Abstract
In this study, the alloying and phase separation behaviors of AlCoCrFeNi-based high-entropy alloys (HEAs) were investigated. The valence electron concentration (VEC) of the AlCoCrFeNi HEA was modified by adding specific elements (Mg, Ti, Mn, Cu, and Zn) to produce biphasic HEAs. These HEAs were prepared by mechanical alloying for 30 hours, followed by the consolidation of the powders at 1000 °C. The results demonstrated the formation of a body-centered cubic (ordered BCC/B2) phase in AlCoCrFeNi–Mg and AlCoCrFeNi–Ti, while a dual-phase face-centered cubic (FCC) phase and minor BCC phases were observed in AlCoCrFeNi–Cu and AlCoCrFeNi–Zn. AlCoCrFeNi and AlCoCrFeNi–Mn exhibited the precipitation of a σ phase in the BCC matrix and a minor FCC phase. The AlCoCrFeNi–Mn HEA exhibited the highest compressive strength among itself, AlCoCrFeNi–Cu, and AlCoCrFeNi–Zn HEAs, owing to the precipitation of a harder σ phase and a higher ordered BCC/B2 fraction. In addition, the AlCoCrFeNi–Cu and AlCoCrFeNi–Zn HEAs exhibited the maximum fracture strain and absorption energies. We propose that a controlled VEC approach by the addition of suitable elements can be used to tailor the microstructure and phase stability of AlCoCrFeNi HEAs.
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References
S. Ranganathan: Curr. Sci., 2003, vol. 85, pp. 1404–06.
B. Cantor, I.T.H. Chang, P. Knight, and A.J.B. Vincent: Mater. Sci. Eng. A., 2004, vol. 375–377, pp. 213–18.
Y. Zhang, T.T. Zuo, Z. Tang, M.C. Gao, K.A. Dahmen, and P.K. Liaw: Prog. Mater. Sci., 2014, vol. 61, pp. 1–93.
Y. Zhang, X. Yang, and P.K. Liaw: JOM., 2012, vol. 64, pp. 830–38.
D.B. Miracle, J.D. Miller, O.N. Senkov, C. Woodward, and M.D. Uchic: Entropy., 2014, vol. 16, pp. 494–525.
X. Liu, Z. Pei, and M. Eisenbach: Mater. Des., 2019, vol. 180, p. 107955.
T. Yang, C. Lu, G. Velisa, K. Jin, P. Xiu, Y. Zhang, H. Bei, and L. Wang: Scr. Mater., 2019, vol. 15, pp. 57–61.
Y.P. Wang, B.S. Li, M.X. Ren, C. Yang, and H.Z. Fu: Mater. Sci. Eng. A., 2008, vol. 491, pp. 154–58.
S.W. Xin, M. Zhang, T.T. Yang, Y.Y. Zhao, B.R. Sun, and T.D. Shen: J. Alloys Compd., 2018, vol. 769, pp. 597–604.
Z.D. Han, N. Chen, S.F. Zhao, L.W. Fan, G.N. Yang, Y. Shao, and K.F. Yao: Intermetallics., 2017, vol. 84, pp. 153–57.
S.Y. Chen, Y. Tong, K.K. Tseng, J.W. Yeh, J.D. Poplawsky, J.G. Wen, M.C. Gao, G. Kim, W. Chen, Y. Ren, R. Feng, W.D. Li, and P.K. Liaw: Scr. Mater., 2019, vol. 158, pp. 50–56.
Y. Cao, Y. Liu, Y. Li, B. Liu, J. Wang, M. Du, and R. Liu: Mater. Lett., 2019, vol. 246, pp. 186–89.
J.M. Zhu, J.L. Meng, and J.L. Liang: Rare Met., 2016, vol. 35, pp. 385–89.
C.J. Tong, Y.L. Chen, S.K. Chen, J.W. Yeh, T.T. Shun, C.H. Tsau, S.J. Lin, and S.Y. Chang: Metall. Mater. Trans. A., 2005, vol. 36A, pp. 881–93.
S. Praveen, B.S. Murty, and R.S. Kottada: Mater. Sci. Eng. A., 2012, vol. 534, pp. 83–89.
Y. Yin, J. Zhang, Q. Tan, W. Zhuang, N. Mo, M. Bermingham, and M.X. Zhang: Mater. Des., 2019, vol. 16, pp. 24–33.
C. Xiang, H.M. Fu, Z.M. Zhang, E.H. Han, H.F. Zhang, J.Q. Wang, and G.D. Hu: J. Alloys Compd., 2020, vol. 818, p. 153352.
X. Yao, J. Wei, and T. Li: IOP Conf. Ser. Mater. Sci. Eng., 2019, vol. 585, p. 012019.
N.D. Stepanov, D.G. Shaysultanov, G.A. Salishchev, M.A. Tikhonovsky, E.E. Oleynik, A.S. Tortika, and O.N. Senkov: J Alloys Compd., 2015, vol. 628, pp. 170–85.
