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Template-free synthesis of hollow carbon-based nanostructures from MOFs for rechargeable battery applications

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Abstract

Hollow carbon-based nanostructures (HCNs) have found broad applications in various fields, particularly rechargeable batteries. However, the syntheses of HCNs usually rely on template methods, which are time-consuming, low-yield, and environmentally detrimental. Metal-organic frameworks (MOFs), constructed by organic ligands and inorganic metal nodes, have been identified as effect platforms for preparing HCNs without adding extra templates. This review summarized the recent progress in template-free synthesis of HCNs enabled by MOFs and their applications in rechargeable batteries. Different template-free strategies were introduced first with mechanistic insights into the hollowing mechanism. Then the electrochemical performances of the HCNs were discussed with highlight on the structure-function correlation. It is found that the built-in cavities and nonporous for HCNs is of critical importance to increase the storage sites for high capacity, to enhance charge and mass transport kinetics for high-rate capability, and to ensure the resilient electrode structure for stable cycling. Finally, the challenges and opportunities regarding MOFs-derived HCNs and their applications in rechargeable batteries were discussed.

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References

  1. Wang J, Wan J, Yang N, Li Q, Wang D. Nat Rev Chem, 2020, 4: 159–168

    CAS  PubMed  Google Scholar 

  2. Bi R, Xu N, Ren H, Yang N, Sun Y, Cao A, Yu R, Wang D. Angew Chem, 2020, 132: 4895–4898

    Google Scholar 

  3. Tian H, Tian H, Wang S, Chen S, Zhang F, Song L, Liu H, Liu J, Wang G. Nat Commun, 2020, 11: 5025

    CAS  PubMed  PubMed Central  Google Scholar 

  4. Liu L, Yin YX, Li JY, Li NW, Zeng XX, Ye H, Guo YG, Wan LJ. Joule, 2017, 1: 563–575

    CAS  Google Scholar 

  5. Liu J, Wickramaratne NP, Qiao SZ, Jaroniec M. Nat Mater, 2015, 14: 763–774

    CAS  PubMed  Google Scholar 

  6. Xu M, Liu Y, Yu Q, Feng S, Zhou L, Mai L. Chin Chem Lett, 2021, 32: 184–189

    CAS  Google Scholar 

  7. Bin DS, Li Y, Sun YG, Duan SY, Lu Y, Ma J, Cao AM, Hu YS, Wan LJ. Adv Energy Mater, 2018, 8: 1800855

    Google Scholar 

  8. Bin DS, Chi ZX, Li Y, Zhang K, Yang X, Sun YG, Piao JY, Cao AM, Wan LJ. J Am Chem Soc, 2017, 139: 13492–13498

    CAS  PubMed  Google Scholar 

  9. Bin DS, Lin XJ, Sun YG, Xu YS, Zhang K, Cao AM, Wan LJ. J Am Chem Soc, 2018, 140: 7127–7134

    CAS  PubMed  Google Scholar 

  10. Yan K, Lu Z, Lee HW, Xiong F, Hsu PC, Li Y, Zhao J, Chu S, Cui Y. Nat Energy, 2016, 1: 16010

    CAS  Google Scholar 

  11. Roberts AD, Li X, Zhang H. Chem Soc Rev, 2014, 43: 4341–4356

    CAS  PubMed  Google Scholar 

  12. Piao J, Bin D, Duan S, Lin X, Zhang D, Cao A. Sci China Chem, 2018, 61: 538–544

    CAS  Google Scholar 

  13. Liu B, Shioyama H, Akita T, Xu Q. J Am Chem Soc, 2008, 130: 5390–5391

    CAS  PubMed  Google Scholar 

  14. Yang W, Li X, Li Y, Zhu R, Pang H. Adv Mater, 2019, 31: 1804740

    Google Scholar 

  15. Cai ZX, Wang ZL, Kim J, Yamauchi Y. Adv Mater, 2019, 31: 1804903

    Google Scholar 

  16. Yan J, Cui Y, Xie M, Yang GZ, Bin DS, Li D. Angew Chem, 2021, 133: 24672–24677

    Google Scholar 

  17. Dang S, Zhu QL, Xu Q. Nat Rev Mater, 2017, 3: 17075

    Google Scholar 

  18. Wang C, Kim J, Tang J, Kim M, Lim H, Malgras V, You J, Xu Q, Li J, Yamauchi Y. Chem, 2020, 6: 19–40

    CAS  Google Scholar 

  19. Pachfule P, Shinde D, Majumder M, Xu Q. Nat Chem, 2016, 8: 718–724

    CAS  PubMed  Google Scholar 

  20. Wang Z, Yang N, Wang D. Chem Sci, 2020, 11: 5359–5368

    CAS  PubMed  PubMed Central  Google Scholar 

  21. Zeng H, Xie M, Wang T, Wei RJ, Xie XJ, Zhao Y, Lu W, Li D. Nature, 2021, 595: 542–548

    CAS  PubMed  Google Scholar 

  22. Zhang W, Jiang X, Zhao Y, Carné-Sánchez A, Malgras V, Kim J, Kim JH, Wang S, Liu J, Jiang JS, Yamauchi Y, Hu M. Chem Sci, 2017, 8: 3538–3546

