Abstract
This minireview outlines the main scientific directions in the research of inorganic nanotubes (INT) and fullerene-like (IF) nanoparticles from layered compounds, in recent years. In particular, this review describes to some detail the progress in the synthesis of new nanotubes, including those from misfit compounds; core-shell and the successful efforts to scale-up the synthesis of WS2 multiwall nanotubes. The high-temperature catalytic growth of nanotubes, via solar ablation is discussed as well. Furthermore, the doping of the IF-MoS2 nanoparticles and its influence on the physiochemical properties of the nanoparticles, including their interesting tribological properties are briefly discussed. Finally, the numerous applications of these nanoparticles as superior solid lubricants and for reinforcing variety of polymers are discussed in brief.
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R. Tenne, L. Margulis, M. Genut, and G. Hodes, Polyhedral and cylindrical structures of tungsten disulphide, Nature, 1992, 360(6403): 444
L. Margulis, G. Salitra, R. Tenne, and M. Talianker, Nested fullerene-like structures, Nature, 1993, 365(6442): 113
Y. Feldman, E. Wasserman, D. J. Srolovitz, and R. Tenne, High-rate, gas-phase growth of MoS2 nested inorganic fullerenes and nanotubes, Science, 1995, 267(5195): 222
M. Homyonfer, B. Alperson, Yu. Rosenberg, L. Sapir, S. R. Cohen, G. Hodes, and R. Tenne, Intercalation of inorganic fullerene-like structures yields photosensitive films and new tips for scanning probe microscopy, J. Am. Chem. Soc., 1997, 119(11): 2693
R. Rosentsveig, A. Margolin, Y. Feldman, R. Popovitz-Biro, and R. Tenne, WS2 nanotube bundles and foils, Chem. Mater., 2002, 14(2): 471
Y. Feldman, A. Zak, R. Popovitz-Biro, and R. Tenne, New reactor for production of tungsten disulfide hollow onionlike (inorganic fullerene-like) nanoparticles, Solid State Sci., 2000, 2(6): 663
Y. Q. Zhu, W. K. Hsu, N. Grobert, B. H. Chang, M. Terrones, H. Terrones, H. W. Kroto, D. R. M. Walton, and B. Q. Wei, Production of WS2 nanotubes, Chem. Mater., 2000, 12(5): 1190
H. A. Therese, J. Li, U. Kolb, and W. Tremel, Facile large scale synthesis of WS2 nanotubes from WO3 nanorods prepared by a hydrothermal route, Solid State Sci., 2005, 7(1): 67
A. Rothschild, J. Sloan, and R. Tenne, Growth of WS2 nanotubes phases, J. Am. Chem. Soc., 2000, 122(21): 5169
A. Zak, L. Sallacan-Ecker, A. Margolin, M. Genut, and R. Tenne, Insight into the growth mechanism of WS2 nanotubes in the scaled-up fluidized-bed reactor, Nano, 2009, 4(02): 91
A. Zak, L. Sallacan Ecker, R. Efrati, L. Drangai, N. Fleischer, and R. Tenne, Large-scale synthesis of WS2 multiwall nanotubes and their dispersion, an update, Sensors & Transducers J., 2011, 12: 1
E. Zohar, S. Baruch, M. Shneider, H. Dodiuk, S. Kenig, H. D. Wagner, A. Zak, A. Moshkovith, L. Rapoport, and R. Tenne, The mechanical and tribological properties of epoxy nanocomposites with WS2 nanotubes, Sensors & Transducers J., 2011, 12: 53
M. Naffakh, M. Remskar, C. Marco, and M. A. Gómez-Fatou,, Dynamic crystallization kinetics and nucleation parameters of a new generation of nanocomposites based on isotactic polypropylene and MoS2 inorganic nanotubes, J. Phys. Chem. B, 2011, 115(12): 2850
K. Tiong, P. Liao, C. Ho, and Y. Huang, Growth and characterization of rhenium-doped MoS2 single crystals, J. Cryst. Growth, 1999, 205(4): 543
P. Yen, Y. Huang, and K. Tiong, The growth and characterization of rhenium-doped WS2 single crystals, J. Phys.: Condens. Matter, 2004, 16(12): 2171
L. Yadgarov, R. Rosentsveig, G. Leitus, A. Albu-Yaron, A. Moshkovith, V. Perfilyev, R. Vasic, A. I. Frenkel, A. N. Enyashin, G. Seifert, L. Rapoport, and R. Tenne, Controlled doping of MS2 (M=W, Mo) nanotubes and fullerene-like nanoparticles, Angew. Chem. Int. Ed., 2012, 51(5): 1148
L. Yadgarov, D. G. Stroppa, R. Rosentsveig, R. Ron, A. N. Enyashin, L. Houben, and R. Tenne, Investigation of rhenium-doped MoS2 nanoparticles with fullerene-like structure, Z. Anorg. Allg. Chem., 2012, 638(15): 2610
L. Rapoport, A. Moshkovich, V. Perfiliev, A. Laikhtman, I. Lapsker, L. Yadgarov, R. Rosentsveig, and R. Tenne, High lubricity of Re-doped fullerene-like MoS2 nanoparticles, Tribol. Lett., 2012, 45(2): 257
L. Yadgarov, V. Petrone, R. Rosentsveig, Y. Feldman, R. Tenne, and A. Senatore, Tribological studies of rhenium doped fullerene-like MoS2 nanoparticles in bound ary, mixed and elasto-hydrodynamic lubrication conditions, Wear, 2013, 297(1–2): 1103
