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Preparation and application of gallium-based conductive materials in the very recent years

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Abstract

Gallium and its alloys are a group of metallic materials with low-melting points at or around room temperature. Apart from the good electrical conductivity, the unique liquid state endows those metals with excellent compliance and self-healing capacity, which present great value in the development of flexible and stretchable electronics. Constrained by the high surface tension and low viscosity, however, liquid metals cannot be applied to some common microelectronics manufacturing technologies such as micro-electro mechanics in the preceding years, which impedes their mass production in electronic devices. To address these issues and broaden the applications of liquid metals in electronics devices, numerous efforts have been taken and great progress has been made especially in the very recent years. This review summaries the recent development of liquid metal-based conductive materials from the aspects of preparation or modification methods and their accommodative fabrication techniques in flexible electronic applications. Further outlook including expectations and challenges of liquid metal-based conductive materials are also presented.

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References

  1. Zheng R, Peng Z, Fu Y, et al. A novel conductive core-shell particle based on liquid metal for fabricating real-time self-repairing flexible circuits. Adv Funct Mater, 2020, 30: 1910524

    Google Scholar 

  2. Wang L, Liu J. Advances in the development of liquid metal-based printed electronic inks. Front Mater, 2019, 6: 303

    Google Scholar 

  3. Wang X, Fan L, Zhang J, et al. Printed conformable liquid metal e-skin-enabled spatiotemporally controlled bioelectromagnetics for wireless multisite tumor therapy. Adv Funct Mater, 2019, 29: 1907063

    Google Scholar 

  4. Wang C, Xia K, Wang H, et al. Advanced carbon for flexible and wearable electronics. Adv Mater, 2019, 31: 1801072

    Google Scholar 

  5. Teng L, Zhu L, Handschuh-Wang S, et al. Robust, multiscale liquidmetal patterning enabled by a sacrificial sealing layer for flexible and wearable wireless powering. J Mater Chem C, 2019, 7: 15243–15251

    Google Scholar 

  6. Kim K, Choi J, Jeong Y, et al. Highly sensitive and wearable liquid metal-based pressure sensor for health monitoring applications: Integration of a 3D-printed microbump array with the microchannel. Adv Healthcare Mater, 2019, 8: 1900978

    Google Scholar 

  7. Lou Z, Chen S, Wang L, et al. An ultra-sensitive and rapid response speed graphene pressure sensors for electronic skin and health monitoring. Nano Energy, 2016, 23: 7–14

    Google Scholar 

  8. Yu Y, Zhang J, Liu J. Biomedical implementation of liquid metal ink as drawable ECG electrode and skin circuit. PLoS ONE, 2013, 8: e58771

    Google Scholar 

  9. Yan J, Lu Y, Chen G, et al. Advances in liquid metals for biomedical applications. Chem Soc Rev, 2018, 47: 2518–2533

    Google Scholar 

  10. Li M, Wu Y, Zhang L, et al. Liquid metal-based electrical interconnects and interfaces with excellent stability and reliability for flexible electronics. Nanoscale, 2019, 11: 5441–5449

    Google Scholar 

  11. Zhou L, Fu J, Gao Q, et al. All-printed flexible and stretchable electronics with pressing or freezing activatable liquid-metal-silicone inks. Adv Funct Mater, 2019, 30: 1906683

    Google Scholar 

  12. Dickey M D. Stretchable and soft electronics using liquid metals. Adv Mater, 2017, 29: 1606425

    Google Scholar 

  13. Yao B, Hong W, Chen T, et al. Highly stretchable polymer composite with strain-enhanced electromagnetic interference shielding effectiveness. Adv Mater, 2020, 32: 1907499

    Google Scholar 

  14. Woo M. Core concept: Liquid metal renaissance points to wearables, soft robots, and new materials. Proc Natl Acad Sci USA, 2020, 117: 5088–5091

    Google Scholar 

  15. Gao H, Kelly J, Zhang X, et al. A reconfigurable MIMO handset antenna employing liquid metal. IEICE Electron Express, 2019, 16: 20190485

    Google Scholar 

  16. Wang H, Yuan B, Liang S, et al. Plus-m: A porous liquid-metal enabled ubiquitous soft material. Mater Horiz, 2018, 5: 222–229

