Abstract
Graphene was produced via a soft chemistry synthetic route for lithium ion battery applications. The sample was characterized by X-ray diffraction, nitrogen adsorption-desorption, field emission scanning electron microscopy and transmission electron microscopy, respectively. The electrochemical performances of graphene as anode material were measured by cyclic voltammetry and galvanostatic charge/discharge cycling. The experimental results showed that the graphene possessed a thin wrinkled paper-like morphology and large specific surface area (342 m2·g−1). The first reversible specific capacity of the graphene was as high as 905 mA·h·g−1 at a current density of 100 mA·g−1. Even at a high current density of 1000 or 2000 mA·g−1, the graphene maintained good cycling stability, indicating that it is a promising anode material for high-performance lithium ion batteries.
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References
Shi JY, Yi CW, Kim K. Improved Electrochemical Performance of AlPO4-coated LiMn1.5Ni0.5O4 Electrode for Lithium-Ion Batteries [J]. Journal of Power Sources, 2010, 195:6 860–6 866
Wang XY, Zhou XF, Yao K, et al. A SnO2/Graphene Composite as a High Stability Electrode for Lithium Ion Batteries[J]. Carbon, 2011, 49: 133–139
Chan CK, Peng HL, Liu G, et al. High-Performance Lithium Battery Anodes Using Silicon Nanowires[J]. Nature Nanotechnology, 2008, 3: 31–35
Wang C, Zhou Y, Ge M Y, et al. Large-Scale Synthesis of SnO2 Nanosheets with High Lithium Storage Capacity [J]. J. Am. Chem. Soc., 2010, 132: 46–47
Lou XW, Wang Y, Yuan CL, et al. Template-Free Synthesis of SnO2 Hollow Nanostructures with High Lithium Storage Capacity[J]. Adv. Mater., 2006, 18(17): 2 325–2 329
Chen J, Xu LN, Li WY, et al. α-Fe2O3 Nanotubes in Gas Sensor and Lithium-Ion Battery Applications [J]. Adv. Mater., 2005, 17: 582–586
Reddy MV, Yu T, Sow CH. α-Fe2O3 Nanoflakes as an Anode Material for Li-Ion Batteries [J]. Adv. Funct.Mater., 2007, 17: 2 792–2 799
Cui ZM, Hang LY, Song WG, et al. High-yield Gas-liquid Interfacial Synthesis of Highly Dispersed Fe3O4 Nanocrystals and Their Application in Lithium-Ion Batteries [J]. Chem. Mater., 2009, 21(6): 1 162–1 166
Li YG, Tan B, Wu YY. Mesoporous Co3O4 Nanowire Arrays for Lithium Ion Batteries with High Capacity and Rate Capability [J]. Nano Lett., 2008, 8(1): 265–270
Cai Y, Liu S, Yin XM, et al. Facile Preparation of Porous One-Dimensional Mn2O3 Nanostructures and Their Application as Anode Materials for Lithium-Ion Batteries [J]. Physica E: Low-dimensional Systems and Nanostructures, 2010, 43(1): 70–75
Wang HB, Pan QM, Cheng YX, et al. Evaluation of ZnO Nanorod Arrays with Dandelion-Like Morphology as Negative Electrodes for Lithium-Ion Batteries [J]. Electrochimica Acta, 2009, 54: 2 851–2 855
Yang SB, Cui GL, Pang SP, et al. Fabrication of Cobalt and Cobalt Oxide/Graphene Composites: Towards High-Performance Anode Materials for Lithium Ion Batteries[J]. Chem Sus Chem., 2010, 3: 236–239
Geim AK, Novoselov KS. The Rise of Graphene [J]. Nature Materials, 2007, 6: 183–191
Guo P, Song HH, Chen XH, et al. Electrochemical Performance of Graphene Nanosheets as Anode Material for Lithium-Ion Batteries [J]. Electrochemistry Communications, 2009, 11: 1 320–1 324
Yoo EJ, Kim J, Hosono E, Zhou HS, et al. Large Reversible Li Storage of Graphene Nanosheet Families for Use in Rechargeable Lithium Ion Batteries [J]. Nano Lett., 2008, 8(8): 2 277–2 282
Hummers W, Offman R. Preparation of Graphitic Oxide [J]. J. Am. Chem. Soc., 1958, 80: 1339
Tang LH, Wang Y, Li YM, et al. Preparation, Structure, and Electrochemical Properties of Reduced Graphene Sheet Films [J]. Adv. Funct. Mater., 2009, 19: 2 782–2 789
Stankovich S, Dikin D A, Dommett G H B, et al. Graphene-based Composite Materials [J]. Nature, 2006, 442: 282–286
Paek SM, Yoo EJ, Honma I. Enhanced Cyclic Performance and Lithium Storage Capacity of SnO2/Graphene Nanoporous Electrodes with Three-Dimensionally Delaminated Flexible Structure[J]. Nano Lett., 2009, 9(1): 72–75
Yao J, Shen XP, Wang B, et al. In Situ Chemical Synthesis of SnO2-Graphene Nanocomposite as Anode Materials for Lithium-Ion Batteries[J]. Electrochemistry Communications, 2009, 11: 1 849–1 852
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Funded by the Chongqing University Scientific & Technological Innovation Fund for Graduates (No. CDJXS12 13 00 06)
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Liu, H., Huang, J., Li, X. et al. Graphene as a high-capacity anode material for lithium ion batteries. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 28, 220–223 (2013). https://doi.org/10.1007/s11595-013-0668-7
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DOI: https://doi.org/10.1007/s11595-013-0668-7