R. Rosentsveig, A. Margolin, A. Gorodnev, R. Popovitz-Biro, Y. Feldman, L. Rapoport, G. R. Samorodnitzky-Naveh, and R. Tenne, Synthesis of fullerene-like MoS2 nanoparticles and their tribological behavior, J. Mater. Chem., 2009, 19(25): 4368
Q. C. Sun, L. Yadgarov, R. Rosentsveig, G. Seifert, R. Tenne, and J. L. Musfeldt, Observation of a Burstein-Moss shift in rhenium-doped MoS2 nanoparticles, ACS Nano, 2013, 7(4): 3506
A. M. Morales and C. M. Lieber, A laser ablation method for the synthesis of crystalline semiconductor nanowires, Science, 1998, 279(5348): 208
A. Yella, E. Mugnaioli, M. Panthofer, H. A. Therese, U. Kolb, and W. Tremel, Bismuth-catalyzed growth of SnS2 nanotubes and their stability, Angew. Chem. Int. Ed., 2009, 48(35): 6426
O. Brontvein, D. G. Stroppa, R. Popovitz-Biro, A. Albu-Yaron, M. Levy, D. Feuerman, L. Houben, R. Tenne, and J. M. Gordon, New high-temperature Pb-catalyzed synthesis of inorganic nanotubes, J. Am. Chem. Soc., 2012, 134(39): 16379
B. Alperson, M. Homyonfer, and R. Tenne, Photoelectrochemical studies with inorganic cage structures of metal dichalcogenides, J. Electroanal. Chem., 1999, 473(1–2): 186
S. Y. Hong, R. Popovitz-Biro, Y. Prior, and R. Tenne, Synthesis of SnS2/SnS fullerene-like nanoparticles: A superlattice with polyhedral shape, J. Am. Chem. Soc., 2003, 125(34): 10470
G. Radovsky, R. Popovitz-Biro, M. Staiger, K. Gartsman, C. Thomsen, T. Lorenz, G. Seifert, and R. Tenne, Synthesis of copious amounts of SnS2 and SnS2/SnS nanotubes with ordered superstructures, Angew. Chem. Int. Ed., 2011, 50(51): 12316
G. Radovsky, R. Popovitz-Biro, and R. Tenne, Study of tubular structures of the misfit layered compound SnS2/SnS, Chem. Mater., 2012, 24(15): 3004
A. Meerschaut, Misfit layer compounds, Curr. Opin. Solid State & Mater. Sci., 1996, 1(2): 250
J. Rouxel and A. Meerecheut, Misfit layer compounds (MX)n(TX2)m [M= Sn, Pb, Bi, Rare earth; T= Transition metal; X=S, Se; 1.08 < n <1.25; m=1, 2, Mol. Cryst. Liq. Cryst. Sci. Tec. A, 1994, 244(1): 343
G. A. Wiegers and A. Meerscheut, Misfit layer compounds (MS)nTS2 (M=Sn, Pb, Bi, Rare earth metals; T=Nb, Ta, Ti, V, Cr; 1.08 < n <1.23): Structures and physical properties, Mater. Sci. Forum, 1992, 100–101: l01
D. Bernaerts, S. Amelinckx, G. Van Tendeloo, and J. Van Landuyt, Microstructure and formation mechanism of cylindrical and conical scrolls of the misfit layer compounds PbNb n S2n+1, J. Cryst. Growth, 1997, 172(3–4): 433
E. Philp, J. Sloan, A. I. Kirkland, R. R. Meyer, S. Friedrichs, J. L. Hutchison, and M. L. H. Green, An encapsulated helical one-dimensional cobalt iodide nanostructure, Nat. Mater., 2003, 2(12): 788
R. Kreizman, S. Y. Hong, J. Sloan, R. Popovitz-Biro, A. Albu-Yaron, G. Tobias, B. Ballesteros, B. G. Davis, M. L. H. Green, and R. Tenne, Core-shell PbI2@WS2 inorganic nanotubes from capillary wetting, Angew. Chem. Int. Ed., 2009, 48(7): 1230
R. Kreizman, A. N. Enyashin, F. L. Deepak, A. Albu-Yaron, R. Popovitz-Biro, G. Seifert, and R. Tenne, Synthesis of core-shell inorganic nanotubes, Adv. Funct. Mater., 2010, 20(15): 2459
L. Rapoport, Yu. Bilik, Y. Feldman, M. Homyonfer, S. R. Cohen, and R. Tenne, Hollow nanoparticles of WS2 as potential solid-state lubricants, Nature, 1997, 387: 791
VA237 and VA267 bearings in SKF catalog: http://www.skf.com/group/products/bearings-units-housings/engineeredproducts/skf-drylube-bearings/designation-system/index.html
A. R. Adini, M. Redlich, and R. Tenne, Medical applications of inorganic fullerene-like nanoparticles, J. Mater. Chem., 2011, 21(39): 15121
A. M. Díez-Pascual, M. Naffakh, C. Marco, and G. Ellis,, Rheological and tribological properties of carbon nanotube/thermoplastic nanocomposites incorporating inorganic fullerene-like WS2 nanoparticles, J. Phys. Chem. B, 2012, 116(27): 7959
A. M. Díez-Pascual, M. Naffakh, C. Marco, and G. Ellis,, Mechanical and electrical properties of carbon nanotube/poly(phenylene sulphide) composites incorporating polyetherimide and inorganic fullerene-like nanoparticles, Composites: Part A, 2012, 43: 603
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Tenne, R. Recent advances in the research of inorganic nanotubes and fullerene-like nanoparticles. Front. Phys. 9, 370–377 (2014). https://doi.org/10.1007/s11467-013-0326-8
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DOI: https://doi.org/10.1007/s11467-013-0326-8