Abstract
A type of novel material with a high hydrogen storage capacity was prepared by supporting PdNi18 alloy nanoparticles, which were synthesized by using a new colloid method, on the surface of pretreated multiwalled carbon nanotubes (MWCNTs). The average PdNi18 alloy particle sizes calculated from XRD patterns were ca. 3 nm, and the high dispersion of these particles on MWCNTs was confirmed by TEM image. Hydrogen storage performance of the composite was investigated under moderate pressure (0.1–1.5 MPa) at room temperature, and a maximum storage capacity of ca. 2.3 wt% was achieved under 1.5 MPa at room temperature, which was much higher than that reported previously under the same conditions.
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Züttel A. Materials for hydrogen storage. Mater Today, 2003, 6(9): 24–33
Zhang G. Y, Qi P F, Wang X R, et al. Hydrogenation and hydrocarbonation and etching of single-walled carbon nanotubes. J Am Chem Soc, 2006, 128(18): 6026–6027
Stobinski L, Tien D-C, Liao C-Y, et al. Ultra-high vacuum system for adsorption-desorption studies of hydrogen storage on/in carbon nanotubes. Surf Coat Technol, 2006, 200(10): 3203–3205
Blackman J M, Patrick J W, Snape C E. An accurate volumetric differential pressure method for the determination of hydrogen storage capacity at high pressures in carbon materials. Carbon, 2006, 44(5): 918–927
Mulana F, Nishimiya N. Application of mechanical milling to synthesis a novel quarterly hydride. J Alloys Compd, 2006, 413(1–2): 273–280
Hao D H, Zhu H W, Zhang X F, et al. Electrochemical hydrogen storage of aligned multiwalled carbon nanotubes. Chin Sci Bull, 2003, 48(6): 538–542
Poirier E, Chanhine R, Bénard P, et al. Storage of hydrogen on single-walled carbon nanotubes and other carbon structures. Appl Phys, 2004, A78(7): 961–967
Lee H, Kang Y S, Kim S H, et al. Hydrogen desorption properties of multiwall carbon nanotubes with closed and open structures. Appl Phys Lett, 2002, 80(4): 577–580
Fan Y Y, Kaufmann A, Mukasyan A, et al. Single-and multi-wall carbon nanotubes produced using the floating catalyst method: Synthesis, purification and hydrogen up-take. Carbon, 2006, 44(11): 2160–2170
Li X S, Zhu H W, Ci L J, et al. Effects of structure and surface properties on carbon nanotubes’ hydrogen storage characteristics. Chin Sci Bull, 2000, 46(16): 1358–1360
Yoo E, Gao L, Komatsu T, et al. Atomic hydrogen storage in carbon nanotubes promoted by metal catalysts. J Phys Chem B, 2004, 108(49): 18903–18907
Zacharia R, Kim K Y, Kibria A K M F, et al. Enhancement of hydrogen storage capacity of carbon nanotubes via spill-over from vanadium and palladium nanoparticles. Chem Phys Lett, 2005, 412(4–6): 369–375
Kim K S, Lee H, Han K S, et al. Hydrogen storage in Ni nanoparticle-dispersed multiwalled carbon nanotubes. J Phys Chem B, 2005, 109(18): 8983–8986
Yu X B, Walker G S, Bowering N, et al. Electrochemical hydrogen storage in hydride-carbon composite. Electrochem Solid-State Lett, 2005, 8(11): A596–A598
Gao X P, Lan Y, Pan G L, et al. Electrochemical hydrogen storage by carbon nanotubes decorated with metallic nickel. Electrochem Solid-State Lett, 2001, 4(10): A173–A175
Huang W, Wang Y, Luo G H, et al. 99.9% purity multi-walled carbon nanotubes by vacuum high-temperature annealing. Carbon, 2003, 41(13): 2585–2590
Bekyarova E, Hashimoto A, Yudasaka M, et al. Palladium nanoclusters deposited on single-walled carbon nanohorns. J Phys Chem B, 2005, 109(9): 3711–3714
Ning G Q, Wei F, Luo G H, et al. Hydrogen storage in muti-wall carbon nanotubes using samples up to 85 g. Appl Phys A, 2004, 78(7): 955–959
Zhou L, Zhou Y P, Sun Y. Studies on the mechanism and capacity of hydrogen uptake by physisorption-based materials. Inter J Hydrogen Energy, 2006, 31(2): 259–264
Mu S C, Tang H L, Qian S H, et al. Hydrogen storage in carbon nanotubes modified by microwave plasma etching and Pd decoration. Carbon, 2006, 44(4): 762–767
Kuji T, Matsumura Y, Uahida H, et al. Hydrogen adsorption of nanocrystalline palladium. J Alloys Compd, 2002, 330–332(1–2): 718–722
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Ren, J., Liao, S. & Liu, J. Hydrogen storage of multiwalled carbon nanotubes coated with Pd-Ni nanoparticles under moderate conditions. CHINESE SCI BULL 51, 2959–2963 (2006). https://doi.org/10.1007/s11434-006-2216-8
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DOI: https://doi.org/10.1007/s11434-006-2216-8