    Google Scholar 

  17. Datta R S, Syed N, Zavabeti A, et al. Flexible two-dimensional indium tin oxide fabricated using a liquid metal printing technique. Nat Electron, 2020, 3: 51–58

    Google Scholar 

  18. Buchanan C, Gardner L. Metal 3D printing in construction: A review of methods, research, applications, opportunities and challenges. Eng Struct, 2019, 180: 332–348

    Google Scholar 

  19. Xu C, Dai G, Hong Y. Recent advances in high-strength and elastic hydrogels for 3D printing in biomedical applications. Acta Biomater, 2019, 95: 50–59

    Google Scholar 

  20. Ni J, Ling H, Zhang S, et al. Three-dimensional printing of metals for biomedical applications. Mater Today Bio, 2019, 3: 100024

    Google Scholar 

  21. Fan L, Duan M, Xie Z, et al. Injectable and radiopaque liquid metal/calcium alginate hydrogels for endovascular embolization and tumor embolotherapy. Small, 2019, 16: 1903421

    Google Scholar 

  22. Guo J, Cheng J, Tan H, et al. Ga-based liquid metal: A novel current-carrying lubricant. Tribol Int, 2019, 135: 457–462

    Google Scholar 

  23. Dobosz A, Plevachuk Y, Sklyarchuk V, et al. Liquid metals in cooling systems: Experimental design of thermophysical properties of eutectic Ga-Sn-Zn alloy with Pb additions. J Mol Liq, 2019, 281: 542–548

    Google Scholar 

  24. Wang X, Guo R, Liu J. Liquid metal based soft robotics: Materials, designs, and applications. Adv Mater Technol, 2018, 1800549

  25. Kalantar-Zadeh K, Tang J, Daeneke T, et al. Emergence of liquid metals in nanotechnology. ACS Nano, 2019, 13: 7388–7395

    Google Scholar 

  26. Kim J H, Seo S. Fabrication of an imperceptible liquid metal electrode for triboelectric nanogenerator based on gallium alloys by contact printing. Appl Surf Sci, 2020, 509: 145353

    Google Scholar 

  27. Ou M, Qiu W, Huang K, et al. Ultrastretchable liquid metal electrical conductors built-in cloth fiber networks for wearable electronics. ACS Appl Mater Interfaces, 2020, 12: 7673–7678

    Google Scholar 

  28. Park Y G, An H S, Kim J Y, et al. High-resolution, reconfigurable printing of liquid metals with three-dimensional structures. Sci Adv, 2019, 5: eaaw2844

    Google Scholar 

  29. Hu L, Wang H, Wang X, et al. Magnetic liquid metals manipulated in the three-dimensional free space. ACS Appl Mater Interfaces, 2019, 11: 8685–8692

    Google Scholar 

  30. Guo J, Wang Y, Wang X, et al. On-demand manipulation of liquid metal droplet via van der Waals adhesion. Adv Mater Interfaces, 2020, 7: 2000732

    Google Scholar 

  31. Jeong J, Lee J B, Chung S K, et al. Electromagnetic three dimensional liquid metal manipulation. Lab Chip, 2019, 19: 3261–3267

    Google Scholar 

  32. Hartl D J, Frank G J, Huff G H, et al. A liquid metal-based structurally embedded vascular antenna: I. Concept and multiphysical modeling. Smart Mater Struct, 2017, 26: 025001

    Google Scholar 

  33. Muth J T, Vogt D M, Truby R L, et al. Embedded 3D printing of strain sensors within highly stretchable elastomers. Adv Mater, 2014, 26: 6307–6312

    Google Scholar 

  34. Kim M, Alrowais H, Brand O. 3D-integrated and multifunctional all-soft physical microsystems based on liquid metal for electronic skin applications. Adv Electron Mater, 2018, 4: 1700434

    Google Scholar 

  35. Liu S, Yuen M C, White E L, et al. Laser sintering of liquid metal nanoparticles for scalable manufacturing of soft and flexible electronics. ACS Appl Mater Interfaces, 2018, 10: 28232–28241

    Google Scholar 

  36. Ning N, Huang W, Liu S, et al. Highly stretchable liquid metal/polyurethane sponge conductors with excellent electrical conductivity stability and good mechanical properties. Compos Part B-Eng, 2019, 179: 107492

    Google Scholar 

  37. Liang C, Qiu H, Song P, et al. Ultra-light mxene aerogel/wood-derived porous carbon composites with wall-like “mortar/brick” structures for electromagnetic interference shielding. Sci Bull, 2020, 65: 616–622

