Abstract
The isothermal transformation kinetics of austenite decomposition in Fe-0.4C-2.78Mn-1.81Si was analyzed by an electrical resistivity technique in the temperature interval 723 K to 418 K (450 °C to 145 °C). The analysis of transformation kinetics of the bainite transformation was performed using the Johnson–Mehl–Avrami–Kolgomorov (JMAK) and Austin–Rickett (AR) approaches. The kinetic parameters, the reaction constant n, rate constant k = k(T), and apparent activation energy Q were evaluated for isothermal transformations below and above the martensite-start temperature M S = 548 K (275 °C), which was determined experimentally. The formation of strain-induced martensite, which starts to accompany the bainite transformation at just above M S , increases the rate of transformation and decreases the apparent activation energy of austenite decomposition.
Similar content being viewed by others
Notes
This term is in current use within the metallurgical community; it refers to a structure that is similar to true bainite, but which contains no carbides.
References
H.K.D.H. Bhadeshia and D.V. Edmonds: Met. Sci., 1983, vol. 17, pp. 411–20.
F.G. Caballero and H.K.D.H. Bhadeshia: Curr. Opin. Solid State Mater. Sci., 2004, vol. 8, pp. 251–57.
O.N. Mohanaty and A.N. Bhagat: Mat.-wiss. Werkstofftech., 2003, vol. 34, pp. 96–101.
S.V. Radcliffe and E.C. Rollason: J. Iron Steel Inst., 1959, vol. 191, pp. 56–65.
P.W. Brown and D. Mack: Metall. Trans., 1973, vol. 4, pp. 2639–43.
O. Schaaber: Trans. AIME, 1955, vol. 203, pp. 559–60.
R.T. Howard and M. Cohen: Trans. AIME, 1949, vol. 176, pp. 384–97.
M.F. Smith, G.R. Speich, and M. Cohen: Trans. TMS AIME, 1959, vol. 215, pp. 528–30.
N.F. Kennon and R.T. Edwards: J. Aust. Inst. Met., 1970, vol. 15, pp. 195–200.
T.Z. Wozniak: Mater. Charact., 2008, vol. 59, pp. 708–16.
M. Oka and H. Okamoto: Metall. Trans. A, 1985, vol. 19A, pp. 447–52.
L.C. Chang: Mater. Sci. Eng., 2004, vol. A368, pp. 175–82.
G.R. Purdy and M. Hillert: Acta Metall., 1984, vol. 32, pp. 823–28.
H.K.D.H. Bhadeshia and D.V. Edmonds: Metall. Trans. A, 1979, vol. 10A, pp. 895–907.
G.R. Speich and M. Cohen: Trans. TMS-AIME, 1960, vol. 218, pp. 1050–59.
M.J. Hawkins and J. Barford: Scripta Mater., 1970, vol. 4, pp. 583–88.
H.K.D.H. Bhadeshia: J. Phys., 1982, Coll. C4, Suppl. 12, pp. C4-443–C4-448.
M. Umemo, K.H. Uchi, and I. Tamura: Trans. ISIJ, 1982, vol. 22, pp. 854–61.
D. Quidort and Y.J.M. Brechet: ISIJ Int., 2002, vol. 42 (9), pp. 1010–17.
J.W. Elmer, T.A. Palmer, S.S. Babu, W. Zhang, and T. DebRoy: Weld. J., 2004, Sept., pp. 244–53.
S.M.C. van Bohemen, M.J. Santofimia, and J. Sietsma: Scripta Mater., 2008, vol. 58, pp. 488–91.
N.V. Luzginova, L. Zhao, and J. Sietsma: Mater. Sci. Eng., 2008, vols. A481–482, pp. 766–69.
M. Niewczas, Z.S. Basinski, S.J. Basinski, and J.D. Embury: Phil. Mag., 2001, vol. 81A, pp. 1121–38.
General Area Detector Diffraction System (GADDS), Version 4.0, User’s Manual, Bruker AXS Inc., Madison, WI, 1999.
K.W. Andrews: JISI, 1965, vol. 203, pp. 721–27.
D.J. Dyson and B. Holmes: JISI, 1970, vol. 208, pp. 469–74.
I.S. Servi and D. Turnbull: Acta Metall., 1966, vol. 14, pp. 161–69.
E.-S. Lee and Y.G. Kim: Acta Metall. Mater., 1990, vol. 38, pp. 1669–76.
W.A. Johnson and K.E. Mehl: Trans. Am. Inst. Min. Met. Enf., 1939, vol. 195, pp. 416–58.
M. Avrami: J. Chem. Phys., 1941, vol. 9, pp. 177–84.
M. Avrami: J. Chem. Phys., 1939, vol. 7, pp. 1103–12.
M. Avrami: J. Chem. Phys., 1940, vol. 8, pp. 212–24.
A.N. Kolgomorov: Izv. Akad. Nauk SSSR, Ser. Mater., 1937, vol. 1, pp. 355–59.
J.B. Austin and R.L. Rickett: Trans. Am. Inst. Eng., 1939, vol. 135, pp. 396–415.
G.B. Olson and M. Cohen: J. Less-Common Met., 1972, vol. 28, pp. 107–18.
G. Ghosh and G.B. Olson: Acta Metall. Mater., 1994, vol. 42, pp. 3361–70.
E. Swallow and H.K.D.H. Bhadeshia: Mater. Sci. Technol., 1996, vol. 12, pp. 121–25.
J.W. Christian: Theory of Phase Transformation in Metals and Alloys, Pergamon Press, Oxford, United Kingdom, 2004, pp. 529–46.
M. Hillert: Acta Metall., 1959, vol. 7, pp. 653–58.
G.V. Kurdjumov and O.P. Maksimova: Dokl. Akad. Nauk SSSR, 1948, vol. 61, pp. 83–93.
G.V. Kurdjumov and O.P. Maksimova: Dokl. Akad. Nauk SSSR, 1950, vol. 73, pp. 95–98.
S.R. Pati and M. Cohen: Acta Metall., 1971, vol. 19, pp. 1327–32.
C.T. Peters, P. Bolton, and A.P. Miodownik: Acta Metall., 1972, vol. 20, pp. 881–86.
S.K. Gupta and V. Raghavan: Acta Metall., 1975, vol. 23, pp. 1239–45.
C. Wells, W. Barz, and R.F. Mehl: Trans. AIME, 1950, vol. 188, pp. 553–60.
H. Sueyoshi and K. Suenaga: J. Jpn. Inst. Met., 1987, vol. 51, pp. 518–24.
U. Bohnenkamp, R. Sandstrom, and G. Grimvall: J. Appl. Phys., 2002, vol. 92, pp. 4402–07.
Acknowledgments
This research was supported by the Natural Sciences and Engineering Research Council of Canada. The authors are grateful to Drs. M. Niewczas and J. Britten for access to the ER equipment and for the XRD measurements, respectively.
Author information
Authors and Affiliations
Corresponding author
Additional information
Manuscript submitted January 13, 2011.
Rights and permissions
About this article
Cite this article
Yakubtsov, I.A., Purdy, G.R. Analyses of Transformation Kinetics of Carbide-Free Bainite Above and Below the Athermal Martensite-Start Temperature. Metall Mater Trans A 43, 437–446 (2012). https://doi.org/10.1007/s11661-011-0911-9
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11661-011-0911-9