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Preparation of styrene-acrylate latex used in ultralow VOC building internal wall coating

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Abstract

Styrene-acrylate latex with high glass transition temperature (T g), low minimum film forming temperature(MFT) and good stability was prepared via core-shell emulsion polymerization. With semicontinuous process, high conversion rate of monomer and low gel rate were achieved. The weight ratio of core monomer to shell monomer was approximately 1.35. It is found that many factors such as emulsifiers, initiators, reaction temperature, pH value and polymerization technology have influences on the permormance of styrene-acrylate latex. The prepared latex was characterized by TEM and FTIR. The obtained latex with T g of 20.57 °, MFT of 5.0 °, and good stability, had good stability of film forming.

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References

  1. Jie Jiang-bin, Liu Yan-hua. VOC Content in the Latex Paint and Indoor Health[J]. China Paint,2004(1):22–23(in Chinese)

  2. Liebscher H. Economic Solutions for Compliance to the New European VOC Directive[J]. Progress in Organic Coatings, 2000,40:75–83

    Article  CAS  Google Scholar 

  3. Chen Li-jun, Chen Huan-qin. Approach to Prepare Low VOC Polyurethane(PUR) Coating and Its Application[J].Chemical Materials for Construction, 2004(6):1–4(in Chinese)

  4. Liu Yong-zhen, Chen Peng, Ren Xiu-quan, et al. Emulsion Blending Technology-Formulation of Latex Coatings with Ultra-low VOC Content[J]. Chemical Materials for Construction, 2003(1):10–13( in Chinese)

  5. Sanjani N S, Mahdavian A R, Bataile P. Emulsion Polymerization of Styrene and DEAEMA with a Core-shell Structure[J]. Journal of Applied Polymer Science,2000,78(11):1 977–1 985

    Article  Google Scholar 

  6. Kim S H, Son W K, Kim Y J, et al. Synthesis of Polystyrene/poly(butyl acrylate) Core-shell Latex and Its Surface Morphology[J]. Journal of Applied Polymer Science, 2003, 88(3): 595–601

    Article  CAS  Google Scholar 

  7. Zou M X, Wang S J, Huang F Z, et al. Preparation and Characterization of Core-shell Polystyrene and Polymethylsilsesquioxane Structure Latex Particles by Seeded Polymerization[J]. Polymer International, 2006, 55(3): 305–311

    Article  CAS  Google Scholar 

  8. Zhang Xin-ya, Tu Wei-ping, Yang Zhuo-ru, et al. Influence of Emulsifying Agent on Stability of Polymeric Latex in Emulsion Polymerization[J]. Technology on Adhesion and Sealing, 2002,23(3):16–19(in Chinese)

    Google Scholar 

  9. Cao Tong-yu, Liu Qing-pu, Hu Jin-sheng. Synthetic Mechanism, Performance and Application of Polymer Latex[M]. Beijing: Chemical Industry Press,1997:199–203( in Chinese)

    Google Scholar 

  10. Okubo M, Yamada A M. Preparation of Composite Particles with Core-shell Structure[J]. Journal of Polymer Science, 1980,203(6): 3 219–3 220

    Google Scholar 

  11. Morguchi N, Tsugaru T, Amiya S. Molecular Design of the Polymer Forming the Complex with MetalI. Design of the Hard-segments of Thermoplastic Elastomers by Using Model Compounds [J]. Journal of Molecular Structure,1999,477: 191–199

    Article  Google Scholar 

  12. Devon M J, Gardon J L, Robert G, et al. Effects of Core-shell Latex Morphology on Film Forming Behavior[J]. Journal of Applied Polymer Science,1990, 39(10): 2 119–2 128

    Article  CAS  Google Scholar 

  13. Li Z M, Yang J H, Yu Y Z,et al. Morphological Characterization of the Core-shell Latex Particle by Transmission Electron Microscopy and Image Analysis[J]. Journal of Applied Polymer Science,2003,89(3):855–861

    Article  CAS  Google Scholar 

  14. Chen Jie. Analysis of Organic Spectrum[M]. Beijing: Beijing University of Science and Technology Press, 1996:35–37(in Chinese)

    Google Scholar 

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Correspondence to Chen Lijun.

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Chen, L., Wu, F., Zhuang, X. et al. Preparation of styrene-acrylate latex used in ultralow VOC building internal wall coating. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 23, 65–70 (2008). https://doi.org/10.1007/s11595-006-1065-2

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  • DOI: https://doi.org/10.1007/s11595-006-1065-2

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