Abstract
CuS pineal microspheres congregated from interleaving nanoflakes with thickness of 40 to 200 nm were synthesized by a pyridine-solvothermal process via the reaction between cupric chloride (CuCl2·2H2O) and thioacetamide (TAA, CH3CSNH2). The products were characterized by X-ray diffraction and scanning electron microscopy. UV-Vis absorption spectrum, excitation and photoluminescence spectra of CuS pineal microspheres were obtained at room temperature to investigate their optical properties. A possible growth mechanism on the formation of CuS pineal microspheres is proposed. The factors influencing the evolution of morphologies of CuS crystals including the dosage of the reactants, surfactant, and sulphur-source were also analyzed.
Similar content being viewed by others
References
R S Mane, C D Lokhande. Chemical Deposition Method for Metal Chalcogenide Thin Films[J]. Mater. Chem. Phys., 2000, 65(1): 1–31
L Reijnen, B Meester, A Goossens, et al. Atomic Layer Deposition of CuxS for Solar Energy Conversion[J]. Chem. Vap. Deposition, 2003, 9(1): 15–20
M T S Nair, P K Nair. Chemical Bath Deposition of CuxS Thin Films and Their Prospective Large Area Applications[J]. Semicond. Sci. Technol., 1989, 4(3): 191–199
W Liang, M H Whangbo. Conductivity Anisotropy and Structural Phase Transition in Covellite CuS[J]. Solid State Commun., 1993, 85(5): 405–408
J S Chung, H J Sohn. Electrochemical Behaviors of CuS as a Cathode Material for Lithium Secondary Batteries[J]. J. Power Sources, 2002, 108(2): 226–231
C Q Xu, Z C Zhang, Q Ye, et al. Synthesis of Copper Sulfide Nanowhisker via Sonochemical Way and Its Characterization[ J]. Chem. Lett., 2003,32(2): 198–199
Y He, X Yu, X Zhao. Synthesis of Hollow CuS Nanostructured Microspheres with Novel Surface Morphologies[J]. Mater. Lett., 2007,61(14–15): 3 014–3 016
X H Liao, N Y Chen, S Xu, et al. A Microwave Assisted Heating Method for the Preparation of Copper Sulfide Nanorods[J]. J. Cryst. Growth, 2003, 252(4): 593–598
L Gao, E Wang, S Lian, et al. Microemulsion-directed Synthesis of Different CuS Nanocrystals[J]. Solid State Commun., 2004,130(5): 309–312
G Mao, W Dong, D G Kurth, et al. Synthesis of Copper Sulfide Nanorod Arrays on Molecular Templates[J]. Nano Lett., 2004,4(2): 249–252
Q Y Lu, F Gao, D Y Zhao. One-step Synthesis and Assembly of Copper Sulfide Nanoparticles to Nanowires, Nanotubes, and Nanovesicles by a Simple Organic Amine-assisted Hydrothermal Process[J]. Nano Lett., 2002,2(7): 725–728
L Y Zhu, Y Xie, X W Zheng, et al. Fabrication of Novel Urchin-like Architecture and Snowflake-like Pattern CuS[J]. J. Cryst. Growth, 2004,260(3–4): 494–499
S Gorai, D Ganguli, S Chaudhuri. Synthesis of Copper Sulfides of Varying Morphologies and Stoichiometries Controlled by Chelating and Nonchelating Solvents in a Solvothermal Process[J]. Cryst. Growth Des., 2005, 5(3): 875–877
Y Ni, F Wang, H Liu, et al. A Novel Source-template Route for Preparation of Copper Sulfide Submicron Wires[J]. Chin. J. Inorg. Chem., 2003,19(11): 1 197–1 201
C Tan, Y Zhu, R Lu, et al. Synthesis of Copper Sulfide Nanotube in the Hydrogel System[J]. Mater. Chem. Phys., 2005, 91(1): 44–47
R Nomura, K Miyawaki, T Toyosaki, et al. Preparation of Copper Sulfide Thin Layers by a Single-source MOCVD Process[J]. Chem. Vap. Depos., 1996, 2(5): 174–179
H L Zhu, X Ji, D Yang, et al. Novel CuS Hollow Spheres Fabricated by a Novel Hydrothermal Method[J]. Micropor. Mesopor. Mat., 2005, 80(1–3): 153–156
A M Qin, Y P Fang, H D Ou, et al. Formation of Various Morphologies of Covellite Copper Sulfide Submicron Crystals by a Hydrothermal Method without Surfactant[J]. Cryst. Growth Des., 2005, 5(3): 855–860
A Ghezelbash, B A Korgel. Nickel Sulfide and Copper Sulfide Nanocrystal Synthesis and Polymorphism[J]. Langmuir, 2005, 21(21): 9 451–9 456
C H An, S T Wang, J He, et al. A Composite-surfactants-assisted-solvothermal Process to Copper Sulfide Nanocrystals[J]. J. Cryst. Growth, 2008, 310(2): 266–269
T Thongtem, A Phuruangrat, S Thongtem. Formation of CuS with Flower-like, Hollow Spherical, and Tubular Structures Using the Solvothermal-microwave Process[J]. Curr. Appl. Phys., 2009, 9(1): 195–200
X Gou, F Cheng, Y Shi, et al. Shape-controlled Synthesis of Ternary Chalcogenide ZnIn2S4 and CuIn(S, Se)2 Nano-/Microstructures via Facile Solution Route[J]. J. Am. Chem. Soc., 2006, 128(22): 7 222–7 229
J Y Gong, S H Yu, H S Qian, et al. Acetic Acid-assisted Solution Process for Growth of Complex Copper Sulfide Microtubes Constructed by Hexagonal Nanoflakes[J]. Chem. Mater., 2006, 18(8): 2 012–2 015
P Roy, S K Srivastava. Synthesis of Twinned CuS Nanorods by a Simple Wet Chemical Method Cryst[J]. Growth Des., 2008, 8(5): 1 530–1 534
C Tan, Y Zhu, R Lu, et al. Synthesis of Copper Sulfide Nanotube in the Hydrogel System[J]. Mater. Chem. Phys., 2005, 91(1): 44–47
H Ji, J Cao, J Feng, et al. Fabrication of CuS Nanocrystals with Various Morphologies in the Presence of a Nonionic Surfactant[J]. Mater. Lett., 2005, 59(24–25): 3 169–3 172
S K Haram, A Mahadeshwar, S G Dixit. Synthesis and Characterization of Copper Sulfide Nanoparticles in Triton-X 100 Water-in-oil Microemulsions[J]. J. Phys. Chem., 1996, 100(14): 5 868–5 873
S Ou, Q Xie, D Ma, et al. A Precursor Decomposition Route to Polycrystalline CuS Nanorods[J]. Mater. Phys. Chem., 2005, 94(2–3): 460–466
Author information
Authors and Affiliations
Corresponding author
Additional information
Funded by the Natural Science Foundation of Hubei Province (No.2008CDB013)
Rights and permissions
About this article
Cite this article
Ke, H., Luo, W., Cheng, G. et al. Formation of CuS pineal microspheres via a pyridine-solvothermal process. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 25, 459–463 (2010). https://doi.org/10.1007/s11595-010-0023-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11595-010-0023-1