    Google Scholar 

  38. Hou Y, Chang H, Song K, et al. Coloration of liquid-metal soft robots: From silver-white to iridescent. ACS Appl Mater Interfaces, 2018, 10: 41627–41636

    Google Scholar 

  39. Sohn Y, Chu K. Flexible hybrid conductor comprising eutectic Ga-In liquid metal and Ag nanowires for the application of electronic skin. Mater Lett, 2020, 265: 127223

    Google Scholar 

  40. Chen G, Wang H, Guo R, et al. Superelastic egain composite fibers sustaining 500% tensile strain with superior electrical conductivity for wearable electronics. ACS Appl Mater Interfaces, 2020, 12: 6112–6118

    Google Scholar 

  41. Martin J H, Yahata B D, Hundley J M, et al. 3D printing of high-strength aluminium alloys. Nature, 2017, 549: 365–369

    Google Scholar 

  42. Yu Y Z, Lu J R, Liu J. 3D printing for functional electronics by injection and package of liquid metals into channels of mechanical structures. Mater Des, 2017, 122: 80–89

    Google Scholar 

  43. Balogun H A, Sulaiman R, Marzouk S S, et al. 3D printing and surface imprinting technologies for water treatment: A review. J Water Process Eng, 2019, 31: 100786

    Google Scholar 

  44. Pan C, Kumar K, Li J, et al. Visually imperceptible liquid-metal circuits for transparent, stretchable electronics with direct laser writing. Adv Mater, 2018, 30: 1706937

    Google Scholar 

  45. Guo R, Sun X, Yuan B, et al. Magnetic liquid metal (Fe-EGaIn) based multifunctional electronics for remote self-healing materials, degradable electronics, and thermal transfer printing. Adv Sci, 2019, 6: 1901478

    Google Scholar 

  46. Chang H, Zhang P, Guo R, et al. Recoverable liquid metal paste with reversible rheological characteristic for electronics printing. ACS Appl Mater Interfaces, 2020, 12: 14125–14135

    Google Scholar 

  47. Peng Y, Liu H, Li T, et al. Hybrid metallic foam with superior elasticity, high electrical conductivity, and pressure sensitivity. ACS Appl Mater Interfaces, 2020, 12: 6489–6495

    Google Scholar 

  48. Liang S T, Liu J. Colorful liquid metal printed electronics. Sci China Tech Sci, 2017, 61: 110–116

    Google Scholar 

  49. Tang J, Zhao X, Li J, et al. Liquid metal phagocytosis: Intermetallic wetting induced particle internalization. Adv Sci, 2017, 4: 1700024

    Google Scholar 

  50. Wang Q, Yu Y, Liu J. Preparations, characteristics and applications of the functional liquid metal materials. Adv Eng Mater, 2018, 20: 1700781

    Google Scholar 

  51. Tang J, Zhao X, Li J, et al. Gallium-based liquid metal amalgams: Transitional-state metallic mixtures (TransM2ixes) with enhanced and tunable electrical, thermal, and mechanical properties. ACS Appl Mater Interfaces, 2017, 9: 35977–35987

    Google Scholar 

  52. Park Y G, Min H, Kim H, et al. Three-dimensional, high-resolution printing of carbon nanotube/liquid metal composites with mechanical and electrical reinforcement. Nano Lett, 2019, 19: 4866–4872

    Google Scholar 

  53. He X, Wu J, Hu T, et al. A 3D-printed coaxial microfluidic device approach for generating magnetic liquid metal droplets with large size controllability. Microfluid Nanofluid, 2020, 24: 30

    Google Scholar 

  54. Skylar-Scott M A, Gunasekaran S, Lewis J A. Laser-assisted direct ink writing of planar and 3D metal architectures. Proc Natl Acad Sci USA, 2016, 113: 6137–6142

    Google Scholar 

  55. Yuan B, Zhao C, Sun X, et al. Lightweight liquid metal entity. Adv Funct Mater, 2020, 30: 1910709

    Google Scholar 

  56. Chen S, Yang X, Cui Y, et al. Self-growing and serpentine locomotion of liquid metal induced by copper ions. ACS Appl Mater Interfaces, 2018, 10: 22889–22895

