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Electrodeposition in organic system and properties of NiO electrochromic films

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Abstract

By electrodeposition in organic system, NiO films with reversible electrochromic property were fabricated. Fluorine-doped tin oxide glass slices were used as substrates, i.e. cathodes. Cyclic voltammetry and ultraviolet-visible transmission spectroscopy were adopted to study the electrochromic properties of the films. High resolution transmission electron microscopy (HRTEM) was employed to analyze the composition and structure of the films. It is found that the films are composed of fine NiO crystal grains of a few nanometers in diameter, endowing them with large visible light transmittance variation, rapid switch rate (i.e. rapid response time) between the bleached and colored states. Their cycling durability reached 6000 cycles.

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References

  1. Granqvist C G, Avendaño E, Azens A. Electrochromic coatings and devices: survey of some recent advances. Thin Solid Films, 2003, 442: 201–211

    Article  Google Scholar 

  2. Granqvist C G. Electrochromic devices. J Eur Ceram Soc, 2005, 25: 2907–2912

    Article  Google Scholar 

  3. Granqvist C G. Oxide electrochromics: why, how, and whither. Sol Energy Mater Sol Cells, 2008, 92: 203–208

    Article  Google Scholar 

  4. Granqvist C G. Solar energy materials. Adv Mater, 2003, 15: 1789–1803

    Article  Google Scholar 

  5. Avendaño E, Berggren L, Niklasson G A, et al. Electrochromic materials and devices: brief survey and new data on optical absorption in tungsten oxide and nickel oxide films. Thin Solid Films, 2006, 496: 30–36

    Article  Google Scholar 

  6. Hu X F, Chen X F, Li Z Y, et al. Study on the solid NiO/WO3 complementary structure. Sci China Ser E-Tech Sci, 1997, 27: 122–125

    Google Scholar 

  7. Sasi B, Gopchandran K G, Manoj P K, et al. Preparation of transparent and semiconducting NiO films. Vacuum, 2002, 68: 149–154

    Article  Google Scholar 

  8. Desai J D, Min S K, Jung K D, et al. Spray pyrolytic synthesis of large area NiOx thin films from aqueous nickel acetate solutions. Appl Surf Sci, 2006, 253: 1781–1786

    Article  Google Scholar 

  9. Ryu H W, Choi G P, Lee W S, et al. Preferred orientations of NiO thin films prepared by RF magnetron sputtering. J Mater Sci, 2004, 39: 4375–4377

    Article  Google Scholar 

  10. Vidales-Hurtado M A, Mendoza-Galván A. Optical and structural characterization of nickel oxide-based thin films obtained by chemical bath deposition. Mater Chem Phys, 2008, 107: 33–38

    Article  Google Scholar 

  11. Korošec R C, Bukovec P. Sol-gel prepared NiO thin films for electrochromic applications. Acta Chim Slov, 2006, 53: 136–147

    Google Scholar 

  12. Tanaka M, Mukai M, Fujimori Y, et al. Transition metal oxide films prepared by pulsed laser deposition for atomic beam detection. Thin Solid Films, 1996, 281–282: 453–456

    Article  Google Scholar 

  13. Uplane M M, Mujawar S H, Inamdar A I, et al. Structural, optical and electrochromic properties of nickel oxide thin films grown from electrodeposited nickel sulphide. Appl Surf Sci, 2007, 253: 9365–9371

    Article  Google Scholar 

  14. Nakaoka K, Ueyama J, Ogura K. Semiconductor and electrochromic properties of electrochemically deposited nickel oxide films. J Electroanal Chem, 2004, 571: 93–99

    Article  Google Scholar 

  15. Sonavane A C, Inamdar A I, Shinde P S, et al. Efficient electrochromic nickel oxide thin films by electrodeposition. J Alloys Comp, 2010, 489: 667–673

    Article  Google Scholar 

  16. Yuan D, Liu G, Tong Y. Electrochemical behavior of Tm3+ ion and cyclic electrodeposition of a Tm-Co alloy film in dimethylsulfoxide. J Electroanal Chem, 2002, 536: 123–127

    Article  Google Scholar 

  17. Kadam L D, Patil P S. Studies on electrochromic properties of nickel oxide thin films prepared by spray pyrolysis technique. Sol Energy Mater Sol Cells, 2001, 69: 361–369

    Article  Google Scholar 

  18. Xia X H, Tu J P, Zhang J, et al. Electrochromic properties of porous NiO thin films prepared by a chemical bath deposition. Sol Energy Mater Sol Cells, 2008, 92: 628–633

    Article  Google Scholar 

  19. Wang Z, Hu X. Electrochromic properties of TiO2-doped WO3 films spin-coated from Ti-stabilized peroxotungstic acid. Electrochim Acta, 2001, 46: 1951–1956

    Article  Google Scholar 

  20. Maruyama T, Arai S. The electrochromic properties of nickel oxide thin films prepared by chemical vapor deposition. Sol Energy Mater Sol Cells, 1993, 30: 257–262

    Article  Google Scholar 

  21. Bouessay I, Rougier A, Beaudoin B, et al. Pulsed laser-deposited nickel oxide thin films as electrochromic anodic materials. Appl Surf Sci, 2002, 186: 490–495

    Article  Google Scholar 

  22. Arakaki J, Reyes R, Horn M, et al. Electrochromism in NiOx and WOx obtained by spray pyrolysis. Sol Energy Mater Sol Cells, 1995, 37: 33–41

    Article  Google Scholar 

  23. Park J Y, Ahn K S, Nah Y C, et al. Electrochemical and electrochromic properties of Ni oxide thin films prepared by a sol-gel method. J Sol-Gel Sci Technol, 2004, 31: 323–328

    Article  Google Scholar 

  24. Cheng K C, Kai J J, Chen F R. Improving the durability of Prussian blue based on nano-composite thin film in Li+ based liquid electrolyte. Electrochim Acta, 2007, 52: 6554–6560

    Article  Google Scholar 

  25. Sato Y, Ando M, Murai K. Electrochromic properties of spin-coated nickel oxide films. Solid State Ionics, 1998, 113–115: 443–447

    Article  Google Scholar 

  26. Sac-Epée N, Palacín M R, Beaudoin B, et al. On the origin of the second low-voltage plateau in secondary alkaline batteries with nickel hydroxide positive electrodes. J Electrochem Soc, 1997, 144: 3896–3907

    Article  Google Scholar 

  27. Lin S H, Chen F R, Kai J J. Electrochromic properties of nano-composite nickel oxide film. Appl Surf Sci, 2008, 254: 3357–3363

    Article  Google Scholar 

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Correspondence to Ge Su.

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Su, G., Song, M., Sun, W. et al. Electrodeposition in organic system and properties of NiO electrochromic films. Sci. China Technol. Sci. 55, 1545–1550 (2012). https://doi.org/10.1007/s11431-012-4858-x

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  • DOI: https://doi.org/10.1007/s11431-012-4858-x

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