B.S. Li, Y.P. Wang, M.X. Ren, C. Yang, and H.Z. Fu: Mater. Sci. Eng. A., 2008, vol. 498, pp. 482–86.
Y. Han, T. Wang, and S. Zhou: Mater. Sci. Forum., 2010, vol. 650, pp. 265–71.
Y.J. Zhao, J.W. Qiao, S.G. Ma, M.C. Gao, H.J. Yang, M.W. Chen, and Y. Zhang: Mater. Des., 2016, vol. 96, pp. 10–15.
A. Sharma, M.C. Oh, and B. Ahn: Mater. Sci. Eng. A., 2020, vol. 797, p. 140066.
M. Liu, W. Xu, S. Zhang, Z. Wang, Z. Wang, B. Wang, D. Wang, and F. Li: J. Alloys Compd., 2020, vol. 824, p. 153881.
Q. Tian, G. Zhang, K. Yin, L. Wang, W. Wang, W. Cheng, Y. Wang, and J.C. Huang: Intermetallics., 2020, vol. 119, p. 106707.
Q. Tian, G. Zhang, K. Yin, W. Wang, W. Cheng, and Y. Wang: Mater. Charact., 2019, vol. 151, pp. 302–09.
K.C. Cheng, J.H. Chen, S. Stadler, and S.H. Chen: Appl. Surf. Sci., 2019, vol. 478, pp. 478–86.
X. Xian, Z. Zhong, B. Zhang, K. Song, C. Chen, S. Wang, J. Cheng, and Y. Wu: Mater. Des., 2017, vol. 121, pp. 229–36.
Y. Yu, J. Wang, J. Li, H. Kou, and W. Liu: Mater. Lett., 2015, vol. 138, pp. 78–80.
S. Guo, C. Ng, J. Lu, and C.T. Liu: J. Appl. Phys., 2011, vol. 109, p. 103505.
M.H. Tsai, K.C. Chang, J.H. Li, R.C. Tsai, and A.H. Cheng: Mater. Res. Lett., 2016, vol. 4, pp. 90–95.
W.R. Wang, W.L. Wang, S.C. Wang, Y.C. Tsai, C.H. Lai, and J.W. Yeh: Intermetallics., 2012, vol. 26, pp. 44–51.
J.M. Torralba, P. Alvaredo, and A.G. Junceda: Powder Met., 2019, vol. 62, pp. 84–114.
K.M. Youssef, A.J. Zaddach, C. Niu, D.L. Irving, and C.C. Koch: Mater. Res. Lett., 2015, vol. 3(2), pp. 95–99.
M.J. Chae, A. Sharma, M.C. Oh, and B. Ahn: Met. Mater. Int., 2020, vol. 27, pp. 629–38.
B. Ren, Z. Liu, B. Cai, M. Wang, and L. Shi: Mater. Des., 2012, vol. 33, pp. 121–26.
A. Shabani, M.R. Toroghinejad, A. Shafyei, and R.E. Loge: J. Mater. Eng. Perform., 2019, vol. 33, pp. 2388–98.
A. Manzoni, H. Daoud, R.V. Olkl, U. Glatzel, and N. Wanderka: Ultramicroscopy., 2013, vol. 132, pp. 212–15.
F. He, Z. Wang, Q. Wu, J. Li, J. Wang, and C.T. Liu: Scr. Mater., 2017, vol. 126, pp. 15–19.
Y.J. Zhou, Y. Zhang, Y.L. Wang, and G.L. Chen: Appl. Phys. Lett., 2007, vol. 90, p. 181904.
Y.J. Chang, C.W. Tsai, A.C. Yeh, and J.W. Yeh: Metall. Mater. Trans. A., 2014, vol. 45A, pp. 184–90.
Y. Zhang, H. Wu, X. Yu, D. Tang, R. Yuan, and H. Sun: J. Mater. Res. Technol., 2021, vol. 12, pp. 2114–27.
W. Fang, R. Chang, X. Zhang, P. Ji, X. Wang, B. Liu, J. Li, X. He, X. Qu, and F. Yin: Mater. Sci. Eng. A., 2018, vol. 723, pp. 221–28.
S. Hori, H. Tai, and E. Matsumoto: J. Jpn. Inst. Light Met., 1987, vol. 34(7), p. 377.
J. Lin, M. Huang, W. Yang, and L. Xing: Sci. Rep., 2018, vol. 8, p. 15190.
P. Wang, H. Cai, S. Zhou, and L. Xu: J. Alloys Compd., 2017, vol. 695, pp. 462–75.
B. Gwalani, R.M. Pohan, J. Lee, B. Lee, R. Banerjee, H.J. Ryu, and S.H. Hong: Sci. Rep., 2018, vol. 9, p. 14085.
A. Kumar, A.K. Swarnakar, A. Basu, and M. Chopkar: J. Alloys Compd., 2018, vol. 748, pp. 889–97.
P. Yang, Y. Liu, X. Zhao, J. Cheng, and H. Li: Adv. Powder Technol., 2016, vol. 27, pp. 1128–33.
K.G. Pradeep, N. Wanderka, P. Choi, J. Banhart, B.S. Murty, and D. Raabe: Acta Mater., 2013, vol. 61, pp. 4696–4706.
