Skip to main content
Log in

Improved conversion efficiency of dye-sensitized solar cells by using novel complex nanostructured TiO2 electrodes

  • Published:
Science China Technological Sciences Aims and scope Submit manuscript

Abstract

A novel complex nanostructured TiO2 electrode and fabrication process were proposed and demonstrated to improve the performance of dye-sensitized solar cells (DSSCs). In the proposed process, a nanoporous TiO2 layer was firstly fabricated on the FTO (fluorine-doped tin oxide) conducting substrate by an anodization process, then a nanoparticulate TiO2 film was deposited on the nanoporous TiO2 layer by the screen printed method to form the complex nanostructured TiO2 electrode. The experiments demonstrated that the nanoporous TiO2 layer can enhance the light scattering, decrease the contact resistance between TiO2 electrode and FTO, and suppress the recombination of I 3 ion with the injected electrons of FTO. The process variables are crucial to obtain the optimized performance of DSSCs. By adopting the optimized process, improved conversion efficiency of DSSCs was achieved at AM 1.5 sunlight.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. O’Regan B, Grätzel B. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature, 1991, 353: 737–740

    Article  Google Scholar 

  2. Grätzel M. Photoelectrochemical cells. Nature, 2001, 414: 338–344

    Article  Google Scholar 

  3. Chiba Y, Islam A, Watanabe Y, et al. Dye-sensitized solar cells with conversion efficiency of 11.1%. Jpn J Appl Phys, 2006, 45: L638–L640

    Article  Google Scholar 

  4. Hu L, Dai S, Weng J, et al. Microstructure design of nanoporous TiO2 photoelectrodes for dye-sensitized solar cell modules. J Phys Chem B, 2007, 111: 358–362

    Article  Google Scholar 

  5. Jiu J, Isoda S, Adachi M, et al. Preparation of TiO2 nanocrystalline with 3-5 nm and application for dye-sensitized solar cell. J Photoch Photobio A, 2007, 189: 314–321

    Article  Google Scholar 

  6. Zhou Y F, Li X P, Zhang J B, et al. Performances improvement of eosin Y sensitized solar cells by modifying TiO2 electrode with silane-coupling reagent. Chin Sci Bull, 2009, 54: 2633–2640

    Article  Google Scholar 

  7. Nguyen T V, Lee H C, Yang O. The effects of pre-thermal treatment of TiO2 nano-particles on the performances of dye-sensitized solar cells. Sol Energ Mat Sol C, 2006, 90: 967–981

    Article  Google Scholar 

  8. Grätzel M. Dye-sensitized solar cells. J Photoch Photobio C, 2003, 4: 145–153

    Article  Google Scholar 

  9. Ma B B, Gao R, Wang L D, et al. Recent progress in interface modification for dye-sensitized solar cells. Sci China Chem, 2010, 53: 1669–1678

    Article  Google Scholar 

  10. Law M, Greene L E, Johnson J C, et al. Nanowire dye-sensitized solar cells. Nat Mater, 2005, 4: 455–459

    Article  Google Scholar 

  11. Mor G K, Shankar K, Paulose M, et al. Enhanced photocleavage of water using titania nanotube arrays. Nano Lett, 2005, 5: 191–195

    Article  Google Scholar 

  12. Yoon J H, Jang S R, Vittal R, et al. TiO2 nanorods as additive to TiO2 film for improvement in the performance of dye-sensitized solar cells. J Photochem Photobiol A, 2006, 180: 184–188

    Article  Google Scholar 

  13. Luo J Q, Gao L, Sun J, et al. A bilayer structure of a titania nanoparticle/ highly-ordered nanotube array for low-temperature dye-sensi-tized solar cells. RSC Adv, 2012, 2: 1884–1889

    Article  Google Scholar 

  14. Miao Q Q, Wu L Q, Cui J N, et al. A new type of dye-sensitized solar cell with a multilayered photoanode prepared by a film-transfer technique. Adv Mater, 2011, 23: 2764–2768

    Article  Google Scholar 

  15. Wang H, Liu Y, Li M, et al. Hydrothermal growth oflarge-scale macroporous TiO2 nanowires and its application in 3D dye sensitized solar cells. Appl Phys A, 2009, 97: 25–29

    Article  Google Scholar 

  16. Tsai T Y, Lu S Y. A novel way of improving light harvesting in dye-sensitized solar cells-electrodeposition of titania. Electrochem Commun, 2009, 11: 2180–2183

    Article  Google Scholar 

  17. Kang T S, Smith A P, Taylor B E, et al. Fabrication of highly-ordered TiO2 nanotube arrays and their use in dye-sensitized solar cells. Nano Lett, 2009, 9: 601–606

    Article  Google Scholar 

  18. Wang C X, Zhang X D, Wang D F, et al. Synthesis of nanostructural ZnO using hydrothermal method for dye-sensitized solar cells. Sci China Tech Sci, 2010, 53: 1146–1149

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to LiFeng Liu or JinFeng Kang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhang, T., Liu, L., Yang, F. et al. Improved conversion efficiency of dye-sensitized solar cells by using novel complex nanostructured TiO2 electrodes. Sci. China Technol. Sci. 56, 115–119 (2013). https://doi.org/10.1007/s11431-012-5012-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11431-012-5012-5

Keywords

Navigation