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Characteristics of indirect laser-induced plasma from a thin film of oil on a metallic substrate

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Abstract

Optical emissions from the major and trace elements embodied in a transparent gel prepared from cooking oil were detected after the gel was spread in a thin film on a metallic substrate. Such emissions are due to the indirect breakdown of the coating layer. The generated plasma, a mixture of substances from the substrate, the layer, and the ambient gas, was characterized using emission spectroscopy. The characteristics of the plasma formed on the metal with and without the coating layer were investigated. The results showed that Al emission induced from the aluminum substrates coated with oil films extends away from the target surface to ablate the oil film. This finally formed a bifurcating circulation of aluminum vapor against a spherical confinement wall in the front of the plume, which differed from the evolution of the plasma induced from the uncoated aluminum target. The strongest emissions of elements from the oil films can be observed at 2 mm above the target after a detection delay of 1.0 μs. A high temperature zone has been observed in the plasma after the delay of 1.0 μs for the plasma induced from the coated metal. This higher temperature determined in the plasma allows the consideration of the sensitive detection of trace elements in liquids, gels, biological samples, or thin films.

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References

  1. Y. H. Wei, J. Y. Zhang, T. C. Dai, T. H. Tu, and L. G. Luo, Determination of chlorine in hogwash oil and edible oil by ion chromatograph, Food Science 32(12), 213 (2011)

    MATH  Google Scholar 

  2. Q. A. Ricardo, M. S. Roseli, C. C. Reinaldo, M. Norbert, and L. P. S. Carmem, The determination of trace in lubricating oils by atomic spectrometry, Spectrochim. Acta B 62(9), 952 (2007)

    Article  Google Scholar 

  3. L. Caneve, F. Colao, F. Sarto, V. Spizzichino, and M. Vadrucci, Laser-induced breakdownspectroscopy as a diagnostic tool for thin films elemental composition, Spectrochim. Acta B 60(7–8), 1098 (2005)

    Article  ADS  Google Scholar 

  4. P. Celio, C. Juliana, M. C. S. Lucas, and B. G. Fabinao, Laser induced breakdown spectroscopy, J. Braz. Chem. Soc. 18(3), 463 (2007)

    Article  Google Scholar 

  5. A. De Giacomo, M. Dell’Aglio, O. De Pascale, and M. Capitelli, From single pulse to double pulse ns-Laser Induced Breakdown Spectroscopy under water: Elemental analysis of aqueous solutions and submerged solid samples, Spectrochim. Acta B 62(8), 721 (2007)

    Article  ADS  Google Scholar 

  6. Z. Wang, T. B. Yuan, Z. Y. Hou, W. D. Zhou, J. D. Lu, H. B. Ding, and X. Y. Zeng, Laser-induced breakdown spectroscopy in China, Front. Phys. 9(4), 419 (2014)

    Article  Google Scholar 

  7. J. Yu and R. E. Zheng, Laser-induced plasma and laserinduced breakdown spectroscopy (LIBS) in China: The challenge and the opportunity, Front. Phys. 7(6), 647 (2012)

    Article  MathSciNet  Google Scholar 

  8. F. Z. Dong, X. L. Chen, Q. Wang, L. X. Sun, H. B. Yu, Y. X. Liang, J. G. Wang, Z. B. Ni, Z. H. Du, Y. W. Ma, and J. D. Lu, Recent progress on the application of LIBS for metallurgical online analysis in China, Front. Phys. 7(6), 679 (2012)

    Article  Google Scholar 

  9. L. Zhang, Z. Y. Hu, W. Y. Bao, D. Huang, W. G. Ma, L. Dong, H. P. Wu, Z. X. Li, L. T. Xiao, and S. T. Jia, Recent progress on laser-induced breakdown spectroscopy for the monitoring of coal quality and unburned carbon in fly ash, Front. Phys. 7(6), 690 (2012)

    Article  Google Scholar 

  10. V. S. Burakov, N. V. Tarasenko, M. I. Nedelko, V. N. Kononovb, N. N. Vasilevb, and S. N. Isakov, Analysis of lead and sulfur in environmental samples by double pulse laser induced breakdown spectroscopy, Spectrochim. Acta B 64(2), 141 (2009)

    Article  ADS  Google Scholar 

  11. F. Boué-Bigne, Laser induced breakdown spectroscopy applications in the steel industry: Rapid analysis of segregation and decarburization, Spectrochim. Acta B 63(10), 1122 (2008)

    Article  ADS  Google Scholar 

  12. J. Kaiser, M. Galiová, K. Novotný, R. Èervenk, L. Reale, J. Novotný, M. Liška, O. Samek, V. Kanický, A. Hrdlièk, K. Stejskal, V. Adam, and R. Kizek, Mapping of lead, magnesium and copper accumulation in plant tissues by laser induced breakdown spectroscopy and laser ablation inductively coupled plasma mass spectrometry, Spectrochim. Acta B 64(1), 67 (2009)

    Article  ADS  Google Scholar 

  13. P. Fichet, P. Mauchien, J. F. Wagner, and C. Moulin, Quantitative elemental determination inwater and oil by laser induced breakdown spectroscopy, Anal. Chim. Acta 429(2), 269 (2001)

    Article  Google Scholar 

  14. M. A. Gondal and T. Hussain, Determination of poisonous metals in wastewater collected from paint manufacturing plant using laser-induced breakdown spectroscopy, Talanta 71(1), 73 (2007)

    Article  MathSciNet  Google Scholar 

  15. A. Kumar, F. Y. Yueh, and J. P. Singh, Double-pulse laserinduced breakdown spectroscopy with liquid jets of different thicknesses, Appl. Opt. 42(30), 6047 (2003)

