Abstract
The silicon/carbon (Si/C) composite material was prepared, and the electrochemical performance was investigated as a promising anode material for lithium ion batteries. The results show that the binder in the electrode acts as an important role for improving the reversible capacity of the Si/C materials during cycling. The Si/C electrode with CMC/SBR binder possesses a better cycle performance than that with PVDF binder. The Si/C composite material shows an initial reversible capacity of more than 700 mAh∙g−1 and remains a reversible capacity of 597 mAh g−1 after 40 cycles.
References
Huggins RA (1999) J Power Sources 81–82:13
Winter M, Besenhard JO (1999) Electrochim Acta 45:31
Obrovac MN, Christensen L (2004) Electrochem Solid state Lett 7:A93
Hatchard TD, Dahn JR (2004) J Electrochem Soc 151:A838
Kasavajjula U, Wang CS, Appleby AJ (2007) J Power Sources 163:1003
Yoshio M, Wang H, Fukuda K, Umeno T, Dimov N, Ogumi Z (2002) J Electrochem Soc 149:A1598
Ryu JH, Kim JW, Sung YE, Oh SM (2004) Electrochem Solid State Lett 7:A306
Li H, Huang X, Chen L, Wu Z (1999) Electrochem Solid state Lett 2:547
Guo ZP, Wang JZ, Liu HK, Dou SX (2005) J Power Sources 146:448
Kim I, Kumta PN, Blomgren GE (2000) Electrochem Solid state Lett 3:493
Kim I, Blomgren GE, Kumta PN (2003) Electrochem Solid state Lett 6:A157
Kim JW, Ryu JH, Lee KT, Oh SM (2005) J Power Sources 147:227
Wang GX, Sun L, Bradhurst DH, Zhong S, Dou SX, Liu HK (2000) J Power Sources 88:278
Liu Y, Hanai K, Yang J, Imanishi N, Hirano A, Takeda Y (2004) Electrochem Solid State Lett 7:A369
Yang X, Wen Z, Zhu X, Huang S (2005) Electrochem Solid State Lett 8:A481
Wang GX, Ahn JH, Yao J, Bewlay S, Liu HK (2004) Electrochem Commun 6:689
Hasegawa T, Mukai SR, Shirato Y, Tamon H (2004) Carbon 42:2573
Holzapfel M, Buqa H, Krumeich F, Novák P, Petrat FM, Veit C (2005) Electrochem Solid State Lett 8:A516
Chen ZH, Christensen L, Dahn JR (2003) Electrochem Commun 5:919
Buqa H, Holzapfel M, Krumeich F, Veit C, Novák P (2006) J Power Sources 161:617
Li J, Lewis RB, Dahn JR (2007) Electrochem Solid State Lett 10:A17
Li J, Le DB, Ferguson PP, Dahn JR (2010) Electrochim Acta 55:2991
Liu WR, Yang MH, Wu HC, Chiao SM, Wu NL (2005) Electrochem Solid State Lett 8:A100
Zuo PJ, Yin GP, Zhao J, Ma YL, Cheng XQ, Shi PF, Tamamura T (2006) Electrochim Acta 52:1527
Zuo PJ, Yin GP, Ma YL (2007) Electrochim Acta 52:4878
Zuo PJ, Wang ZB, Yin GP, Jia DC, Cheng XQ, Du CY, Shi PF (2008) J Mater Sci 43:3149
Acknowledgements
This work was partially supported by The Natural Science Foundation of China (no. 50902038), China Postdoctoral Science Foundation funded project (20070420860, 200902392), Natural Scientific Research Innovation Foundation in Harbin Institute of Technology (HIT.NSRIF. 2008.25).
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Zuo, P., Yang, W., Cheng, X. et al. Enhancement of the electrochemical performance of silicon/carbon composite material for lithium ion batteries. Ionics 17, 87–90 (2011). https://doi.org/10.1007/s11581-010-0494-2
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DOI: https://doi.org/10.1007/s11581-010-0494-2