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Ribbon-like Cu doped V6O13 as cathode material for high-performance lithium ion batteries

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Abstract

Ribbon-like Cu doped V6O13 was synthesized via a simple solvothermal approach followed by heat treatment in air. As an cathode material for lithium ion battery, the ribbon-like Cu doped V6O13 electrode exhibited good capacity retention with a reversible capacity of over 313 mAh·g−1 for up to 50 cycles at 0.1 C, as well as a high charge capacity of 306 mAh·g−1 at a high current rate of 1 C, in comparison to undoped V6O13 electrode (267 mAh·g−1 at 0.1C and 273 mAh·g−1 at 1 C). The high rate capability and better cycleability of the doped electrode can be attributed to the influence of the Cu ions on the mophology and the electronic conductivity of V6O13 during the lithiation and delithiation process.

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Authors and Affiliations

  1. Guangxi Key Laboratory of New Energy and Building Energy Saving, Guilin University of Technology, Guilin, 541004, China

    Jinyun He  (何金云)

  2. Key Laboratory of Nonferrous Materials and New Processing Technology, Ministry of Education, Guilin University of Technology, Guilin, 541004, China

    Fei Long  (龙飞), Daijiang Peng, Xiaoli Wu, Shuyi Mo & Zhengguang Zou

Authors
  1. Jinyun He  (何金云)
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  2. Fei Long  (龙飞)
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  3. Daijiang Peng
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  4. Xiaoli Wu
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  5. Shuyi Mo
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  6. Zhengguang Zou
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Corresponding author

Correspondence to Fei Long  (龙飞).

Additional information

Funded by the Program for New Century Excellent Talents in University of Ministry of Education, (No.NCET-12-0655) and the Guangxi Natural Science Foundation (No.2014GXNSFFA118004)

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He, J., Long, F., Peng, D. et al. Ribbon-like Cu doped V6O13 as cathode material for high-performance lithium ion batteries. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 32, 1397–1401 (2017). https://doi.org/10.1007/s11595-017-1759-7

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  • DOI: https://doi.org/10.1007/s11595-017-1759-7

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