    Article  ADS  Google Scholar 

  16. N. K. Rai and A. K. Rai, LIBS-An efficient approach for the determination of Cr in industrial wastewater, J. Hazard. Mater. 150(3), 835 (2008)

    Article  MathSciNet  Google Scholar 

  17. R. L. VanderWal, T. M. Ticich, J. R. West, and Jr. P. A. Householder, Trace metal detection by Laser-Induced Breakdown Spectroscopy, Appl. Spectrosc. 53(10), 1226 (1999)

    Article  ADS  Google Scholar 

  18. Z. J. Chen, H. K. Li, M. Liu, and R. H. Li, Fast and sensitive trace metal analysis in aqueous solutions by laser-induced breakdown spectroscopy using wood slice substrates, Spectrochim. Acta B 63(1), 64 (2008)

    Article  ADS  Google Scholar 

  19. D. Alamelu, A. Sarkar, and S. K. Aggarwal, Laser-induced breakdown spectroscopy for simultaneous determination of Sm, Eu and Gd in aqueous solution, Talanta 77(1), 256 (2008)

    Article  Google Scholar 

  20. Y. L. Yu, W. D. Zhou, H. G. Qian, X. J. Su, and K. Ren, Simultaneous determination of trace lead and chromium in water using laser-induced breakdown spectroscopy and paper substrate, Plasma Sci. Technol. 16(7), 683 (2014)

    Article  ADS  Google Scholar 

  21. Q. Y. Lin, Z. M. Wei, M. J. Xu, S. Wang, G. H. Niu, K. P. Liu, Y. X. Duan, and J. Yang, Laser-induced breakdown spectroscopy for solution sample analysis using porous electrospun ultrafine fibers as a solid-phase support, RSC Advances 4(28), 14392 (2014)

    Article  Google Scholar 

  22. A. Nadir, Ü. Y. Semira, A. A. Dilek, Y. Erife, Ultrasonic nebulization-sample introduction system for quantitative analysis of liquid samples by laser-induced breakdown spectroscopy, Spectrochim. Acta B 74–75(8–9), 87 (2012)

    Google Scholar 

  23. P. Yaroshchyk, R. J. S. Morrison, D. Body, and B. L. Chadwick, Quantitative determination of wear metal in engine oils using laser-induced breakdown spectroscopy: A comparison between liquid jets and static liquids, Spectrochim. Acta B 60(7–8), 986 (2005)

    Article  ADS  Google Scholar 

  24. I. Y. Elnasharty, A. K. Kassem, M. Sabsabi, and M. A. Harith, Diagnosis of lubricating oil by evaluating cyanide and carbon molecular emission lines in laser induced breakdown spectra, Spectrochim. Acta B 66(8), 588 (2011)

    Article  ADS  Google Scholar 

  25. M. A. Aguirre, S. Legnaioli, F. Almodóvar, M. Hidalgo, V. Palleschi, and A. Canals, Elemental analysis by surfaceenhanced Laser-Induced Breakdown Spectroscopy combined with liquid-liquid microextraction, Spectrochim. Acta B 79–80(1–2), 88 (2013)

    Article  Google Scholar 

  26. L. St-Onge, E. Kwong, M. Sabsabi, and E. B. Vadas, Quantitative analysis of pharmaceutical products by laser-induced breakdown spectroscopy, Spectrochim. Acta B 57(7), 1131 (2002)

    Article  ADS  Google Scholar 

  27. X. S. Bai, Q. L. Ma, V. Motto-Ros, J. Yu, D. Sabourdy, L. Nguyen, and A. Jalocha, Convoluted effect of laser fluence and pulse duration on the property of a nanosecond laser-induced plasma into an argon ambient gas at the atmospheric pressure, J. Appl. Phys. 113(1), 013304 (2013)

    Article  ADS  Google Scholar 

  28. A. Sáinz, A. Díaz, D. Casas, M. Pineda, F. Cubillo, and M. D. Calzada, Abel inversionapplied to a small set of emission data from a microwave plasma, Appl. Spectrosc. 60(3), 229 (2006)

    Article  ADS  Google Scholar 

  29. Q. L. Ma, V. Motto-Ros, W. Q. Lei, M. Boueri, X. S. Bai, L. J. Zheng, H. P. Zeng, and J. Yu, Temporal and spatial dynamics of laser-induced aluminum plasma in argon background at atmospheric pressure: Interplay with the ambient gas, Spectrochim. Acta B 65(11), 89 (2010)

    Article  Google Scholar 

  30. T. Sakka, T. Nakajima, and Y. H. Ogata, Spatial population distribution of laser ablationspecies determined by self-reversed emission line profile, J. Appl. Phys. 92(5), 2296 (2002)

    Article  ADS  Google Scholar 

  31. A. M. El Sherbini, H. Hegazy, and Th. M. El Sherbini, Measurement of electron density utilizing the Hα-line from laser produced plasma in air, Spectrochim. Acta B 61(5), 532 (2006)

    Article  ADS  Google Scholar 

  32. H. R. Griem, Spectral Line Broadening by Plasmas, New York: Academic Press, 1974

    Google Scholar 

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Correspondence to Jun-Shan Xiu  (修俊山).

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Xiu, JS., Bai, XS., Motto-Ros, V. et al. Characteristics of indirect laser-induced plasma from a thin film of oil on a metallic substrate. Front. Phys. 10, 231–239 (2015). https://doi.org/10.1007/s11467-014-0450-0

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  • DOI: https://doi.org/10.1007/s11467-014-0450-0

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