    Google Scholar 

  57. Wang H, Yao Y, Wang X, et al. Large-magnitude transformable liquid-metal composites. ACS Omega, 2019, 4: 2311–2319

    Google Scholar 

  58. Wang Z, Gao H, Niu J, et al. Transforming bulk metals into metallic nanostructures: A liquid-metal-assisted top-down dealloying strategy with sustainability. ACS Sustain Chem Eng, 2019, 7: 3274–3281

    Google Scholar 

  59. Yu Y, Miyako E. Alternating-magnetic-field-mediated wireless manipulations of a liquid metal for therapeutic bioengineering. iScience, 2018, 3: 134–148

    Google Scholar 

  60. Guo J, Cheng J, Wang S, et al. A protective FeGa3 film on the steel surface prepared by in-situ hot-reaction with liquid metal. Mater Lett, 2018, 228: 17–20

    Google Scholar 

  61. Park Y G, Kim H, Park S Y, et al. Instantaneous and repeatable self-healing of fully metallic electrodes at ambient conditions. ACS Appl Mater Interfaces, 2019, 11: 41497–41505

    Google Scholar 

  62. Liao M, Liao H, Ye J, et al. Polyvinyl alcohol-stabilized liquid metal hydrogel for wearable transient epidermal sensors. ACS Appl Mater Interfaces, 2019, 11: 47358–47364

    Google Scholar 

  63. Park J E, Kang H S, Baek J, et al. Rewritable, printable conducting liquid metal hydrogel. ACS Nano, 2019, 13: 9122–9130

    Google Scholar 

  64. Huang Y, Yu B, Zhang L, et al. Highly stretchable conductor by self-assembling and mechanical sintering of a 2D liquid metal on a 3D polydopamine-modified polyurethane sponge. ACS Appl Mater Interfaces, 2019, 11: 48321–48330

    Google Scholar 

  65. Shim B S, Chen W, Doty C, et al. Smart electronic yarns and wearable fabrics for human biomonitoring made by carbon nanotube coating with polyelectrolytes. Nano Lett, 2008, 8: 4151–4157

    Google Scholar 

  66. Liu Z F, Fang S, Moura F A, et al. Hierarchically buckled sheath-core fibers for superelastic electronics, sensors, and muscles. Science, 2015, 349: 400–404

    Google Scholar 

  67. Liang J, Tong K, Pei Q. A water-based silver-nanowire screen-print ink for the fabrication of stretchable conductors and wearable thin-film transistors. Adv Mater, 2016, 28: 5986–5996

    Google Scholar 

  68. Madaria A R, Kumar A, Zhou C. Large scale, highly conductive and patterned transparent films of silver nanowires on arbitrary substrates and their application in touch screens. Nanotechnology, 2011, 22: 245201

    Google Scholar 

  69. Kim Y, Zhu J, Yeom B, et al. Stretchable nanoparticle conductors with self-organized conductive pathways. Nature, 2013, 500: 59–63

    Google Scholar 

  70. Park M, Im J, Shin M, et al. Highly stretchable electric circuits from a composite material of silver nanoparticles and elastomeric fibres. Nat Nanotech, 2012, 7: 803–809

    Google Scholar 

  71. Wang D, Gao C, Wang W, et al. Shape-transformable, fusible rodlike swimming liquid metal nanomachine. ACS Nano, 2018, 12: 10212–10220

    Google Scholar 

  72. Chechetka S A, Yu Y, Zhen X, et al. Light-driven liquid metal nanotransformers for biomedical theranostics. Nat Commun, 2017, 8: 15432

    Google Scholar 

  73. Lu Y, Hu Q, Lin Y, et al. Transformable liquid-metal nanomedicine. Nat Commun, 2015, 6: 10066

    Google Scholar 

  74. Song H, Kim T, Kang S, et al. Ga-based liquid metal micro/nanoparticles: Recent advances and applications. Small, 2020, 16: 1903391

    Google Scholar 

  75. Zhang M, Yao S, Rao W, et al. Transformable soft liquid metal micro/nanomaterials. Mater Sci Eng-R-Rep, 2019, 138: 1–35

    Google Scholar 

  76. Yi L, Liu J. Liquid metal biomaterials: A newly emerging area to tackle modern biomedical challenges. Int Mater Rev, 2017, 62: 415–440

