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Influence of p-layer on the performance of n-i-p μc-Si:H thin film solar cells

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Abstract

The high pressure radio frequency plasma enhanced chemical vapor deposition (RF-PECVD) process was adopted to prepare the n-i-p microcrystalline silicon solar cells, the influence of p-type layers on the performance of the solar cells was investigated, and the optimum p layer suited to the n-i-p microcrystalline silicon solar cells was obtained. The experimental results demonstrate that the performance of the solar cells can be highly affected by the structural and optical properties of the p-layers, and the performance of solar cells can be greatly improved by optimizing p layers. We have achieved an initial active-area efficiency of 8.17% (V oc=0.49 V, J sc=24.9 mA/cm2, FF=67%) for the μc-Si:H single-junction n-i-p solar cells and an initial active-area efficiency of 10.93% (V oc=1.31 V, J sc=13.09 mA/cm2, FF=64%) for the a-Si:H/μc-Si:H tandem n-i-p solar cells.

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Referenes

  1. Meier J, Dubail S, Platz R, et al. Towards high-efficiency thin-film silicon solar cells with the “micromorph” concept. Sol Energy Mater Sol Cells, 1997, 49(1–4): 35–44

    Google Scholar 

  2. Vetterl O, Finger F, Carius R, et al. Intrinsic microcrystalline silicon: A new material for photovoltaics. Sol Energy Mater Sol Cells, 2000, 62(1–2): 97–108

    Google Scholar 

  3. Droz C, Vallat-Sauvain E, Bailat J, et al. Relationship between Raman crystallinity and open-circuit voltage in microcrystalline silicon solar cells. Sol Energy Mater Sol Cells, 2004, 81: 61–71

    Article  Google Scholar 

  4. Rath J K, Schropp R E I. Incorporation of p-type microcrystalline silicon films in amorphous silicon based solar cells in a superstrate structure. Sol Energy Mater Sol Cells, 1998, 53: 189–203

    Article  Google Scholar 

  5. Zhu F, Zhao Y, Wei C, et al. The effect of P layer’s crystallization on microcrystalline silicon solar cell. 20th European photovoltaic Solar Energy Conference and Exhibition, 2005, 3DV.3.6

  6. Vetterl O, Hulsbeck M, Wolff J, et al. Preparation of microcrystalline silicon seed-layers with defined structural properties. Thin Solid Films, 2003, 427: 46–50

    Article  ADS  Google Scholar 

  7. Li Y, Li L, Selvan J A, et al. Effects of seeding methods on the fabrication of microcrystalline silicon solar cells using radio frequency plasma enhanced chemical vapor deposition. Thin Solid Films, 2005, 483: 84–88

    Article  ADS  Google Scholar 

  8. Demichelis F, Pirri C F, Tresso E. Influence of doping on the structural and optoelectronic properties of amorphous and microcrystalline silicon carbide. J Appl Phys, 1992, 72(4): 1327–1333

    Article  ADS  Google Scholar 

  9. Das D, Jana M. Development of highly conducting p-type μc-Si:H films from minor diborane doping in highly hydrogenated SiH4 plasma. Mater Lett, 2004, 58: 980–985

    Article  Google Scholar 

  10. Yan B, Owens J M, Yang J, et al. High efficiency triple-junction solar cells with hydrogenated nanocrystalline silicon bottom cell. Conference Record of the 31st IEEE Photovoltaic Specialist Conference, 2006, 1456–1459

  11. Zi J, Buscher H, Falter C, et al. Raman shifts in Si nanocrystals. Appl Phys Lett, 1996, 69: 200–202

    Article  ADS  Google Scholar 

  12. He Y L, Chen G H, Zhang F Q. Physics of Amorphous Semiconductors. Beijing: Higher Education Press, 1989

    Google Scholar 

  13. Chen Z M. Amorphous Semiconductor Materials and Devices. Beijing: Science Press, 1991

    Google Scholar 

  14. Luo J S, Rong A L. Amorphous Semiconductors. Xi’an: Xi’an Jiaotong University Press, 1986

    Google Scholar 

  15. Hu Z H, Liao X B, Diao H W, et al. Hydrogenated p-type nanocrystalline silicon in amorphous silicon solar cells. J Non-Crystall Solids, 2006, 352: 1900–1903

    Article  ADS  Google Scholar 

  16. Du W H, Liao X B, Yang X S, et al. Hydrogenated nanocrystalline silicon p-layer in amorphous silicon n-i-p solar cells. Sol Energy Mater Sol Cells, 2006, 90: 1098–1104

    Article  Google Scholar 

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Correspondence to YuJie Yuan.

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Yuan, Y., Zhang, K., Wei, Z. et al. Influence of p-layer on the performance of n-i-p μc-Si:H thin film solar cells. Sci. China Phys. Mech. Astron. 53, 2042–2046 (2010). https://doi.org/10.1007/s11433-010-4143-6

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  • DOI: https://doi.org/10.1007/s11433-010-4143-6

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