Abstract
Structure, crystallization and dissolution properties of CaO-MgO-SiO2 inorganic glass fiber in the presence of additives (Al2O3, Y2O3) were investigated by DTA, XRD, FTIR and ICP-AES techniques. The results show that with the addition of Al2O3 and Y2O3, the glass network structure is strengthened and the precipitation of crystals is inhibited for heat-treated fibers. Compared with Y2O3 doped fibers, Al2O3 presents more significant effects on the enhancement of silica network and the inhibition of crystallization in fibers. As for dissolution properties in physiological fluids, though the weight losses, changes of pH values and leached ions concentration lower slightly with the addition of Al2O3 and Y2O3 for the intensified network structure, and fibers still present high dissolution rates.
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References
International Agency for Research on Cancer (IARC). Monographs on the Evaluation of Carcinogenic Risk to Humans: Man-Made Vitreous Fibers [C]. Lyon, France, 2002, 81: 57–339
Hesterberg T W, Hart G A, Chevalier J, et al. The Importance of Fiber Biopersistence and Lung Dose in Determining the Chronic Inhalation Effects of X607, RCF1, and Chrysotile Asbestos in Rats [J]. Toxicol. Appl. Pharmacol., 1998, 153(1): 68–82
Liu H, Wang X T, Wang Z F, et al. Effect of TiO2-coating on the Crystallization Behavior of CaO-MgO-SiO2 System Ceramic Fibers [J]. Journal of Wuhan University of Science and Technology, 2009, 32(1): 170–172 (in Chinese)
Wang X T, Luo C Z, Zhang B G. Behavior of CaO-MgO-SiO2 System Bio-soluble Refractory Ceramic Fibers [J]. Key Eng. Mater., 2007, 336–338: 1 556–1 558
Wallenberger F T, Hichs R J, Bierhals A T. Design of Environmentally Friendly Fiberglass Compositions: Ternary Eutectic SiO2-Al2O3-CaO Compositions, Structures and Properties [J]. J. Non-Cryst. Solids, 2004, 349: 377–387
Shyu J J, Hwang C S. Effect of Y2O3 and La2O3 Addition on the Crystallization of Li2O·Al2O3·4SiO2 Glass-Ceramics [J]. J. Mater. Sci., 1996, 31(10): 2 631–2 639
Wang M T, Cheng J S, Liu Q M, et al. The Effect of Light Rare Earths on the Chemical Durability and Weathering of Na2O-CaO-SiO2 Glasses [J]. J. Nucl. Mater., 2010, 400(2): 107–111
Kim K A, Lee W K, Kim J K, et al. Mechanism of Refractory Ceramic Fiber- and Rock Wool-induced Cytotoxicity in Alveolar Macrophages [J]. Int. Arch. Occup. Environ. Health, 2001, 74(1): 9–15
Potter R M, Mattson S M. Glass Fiber Dissolution in a Physiological Saline Solution [J]. Glastech. Ber., 1991, 64: 16–28
Lusvardi G, Malavasi G, Menabue L, et al. A Computational Tool for the Prediction of Crystalline Phases Obtained from Controlled Crystallization of Glasses [J]. J. Phys. Chem. B, 2005, 109(46): 21 586–21 592
Lange P. Evidence for Disorder-induced Vibrational Mode Coupling in Thin Amorphous SiO2 Films [J]. J. Appl. Phys., 1989, 66(1): 201–204
Parada E G, González P, Pou J, et al. Aging of Photochemical Vapor Deposited Silicon Oxide Thin Films [J]. J. Vac. Sci. Technol. A, 1996, 14(2): 436–440
Szumera M, Waclawska I, Mozgawa W, et al. Spectroscopic Study of Biologically Active Glass [J]. J. Mol. Struct., 2005, 744–747: 609–614
Baillif P, Chouikhi B, Barbanson L, et al. Dissolution Kinetics of Glass Fibres in Saline Solution: in Vitro Persistence of a Sparingly Soluble Aluminium-rich Leached Layer [J]. J. Material. Sci., 1995, 30(22): 5 691–5 699
Brady P V. Silica Surface Chemistry at Elevated Temperatures [J]. Geochim. Cosmochim. Acta, 1992, 56(7): 2 941–2 946
Dove P M, Crerara D A. Kinetics of Quartz Dissolution in Electrolyte Solutions Using a Hydrothermal Mixed Flow Reactor [J]. Geochim. Cosmochim. Acta, 1990, 54(4): 955–969
Leineweber J P. Solubility of Fibres in Vitro and in Vivo. In: Proceedings of a WHO/IARC Conference on Biological Effects of Manmade Mineral Fibres [C]. Copenhagen: World Health Organization, 1984, 12: 87–101
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Funded by the National High Technology Research and Development Program (“863” Program) of China (No.2009AA032503), the National Natural Science Foundation of China (Nos.50872098, 51004080), and the Open Fund of the Key State Laboratory Breeding Base of Refractories and Ceramics (Wuhan University of Science and Technology (No.G201004)
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Liu, H., Wang, X., Zhang, B. et al. Structure and properties of CaO-MgO-SiO2 inorganic glass fiber with additives (Al2O3, Y2O3). J. Wuhan Univ. Technol.-Mat. Sci. Edit. 27, 58–62 (2012). https://doi.org/10.1007/s11595-012-0407-5
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DOI: https://doi.org/10.1007/s11595-012-0407-5