    Google Scholar 

  77. Fan L, Duan M, Sun X, et al. Injectable liquid metal- and methotrexate-loaded microsphere for cancer chemophotothermal synergistic therapy. ACS Appl Bio Mater, 2020, 3: 3553–3559

    Google Scholar 

  78. Zhang J, Sheng L, Jin C, et al. Liquid metal as connecting or functional recovery channel for the transected sciatic nerve. arXiv: 1404.5931, 2014

  79. Wang Q, Yu Y, Pan K, et al. Liquid metal angiography for mega contrast X-ray visualization of vascular network in reconstructing invitro organ anatomy. IEEE Trans Biomed Eng, 2014, 61: 2161–2166

    Google Scholar 

  80. Bartlett M D, Kazem N, Powell-Palm M J, et al. High thermal conductivity in soft elastomers with elongated liquid metal inclusions. Proc Natl Acad Sci USA, 2017, 114: 2143–2148

    Google Scholar 

  81. Yarema M, Wörle M, Rossell M D, et al. Monodisperse colloidal gallium nanoparticles: Synthesis, low temperature crystallization, surface plasmon resonance and Li-ion storage. J Am Chem Soc, 2014, 136: 12422–12430

    Google Scholar 

  82. Zhang W, Ou J Z, Tang S Y, et al. Liquid metal/metal oxide frameworks. Adv Funct Mater, 2014, 24: 3799–3807

    Google Scholar 

  83. Liang S T, Wang H Z, Liu J. Progress, mechanisms and applications of liquid-metal catalyst systems. Chem Eur J, 2018, 24: 17616–17626

    Google Scholar 

  84. Tersoff J, Jesson D E, Tang W X. Running droplets of gallium from evaporation of gallium arsenide. Science, 2009, 324: 236–238

    Google Scholar 

  85. Dubrovskii V G, Xu T, Álvarez A D, et al. Self-equilibration of the diameter of Ga-catalyzed GaAs nanowires. Nano Lett, 2015, 15: 5580–5584

    Google Scholar 

  86. Gherasimova M, Cui G, Jeon S R, et al. Droplet heteroepitaxy of gan quantum dots by metal-organic chemical vapor deposition. Appl Phys Lett, 2004, 85: 2346–2348

    Google Scholar 

  87. Zhang C, Allioux F M, Rahim M A, et al. Nucleation and growth of polyaniline nanofibers onto liquid metal nanoparticles. Chem Mater, 2020, 32: 4808–4819

    Google Scholar 

  88. Çınar S, Tevis I D, Chen J, et al. Mechanical fracturing of core-shell undercooled metal particles for heat-free soldering. Sci Rep, 2016, 6: 21864

    Google Scholar 

  89. Cutinho J, Chang B S, Oyola-Reynoso S, et al. Autonomous thermaloxidative composition inversion and texture tuning of liquid metal surfaces. ACS Nano, 2018, 12: 4744–4753

    Google Scholar 

  90. Tevis I D, Newcomb L B, Thuo M. Synthesis of liquid core-shell particles and solid patchy multicomponent particles by shearing liquids into complex particles (slice). Langmuir, 2014, 30: 14308–14313

    Google Scholar 

  91. Tang S Y, Qiao R, Yan S, et al. Microfluidic mass production of stabilized and stealthy liquid metal nanoparticles. Small, 2018, 14: 1800118

    Google Scholar 

  92. Tang S Y, Qiao R, Lin Y, et al. Functional liquid metal nanoparticles produced by liquid-based nebulization. Adv Mater Technol, 2019, 4: 1800420

    Google Scholar 

  93. Ren L, Zhuang J, Casillas G, et al. Nanodroplets for stretchable superconducting circuits. Adv Funct Mater, 2016, 26: 8111–8118

    Google Scholar 

  94. Farrell Z J, Tabor C. Control of gallium oxide growth on liquid metal eutectic gallium/indium nanoparticles via thiolation. Langmuir, 2018, 34: 234–240

    Google Scholar 

  95. Sun X, Sun M, Liu M, et al. Shape tunable gallium nanorods mediated tumor enhanced ablation through near-infrared photothermal therapy. Nanoscale, 2019, 11: 2655–2667

    Google Scholar 

  96. Moon K S, Dong H, Maric R, et al. Thermal behavior of silver nanoparticles for low-temperature interconnect applications. J Elec Materi, 2005, 34: 168–175

