Abstract
The microstructure and compression strengths of Ir-15 at. pct X (X=Ti, Ta, Nb, Hf, Zr, or V) binary alloys at temperatures between room temperature and 1800 °C were investigated to evaluate the potential of these alloys for ultra-high-temperature use. The fcc and L12 two-phase structures of these alloys were examined by transmission electron microscopy (TEM) and scanning electron microscopy (SEM). The strengths of the Ir-Ta, -Nb, -Hf, and -Zr alloys were above 800 MPa at temperatures up to 1200 °C and about 200 MPa at 1800 °C. The strengths of these alloys under 1000 °C are equivalent to or higher than those of the commercially used Ni-base superalloys, MAR-M247 and CMSX-10. The Nb concentration dependence of strength was investigated using a series of Ir-Nb alloys with Nb concentrations from 0 to 25 at. pct. It was found that the Ir-base alloys were strengthened by L12 precipitation hardening. The potential of the Ir-base alloys for ultra-high temperature use is discussed.
Similar content being viewed by others
References
C.T. Sims, N.S. Stoloff, and W.C. Hagel: Superalloys II, John Wiley & Sons, New York, NY, 1987, pp. 13 and 551.
H. Harada, T. Yamagata, Y. Yokokawa, K. Ohno, and M. Yamazaki: Proc. 5th Int. Conf. on Creep and Fracture of Engineering Materials and Structures, B. Wilshire and R.W. Evans, eds., The Institute of Materials, Swansea, United Kingdom, 1993, pp. 255–64.
D.B. Miracle and R. Darolia: Intermetallic Compounds Principles and Practice, J.H. Westbrook and R.L. Fleischer, eds., John Wiley & Sons, New York, NY, 1995, vol. 2, pp. 53–72.
W.F. Brown, Jr., H. Mindin, and C.Y. Ho: Aerospace Structural Metals Handbook, CINDAS/Purdue University, Weat Latayette, IN, 1992, vol. 5, pp. 4218 and 5502.
T. Yamagata: Proc. 5th Symp. on High-Performance Materials for Severe Environments, RIMCOF, Tokyo, Japan, 1994, pp. 107–14.
R.L. Fleischer: Platinum Met. Rev., 1992, vol. 36 (3), pp. 138–45.
A.M. Gyurko and J.M. Sanchez: Mater. Sci. Eng., 1993, vol. A170, pp. 169–75.
Y. Yamabe, Y. Koizumi, H. Murakami, Y. Ro, T. Maruko, and H. Harada: Scripta Metall. Mater., 1996, vol. 35, pp. 211–15.
Y. Yamabe-Mitarai, Y. Koizumi, H. Murakami, Y. Ro, T. Maruko, and H. Harada: Scripta Metall Mater., 1997, vol. 36, pp. 393–98.
Y. Ro, Y. Koizumi, and H. Harada: Mater. Sci. Eng., 1997, vol. A223, pp. 59–63.
International Tables of Selected Constants 16, Metals, Thermal and Mechanical Data.
Binary Alloy Phase Diagrams, T.B. Massalski, ed., ASM INTERNATIONAL, Materials Park, OH, 1992, pp. 2082, 2330, 2355, 2361, and 2366.
P. Beardmore, R.G. Davies, and T.L. Johnson: TMS-AIME, 1969, vol. 245, pp. 1537–45.
G.L. Elickson: Superalloys 1996, R.D. Kissinger, D.J. Deye, D.L. Anton, A.D. Cetel, M.V. Nathal, T.M. Pollock, and D.A. Woodford, eds., TMS, Warrendale, PA, 1996, pp. 35–44.
D.A. Porter and K.E. Easterling: Phase Transformations in Metals and Alloys, Chapman & Hall, London, 1992, pp. 149–60.
A.E. Dwight and P.A. Beck: TMS-AIME, 1959, vol. 215 pp. 976–79.
M.E. Thompson, C.S. Su, and P.W. Voorhees: Acta Metall. Mater, 1994, vol. 42 (6), pp. 2107–22.
H. Harada, M. Yamazaki, Y. Koizumi, N. Sakuma, N. Fukuya, and H. Kamiya: Proc. High Temperature Alloys for Gas Turbines, R. Brunetaund, D. Coutsouradis, T.B. Gibbons, Y. Lindblom, D.B. Meadowcroft, and R. Stickler, eds., D. Reidel Publishing Company, Liege, Belgium, 1982, pp. 721–35.
H. Harada, K. Ohno, T. Yamagata, T. Yokokawa, and M. Yamazaki: Superalloys 1988, S. Reichman, D.N. Duhl, G. Maurer, S. Antolovich, and C. Lund, eds., TMS, Warrendale, PA, 1988, pp. 733–42.
T. Yokokawa, K. Ohno, H. Murakami, T. Kobayashi, T. Yamagata, and H. Harada: Adv. X-ray Analy., 1995, vol. 39, pp. 449–56.
D.D. Pearson, F.D. Lemkey, and B.H. Kear: Superalloys 1980, J.K. Tien, S.T. Wlodek, H. Morrow III, M. Gell, and G.E. Maurer, eds., ASM, Metals Park, OH, 1980, pp. 513–19.
J.K. Tien and R.P. Gamble: Metall. Trans., 1972, vol. 3, pp. 2157–62.
P.H. Thornton and R.G. Davies: Metall. Trans., 1970, vol. 1, pp. 549–50.
S. Takeuchi and E. Kuramoto: J. Phys. Soc. Jpn., 1971, vol. 31, p. 1282.
E.M. Schulman and J.A. Roy: Acta Metall., 1978, vol. 26, pp. 29–37.
J.W. Guard and J.H. Westbrook: TMS-AIME, 1959, vol. 215, pp. 807–14.
D.-M. Wee, O. Noguchi, Y. Oya, and T. Suzuki: Trans. JIM, 1980, vol. 21, pp. 237–47.
S.M. Brummer, J.L. Birmhall, and C.H. Hengager, Jr.: Mater. Res. Soc. Symp. Proc., D.L. Anton, P.L. Martin, D.B. Miracle, and R. McMeeking, eds., MRS, Pittsburgh, PA, 1990, vol. 194, pp. 257–62.
Metals Reference Book, 5th ed., C.J. Smithells, ed., Butterworth and Co., London, 1976, p. 942.
ASM Metals Reference Book, W.H. Cubberly, ed., ASM, Metals Park, OH, 1983.
High Temperature High Strength Nickel Base Alloys, The International Nickel Company, Inc., 1977, p. 8.
D.E. Harasyn, R.L. Heestand, and C.T. Liu: Mater. Sci. Eng., 1994, vol. A187, pp. 138–45.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Yamabe-Mitarai, Y., Ro, Y., Harada, H. et al. Ir-base refractory superalloys for ultra-high temperatures. Metall Mater Trans A 29, 537–549 (1998). https://doi.org/10.1007/s11661-998-0135-9
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11661-998-0135-9