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The surface tensions and foaming behavior of melts in the system CaO-FeO-SiO2

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Abstract

The surface tensions of melts in the system CaO-FeO-SiO2 have been measured in the temperature range 1573 to 1708 K using the hollow cylinder technique. The iron oxide content was maintained constant at 30 wt pct and the CaO/SiO2 wt pct ratio was varied in the range 0.43 to 1.5. Surface tension increases with increasing basicity and with decreasing temperature. The data were used to test published correlations of slag foaming indexes with surface tension and viscosity. Foam life increases with increasing viscosity and with decreasing surface tension.

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References

  1. P. Kozakevitch: J. Met., 1969, pp. 57–68.

  2. J.W. Gibbs: The Collected Works of J.W. Gibbs, vol. I, Thermodynamics, Yale University Press, New Haven, CT, 1948, p. 300.

    Google Scholar 

  3. W. Harkins and F. Jordan: J. Am. Chem. Soc., 1930, vol. 52, pp. 1751–72.

    Article  CAS  Google Scholar 

  4. Y. Kawai, K. Mori, H. Shiraishi, and N. Yamada: Tetsu-to-Hagané, 1976, vol. 62, pp 53–61.

    CAS  Google Scholar 

  5. P. Kozakevitch and A. Konoenko: J. Phys. Chem., 1940, vol. 14, p. 1118.

    Google Scholar 

  6. J. Swisher and C. McCabe: Trans. AIME, 1964, vol. 230, pp. 1669–75.

    CAS  Google Scholar 

  7. C. Cooper and J.A. Kitchener: J. Iron Steel Inst., 1959, vol. 193, pp. 48–51.

    CAS  Google Scholar 

  8. J.F. Elliott: W.O. Philbrook Memorial Symp. Conf. Proc., Iron and Steel Society, Warrendale, PA, 1988, pp. 3–5.

    Google Scholar 

  9. P. Bhattacharyya and D.R. Gaskell: Metall. Mater. Trans. B, 1996, vol. 27B, pp. 139–41.

    Article  CAS  Google Scholar 

  10. C. Cooper and J.A. Kitchener: J. Iron Steel Inst., 1959, vol. 193, pp. 48–59.

    CAS  Google Scholar 

  11. J. Swisher and C. McCabe: Trans. AIME, 1964, vol. 230, pp. 1669–75.

    CAS  Google Scholar 

  12. S. Hara and O. Ogino: The Reinhardt Schuhmann Int. Symp. on Innovative Technology and Reactor Design in Extraction Metallurgy, TMS-AIME, Warrendale, PA, 1986, pp. 639–47.

    Google Scholar 

  13. K. Ito and R.J. Fruehan: Metall. Trans. B, 1989, vol. 20B, pp. 509–14.

    CAS  Google Scholar 

  14. K. Ito and R.J. Fruehan: Metall. Trans. B, 1989, vol. 20B, pp. 515–21.

    CAS  Google Scholar 

  15. R. Jiang and R.J. Fruehan: Metall. Trans. B, 1991, vol. 22B, pp. 481–89.

    CAS  Google Scholar 

  16. G. Urbain, Y. Bottinga, and P. Richet: Geochim. Cosmochim. Acta, 1982, vol. 46, pp. 1061–72.

    Article  CAS  Google Scholar 

  17. P. Rontgen: Z. Erz. Metallhuttenwes., 1960, vol. 13, pp. 363–73.

    CAS  Google Scholar 

  18. Y.E. Lee and D.R. Gaskell: Metall. Trans., 1974, vol. 5, pp. 853–60.

    CAS  Google Scholar 

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This article is based on a presentation made in the “Geoffrey Belton Memorial Symposium,” held in January 2000, in Sydney, Australia, under the joint sponsorship of ISS and TMS.

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Skupien, D., Gaskell, D.R. The surface tensions and foaming behavior of melts in the system CaO-FeO-SiO2 . Metall Mater Trans B 31, 921–925 (2000). https://doi.org/10.1007/s11663-000-0068-1

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