    Google Scholar 

  97. Perelaer J, Klokkenburg M, Hendriks C E, et al. Microwave flash sintering of inkjet-printed silver tracks on polymer substrates. Adv Mater, 2009, 21: 4830–4834

    Google Scholar 

  98. Angmo D, Larsen-Olsen T T, Jørgensen M, et al. Roll-to-roll inkjet printing and photonic sintering of electrodes for ITO free polymer solar cell modules and facile product integration. Adv Energy Mater, 2013, 3: 172–175

    Google Scholar 

  99. Chung J, Ko S, Bieri N R, et al. Conductor microstructures by laser curing of printed gold nanoparticle ink. Appl Phys Lett, 2004, 84: 801–803

    Google Scholar 

  100. Reinhold I, Hendriks C E, Eckardt R, et al. Argon plasma sintering of inkjet printed silver tracks on polymer substrates. J Mater Chem, 2009, 19: 3384–3388

    Google Scholar 

  101. Walker S B, Lewis J A. Reactive silver inks for patterning high-conductivity features at mild temperatures. J Am Chem Soc, 2012, 134: 1419–1421

    Google Scholar 

  102. Magdassi S, Grouchko M, Berezin O, et al. Triggering the sintering of silver nanoparticles at room temperature. ACS Nano, 2010, 4: 1943–1948

    Google Scholar 

  103. Grouchko M, Kamyshny A, Mihailescu C F, et al. Conductive inks with a “built-in” mechanism that enables sintering at room temperature. ACS Nano, 2011, 5: 3354–3359

    Google Scholar 

  104. Ko S H, Pan H, Grigoropoulos C P, et al. All-inkjet-printed flexible electronics fabrication on a polymer substrate by low-temperature high-resolution selective laser sintering of metal nanoparticles. Nanotechnology, 2007, 18: 345202

    Google Scholar 

  105. Boley J W, White E L, Kramer R K. Mechanically sintered galliumindium nanoparticles. Adv Mater, 2015, 27: 2355–2360

    Google Scholar 

  106. Lin Y, Cooper C, Wang M, et al. Handwritten, soft circuit boards and antennas using liquid metal nanoparticles. Small, 2015, 11: 6397–6403

    Google Scholar 

  107. Li F, Qin Q, Zhou Y, et al. Recyclable liquid metal-based circuit on paper. Adv Mater Technol, 2018, 3: 1800131

    Google Scholar 

  108. Yang Y, Han J, Huang J, et al. Stretchable energy-harvesting tactile interactive interface with liquid-metal-nanoparticle-based electrodes. Adv Funct Mater, 2020, 30: 1909652

    Google Scholar 

  109. Li X, Li M, Zong L, et al. Liquid metal droplets wrapped with polysaccharide microgel as biocompatible aqueous ink for flexible conductive devices. Adv Funct Mater, 2018, 28: 1804197

    Google Scholar 

  110. David R, Miki N. Synthesis of sub-micrometer biphasic Au-AuGa2/liquid metal frameworks. Nanoscale, 2019, 11: 21419–21432

    Google Scholar 

  111. Tang J, Zhao X, Li J, et al. Thin, porous, and conductive networks of metal nanoparticles through electrochemical welding on a liquid metal template. Adv Mater Interfaces, 2018, 5: 1800406

    Google Scholar 

  112. Liu S, Reed S N, Higgins M J, et al. Oxide rupture-induced conductivity in liquid metal nanoparticles by laser and thermal sintering. Nanoscale, 2019, 11: 17615–17629

    Google Scholar 

  113. Deng B, Cheng G J. Pulsed laser modulated shock transition from liquid metal nanoparticles to mechanically and thermally robust solid-liquid patterns. Adv Mater, 2019, 31: 1807811

    Google Scholar 

  114. Li X, Li M, Xu J, et al. Evaporation-induced sintering of liquid metal droplets with biological nanofibrils for flexible conductivity and responsive actuation. Nat Commun, 2019, 10: 3514

    Google Scholar 

  115. Wang J, Cai G, Li S, et al. Printable superelastic conductors with extreme stretchability and robust cycling endurance enabled by liquid-metal particles. Adv Mater, 2018, 30: 1706157

    Google Scholar 

  116. Silva C A, Lv J, Yin L, et al. Liquid metal based island-bridge architectures for all printed stretchable electrochemical devices. Adv Funct Mater, 2020, 30: 2002041

