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Morphological and Mechanical Properties of Hydroxyapatite Bilayer Coatings Deposited on 316L SS by Sol–Gel Method

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Abstract

The present paper reports on the influence of the addition of TiO2 and SiO2 oxides as sub-layer, on the morphological and mechanical properties of the hydroxyapatite (HAP) bioceramic coatings deposited on 316L stainless steel by sol–gel method in order to improve the properties of hydroxyapatite and expand its clinical application. The stability of the sols suspensions was evaluated by measuring the time dependence of the viscosity. Annealed properties of the coatings were analyzed by XPS, XRD, SEM, and EDS. The Vickers microhardness of the coatings is obtained under the same indentation load of 10 g. The hydroxyapatite coating deposited on the surface of the 316L SS substrate exhibits a porous carbonated apatitic structure. The results clearly demonstrate that HAP-TiO2 and HAP-SiO2 bilayer coatings where hydroxyapatite is deposited on the surface of TiO2- and SiO2-coated 316L SS substrate systems were highly homogeneous and uniform and show higher microhardness compared to HAP-coated 316L SS. A gap of nearly 10 pct is observed. The addition of TiO2 and SiO2 as sub-layer of a hydroxyapatite coating results in changes in surface morphology as well as an increase of the microhardness.

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Acknowledgments

The authors gratefully acknowledge the contribution of Prof. Abdelaziz Ati, from the mechanical laboratory of Bejaia for providing the mechanical experiments.

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Authors and Affiliations

  1. Laboratoire de Génie de l’Environnement, Département de Génie des Procédés, Université de Bejaia, Route Targa Ouzemour, 06000, Bejaïa, Algeria

    Djahida Sidane, Hafit Khireddine, Sabeha Yala, Salima Ziani & Fatima Bir

  2. Laboratoire de Mécanique de Lille (LML), UMR CNRS 8107, Université des Sciences et Technologie de Lille 1, IUT Le Recueil, Rue de la Recherche, BP 90179, 59653, Villeneuve d’Ascq Cedex, France

    Didier Chicot

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  1. Djahida Sidane
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  2. Hafit Khireddine
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  3. Sabeha Yala
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  4. Salima Ziani
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  5. Fatima Bir
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  6. Didier Chicot
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Correspondence to Djahida Sidane.

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Manuscript submitted January 15, 2015.

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Sidane, D., Khireddine, H., Yala, S. et al. Morphological and Mechanical Properties of Hydroxyapatite Bilayer Coatings Deposited on 316L SS by Sol–Gel Method. Metall Mater Trans B 46, 2340–2347 (2015). https://doi.org/10.1007/s11663-015-0397-8

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  • DOI: https://doi.org/10.1007/s11663-015-0397-8

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