, W. Wang, and B. Jiang: Metall. Mater. Trans. B, 2014, vol. 45B, pp. 1496–1509.

    Article  Google Scholar 

  20. L. Zhou, H. Li, W. Wang, D. Xiao, L. Zhang, and J. Yu: Metall. Mater. Trans. B, 2018, vol. 49B, pp. 2232–2240.

    Article  Google Scholar 

  21. H. Kim and I. Sohn: ISIJ Int., 2011, vol. 51, pp. 1–8.

    Article  CAS  Google Scholar 

  22. D. Xiao, W. Wang, and B. Lu: Metall. Mater. Trans. B, 2015, vol. 46B, pp. 873–881.

    Article  Google Scholar 

  23. W. Yan, W. Chen, Y. Yang, C. Lippold, and A. Mclean: ISIJ Int., 2015, vol. 55, pp. 1000–1009.

    Article  CAS  Google Scholar 

  24. Y.-B. Kang, M.-S. Kim, S.-W. Lee, J.-W. Cho, M.-S. Park, and H.-G. Lee: Metall. Mater. Trans. B, 2013, vol. 44B, pp. 309–316.

    Article  Google Scholar 

  25. M.-S. Kim and Y.-B. Kang: Calphad, 2018, vol. 61, pp. 105–115.

    Article  CAS  Google Scholar 

  26. J. Li, B. Kong, L. Jiang, D. Jia, S. Ren, J. Yang, Q. Liu, Q. Shu, and K. Chou: High Temp. Mater. Process., 2018, vol. 37, pp. 981–985.

    Article  CAS  Google Scholar 

  27. J. Yang, J. Zhang, O. Ostrovski, C. Zhang, and D. Cai: Metall. Italiana, vol. 1, 2019, pp. 12–19.

    Google Scholar 

  28. T.-I. Chung, J.-W. Cho, and Y.-B. Kang: Metall. Mater. Trans. B, 2016, vol. 47B, pp. 779–787.

    Article  Google Scholar 

  29. C. W. Bale, E. Bélisle, P. Chartrand, S. A. Decterov, G. Eriksson, A. E. Gheribi, K. Hack, I. H. Jung, Y. B. Kang, J. Melançon, A. D. Pelton, S. Petersen, C. Robelin, J. Sangster, P. Spencer, and M.-A. Van Ende: Calphad, 2016, vol. 54, pp. 35–53.

    Article  CAS  Google Scholar 

  30. W.-Y. Kim, A.D. Pelton, and S. Decterov: Int. J. Mat. Res., 2012, vol. 103, pp. 313–328.

    Article  CAS  Google Scholar 

  31. K. C. Mills and C.-Å. Däcker: in The Casting Powders Book, Springer, Cham, pp. 19–58, 2017.

    Book  Google Scholar 

  32. L. T. Hoai and J. Lee: J. Mater. Sci., 2012, vol. 47, pp. 8303–8307.

    Article  CAS  Google Scholar 

Download references

This research was financially supported by POSCO, Republic of Korea.

Author information

Authors and Affiliations

  1. Graduate Institute of Ferrous Technology, Pohang University of Science and Technology, Pohang, Kyungbuk, 37673, Republic of Korea

    Min-Su Kim & Youn-Bae Kang

  2. Technical Research Laboratories, POSCO, Kwangyang, Jeonnam, 57807, Republic of Korea

    Min-Seok Park

  3. Jeonbuk Regional Division, Korean Institute of Industrial Technology, Kimje, Jeonbuk, 54325, Republic of Korea

    Min-Su Kim

Authors
  1. Min-Su Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Min-Seok Park
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Youn-Bae Kang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Youn-Bae Kang.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Manuscript submitted March 26, 2019.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kim, MS., Park, MS. & Kang, YB. A Reaction Between High Mn–High Al Steel and CaO-SiO2-Type Molten Mold Flux: Reduction of Additive Oxide Components in Mold Flux by Al in Steel. Metall Mater Trans B 50, 2077–2082 (2019). https://doi.org/10.1007/s11663-019-01658-1

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11663-019-01658-1

Search

Navigation