    Google Scholar 

  117. Wu Y, Deng Z, Peng Z, et al. A novel strategy for preparing stretchable and reliable biphasic liquid metal. Adv Funct Mater, 2019, 29: 1903840

    Google Scholar 

  118. Wang Y, Duan W, Zhou C, et al. Phoretic liquid metal micro/nanomotors as intelligent filler for targeted microwelding. Adv Mater, 2019, 31: 1905067

    Google Scholar 

  119. Tavakoli M, Malakooti M H, Paisana H, et al. Egain-assisted room-temperature sintering of silver nanoparticles for stretchable, inkjetprinted, thin-film electronics. Adv Mater, 2018, 30: 1801852

    Google Scholar 

  120. Sun Z, Wang L, Jiang X, et al. Self-healing, sensitive and antifreezing biomass nanocomposite hydrogels based on hydroxypropyl guar gum and application in flexible sensors. Int J Biol Macromolecules, 2020, 155: 1569–1577

    Google Scholar 

  121. Markvicka E J, Bartlett M D, Huang X, et al. An autonomously electrically self-healing liquid metal-elastomer composite for robust soft-matter robotics and electronics. Nat Mater, 2018, 17: 618–624

    Google Scholar 

  122. Shay T, Velev O D, Dickey M D. Softelectrodes combining hydrogel and liquid metal. Soft Matter, 2018, 14: 3296–3303

    Google Scholar 

  123. Choi Y Y, Ho D H, Cho J H. Self-healable hydrogel-liquid metal composite platform enabled by a 3D printed stamp for a multimodular sensor system. ACS Appl Mater Interfaces, 2020, 12: 9824–9832

    Google Scholar 

  124. Merhebi S, Mayyas M, Abbasi R, et al. Magnetic and conductive liquid metal gels. ACS Appl Mater Interfaces, 2020, 12: 20119–20128

    Google Scholar 

  125. Xu J, Wang Z, You J, et al. Polymerization of moldable self-healing hydrogel with liquid metal nanodroplets for flexible strain-sensing devices. Chem Eng J, 2020, 392: 123788

    Google Scholar 

  126. Peng H, Xin Y, Xu J, et al. Ultra-stretchable hydrogels with reactive liquid metals as asymmetric force-sensors. Mater Horiz, 2019, 6: 618–625

    Google Scholar 

  127. Pan C, Markvicka E J, Malakooti M H, et al. A liquid-metal-elastomer nanocomposite for stretchable dielectric materials. Adv Mater, 2019, 31: 1900663

    Google Scholar 

  128. Tutika R, Kmiec S, Haque A B M T, et al. Liquid metal-elastomer soft composites with independently controllable and highly tunable droplet size and volume loading. ACS Appl Mater Interfaces, 2019, 11: 17873–17883

    Google Scholar 

  129. Fassler A, Majidi C. Liquid-phase metal inclusions for a conductive polymer composite. Adv Mater, 2015, 27: 1928–1932

    Google Scholar 

  130. Blaiszik B J, Kramer S L B, Grady M E, et al. Autonomic restoration of electrical conductivity. Adv Mater, 2012, 24: 398–401

    Google Scholar 

  131. Wang H, Yao Y, He Z, et al. A highly stretchable liquid metal polymer as reversible transitional insulator and conductor. Adv Mater, 2019, 31: 1901337

    Google Scholar 

  132. Yun G, Tang S Y, Sun S, et al. Liquid metal-filled magnetorheological elastomer with positive piezoconductivity. Nat Commun, 2019, 10: 1300

    Google Scholar 

  133. Idrus-Saidi S A, Tang J, Yang J, et al. Liquid metal-based route for synthesizing and tuning gas-sensing elements. ACS Sens, 2020, 5: 1177–1189

    Google Scholar 

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Correspondence to Liang Hu.

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This work was supported by the 111 Project (Grant No. B13003), the National Natural Science Foundation of China (Grant No. 81801794) and the Open Laboratory Foundation of the Chinese Academy of Sciences (Grant No. CRY0201915).

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Wang, X., Guo, J. & Hu, L. Preparation and application of gallium-based conductive materials in the very recent years. Sci. China Technol. Sci. 64, 681–695 (2021). https://doi.org/10.1007/s11431-020-1733-x

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