Z. Cai, X. Cui, G. Jin, Z. Liu, Y. Li, and M. Dong: Micron., 2017, vol. 103, pp. 84–89.
S.A. Kube, S. Sohn, D. Uhl, A. Datye, A. Mehta, and J. Schroers: Acta Mater., 2019, vol. 166, pp. 677–86.
Ł Rogal, Z. Szklarz, P. Bobrowski, D. Kalita, G. Garzeł, A. Tarasek, M. Kot, and M. Szlezynger: Met. Mater. Int., 2019, vol. 25, pp. 930–45.
M.V. Klimova, D.G. Shaysultanov, S.V. Zherebtsov, and N.D. Stepanov: Mater. Sci. Eng. A., 2019, vol. 748, pp. 228–35.
G. Hillel, L. Natovitz, S. Salhov, S. Haroush, M. Pinkas, and L. Meshi: Metals., 2020, vol. 10, p. 1275.
Y. Qiu, S. Thomas, D. Fabijanic, A.J. Barlow, H.L. Fraser, and N. Birbilis: Mater. Des., 2019, vol. 170, p. 107698.
H. Liu, J. Liu, P. Chen, H. Yang, J. Hao, and X. Tian: J. Mater. Eng. Perform., 2019, vol. 28, pp. 1544–52.
S. Guo and C.T. Liu: Prog. Nat. Sci., 2011, vol. 21, pp. 433–46.
N.G. Jones, R. Izzo, P.M. Mignanelli, K.A. Christofidou, and H.J. Stone: Intermetallics., 2016, vol. 71, pp. 43–50.
K.K. Alaneme, M.O. Bodunrin, and S.R. Oke: J. Mater. Res. Technol., 2016, vol. 5, pp. 384–93.
C.T. Liu: Int. Mater. Rev., 1984, vol. 29, pp. 168–94.
M. Heczko, V. Mazánová, R. Gröger, T. Záležák, M.S. Hooshmand, E.P. George, M.J. Mills, and A. Dlouhý: Acta Mater., 2021, vol. 208, p. 116719.
Y. Yu, P. Shi, K. Feng, J. Liu, J. Cheng, Z. Qiao, J. Yang, J. Li, and W. Liu: Acta Metall. Sin. Engl., 2020, vol. 33, pp. 1077–90.
D.J. Dingley and S.I. Wright: J. Appl. Crystallogr., 2009, vol. 42, pp. 234–41.
G. Laplanche, S. Berglund, C. Reinhart, A. Kostka, F. Fox, and E.P. George: Acta Mater., 2018, vol. 161, pp. 338–51.
A. Zhang, J. Han, J. Meng, B. Su, and P. Li: Mater. Lett., 2016, vol. 181, pp. 82–85.
T. Nagase, A. Shibata, M. Matsumuro, M. Takemura, and S. Semboshi: Mater. Des., 2019, vol. 181, p. 107900.
L. Wei, X. Liu, Y. Gao, X. Peng, N. Hu, and M. Che: Intermetallics., 2021, vol. 138, p. 107310.
M. Oh, A. Sharma, H. Lee, and B. Ahn: Intermetallics., 2021, vol. 139, p. 107369.
Y. Zhang, Y. Ai, W. Chen, and S. Ouyang: J. Alloys Compd., 2022, vol. 900, p. 163352.
Acknowledgments
This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean Government (MSIT) (No. 2021R1A2C1005478), (No. 2021R1F1A1062039), (No. 2021R1A4A1031357).
Author Contributions
MCO: conceptualization, methodology, validation, investigation, formal analysis, resources, writing–original draft, writing–review & editing. AS: investigation, resources, data curation, writing–review & editing, visualization, funding acquisition. HL: investigation, data curation, writing–original draft, writing–review & editing. BA: conceptualization, methodology, writing–review & editing, supervision, project administration, funding acquisition.
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The authors declare that they have no known competing financial interests or personal relationships that could have influenced the work reported in this paper.
Funding
This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korean Government (MSIT) (No. 2021R1A2C1005478), (No. 2021R1F1A1062039), (No. 2021R1A4A1031357).
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Oh, M.C., Lee, H., Sharma, A. et al. Controlled Valence Electron Concentration Approach to Tailor the Microstructure and Phase Stability of an Entropy-Enhanced AlCoCrFeNi Alloy. Metall Mater Trans A 53, 1831–1844 (2022). https://doi.org/10.1007/s11661-022-06637-x
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DOI: https://doi.org/10.1007/s11661-022-06637-x