Abstract
The formation of conventional metal-matrix composites reinforced with carbon nanotubes (CNTs) has proven difficult because of the agglomeration and inability of CNTs to disperse. We have explored the explosive consolidation of 150-μm aluminum powder/multiwalled carbon nanotube (MWCNT) aggregates (including multiconcentric fullerenes) at volume percentages of 2 and 5 pct. These consolidated mixtures formed two-phase, monolithic systems (TPSs) with the MWCNT aggregate material spreading along the Al grains and forming carbon phases mainly at the Al particle triple points. The Al powder particle (or grain) hardness increased from HRE 22 to HRE 40 for the consolidated Al, while the two-phase system hardness dropped from HRE 40 to HRE 39 and 33, respectively, for 2 and 5 vol pct MWCNT aggregate additions. Transmission electron microscopy (TEM) and scanning electron microscopy (SEM) observations illustrate a laminate-like structure of the consolidated MWCNT aggregate material, which is easily delaminated, causing intergranular (Al) failure. The Al grains exhibited a shock-induced dislocation substructure (0.5 to 3 μm) and recrystallized subgrains, which increased the individual particle/grain Vickers hardness from 24 to 43 HV.
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Acknowledgments
The authors express their appreciation to Rodrigo Rios-Rodriguez and Alejandro Loya-Puga, Universidad Autónoma de Ciudad Juárez (UACJ), Manufacturing Engineering Laboratories; Frank Medina and Hector Sandoval, UTEP W.M. Keck Lab.; Tony Zimmerly and Kevin Dziegiel, New Mexico Tech, EMRTC; and Drs. John McClure and Luis Trueba, Metallurgical and Materials Engineering Department, UTEP. This research is supported by a CONACYT-PROMEP (Mexico) Fellowship and a Mr. and Mrs. MacIntosh Murchison Endowment at UTEP.
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This article is based on a presentation made in the symposium entitled “Dynamic Behavior of Materials,” which occurred during the TMS Annual Meeting and Exhibition, February 25–March 1, 2007 in Orlando, Florida, under the auspices of The Minerals, Metals and Materials Society, TMS Structural Materials Division, and TMS/ASM Mechanical Behavior of Materials Committee.
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Salas, W., Alba-Baena, N. & Murr, L. Explosive Shock-Wave Consolidation of Aluminum Powder/Carbon Nanotube Aggregate Mixtures: Optical and Electron Metallography. Metall Mater Trans A 38, 2928–2935 (2007). https://doi.org/10.1007/s11661-007-9336-x
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DOI: https://doi.org/10.1007/s11661-007-9336-x