    CAS  PubMed  PubMed Central  Google Scholar 

  23. Wei YS, Zhang M, Kitta M, Liu Z, Horike S, Xu Q. J Am Chem Soc, 2019, 141: 7906–7916

    CAS  PubMed  Google Scholar 

  24. Liu W, Huang J, Yang Q, Wang S, Sun X, Zhang W, Liu J, Huo F. Angew Chem Int Ed, 2017, 56: 5512–5516

    CAS  Google Scholar 

  25. Liu S, Wang Z, Zhou S, Yu F, Yu M, Chiang CY, Zhou W, Zhao J, Qiu J. Adv Mater, 2017, 29: 1700874

    Google Scholar 

  26. Liu P, Gao S, Zhang G, Huang Y, You W, Che R. Adv Funct Mater, 2021, 31: 2102812

    CAS  Google Scholar 

  27. Zhang H, Shen Y, Tian D, Huo F. Chin Sci Bull, 2019, 64: 3632–3639

    Google Scholar 

  28. Hu M, Belik AA, Imura M, Yamauchi Y. J Am Chem Soc, 2013, 135: 384–391

    CAS  PubMed  Google Scholar 

  29. Yu D, Shao Q, Song Q, Cui J, Zhang Y, Wu B, Ge L, Wang Y, Zhang Y, Qin Y, Vajtai R, Ajayan PM, Wang H, Xu T, Wu Y. Nat Commun, 2020, 11: 927

    CAS  PubMed  PubMed Central  Google Scholar 

  30. Xu X, Sun Y, Zhang Q, Wang S, Zhang L, Wu Z, Lu G. Chem Select, 2016, 1: 1763–1767

    CAS  Google Scholar 

  31. Chen H, Shen K, Tan Y, Li Y. ACS Nano, 2019, 13: 7800–7810

    CAS  PubMed  Google Scholar 

  32. Pan Y, Sun K, Liu S, Cao X, Wu K, Cheong WC, Chen Z, Wang Y, Li Y, Liu Y, Wang D, Peng Q, Chen C, Li Y. J Am Chem Soc, 2018, 140: 2610–2618

    CAS  PubMed  Google Scholar 

  33. Zhao R, Liang Z, Gao S, Yang C, Zhu B, Zhao J, Qu C, Zou R, Xu Q. Angew Chem, 2019, 131: 1997–2001

    Google Scholar 

  34. Huang Y, Fang Y, Lu XF, Luan D, Lou XWD. Angew Chem, 2020, 132: 20086–20090

    Google Scholar 

  35. Xu H, Zhao L, Liu X, Huang Q, Wang Y, Hou C, Hou Y, Wang J, Dang F, Zhang J. Adv Funct Mater, 2020, 30: 2006188

    CAS  Google Scholar 

  36. Shi H, Ren X, Lu J, Dong C, Liu J, Yang Q, Chen J, Wu ZS. Adv Energy Mater, 2020, 10: 2002271

    CAS  Google Scholar 

  37. Chen T, Zhang Z, Cheng B, Chen R, Hu Y, Ma L, Zhu G, Liu J, Jin Z. J Am Chem Soc, 2017, 139: 12710–12715

    CAS  PubMed  Google Scholar 

  38. Dong S, Li C, Ge X, Li Z, Miao X, Yin L. ACS Nano, 2017, 11: 6474–6482

    CAS  PubMed  Google Scholar 

  39. Chen X, Zeng S, Muheiyati H, Zhai YJ, Li C, Ding X, Wang L, Wang D, Xu L, He Y, Qian Y. ACS Energy Lett, 2019, 4: 1496–1504

    CAS  Google Scholar 

  40. Zhou K, Qiu R, Zhen Y, Huang Z, Mathur S, Hong Z. Small, 2021, 17: 2100538

    CAS  Google Scholar 

  41. Yan L, Xu Y, Chen P, Zhang S, Jiang H, Yang L, Wang Y, Zhang L, Shen J, Zhao X, Wang L. Adv Mater, 2020, 32: 2003313

    CAS  Google Scholar 

  42. Zhang P, Li J, Feng J, Wang Y, Xu A, Chen T, Zhao L, Dang F, Zhang X, Wang H. Chin Chem Lett, 2021, 32: 2438–2442

    CAS  Google Scholar 

  43. Ding H, Zhang XK, Fan JQ, Zhan XQ, Xie L, Shi D, Jiang T, Tsai FC. ACS Omega, 2019, 4: 13241–13249

    CAS  PubMed  PubMed Central  Google Scholar 

  44. Bin DS, Xu YS, Guo SJ, Sun YG, Cao AM, Wan LJ. Acc Chem Res, 2020, 54: 221–231

    PubMed  Google Scholar 

  45. Luo JM, Sun YG, Guo SJ, Xu YS, Chang BB, Liu CT, Cao AM, Wan LJ. Mater Chem Front, 2020, 4: 2283–2306

    CAS  Google Scholar 

  46. Sun YG, Piao JY, Hu LL, Bin DS, Lin XJ, Duan SY, Cao AM, Wan LJ. J Am Chem Soc, 2018, 140: 9070–9073

    CAS  PubMed  Google Scholar 

  47. Kim M, Xu X, Xin R, Earnshaw J, Ashok A, Kim J, Park T, Nanjundan AK, El-Said WA, Yi JW, Na J, Yamauchi Y. ACS Appl Mater Interfaces, 2021, 13: 52034–52043

    CAS  PubMed  Google Scholar 

  48. Wong YJ, Zhu L, Teo WS, Tan YW, Yang Y, Wang C, Chen H. J Am Chem Soc, 2011, 133: 11422–11425

    CAS  PubMed  Google Scholar 

  49. Tao XS, Sun YG, Liu Y, Chang BB, Liu CT, Xu YS, Yang XC, Cao AM. ACS Appl Mater Interfaces, 2020, 12: 13182–13188

    CAS  PubMed  Google Scholar 

  50. Kim M, Park T, Wang C, Tang J, Lim H, Hossain MSA, Konarova M, Yi JW, Na J, Kim J, Yamauchi Y. ACS Appl Mater Interfaces, 2020, 12: 34065–34073

    CAS  PubMed  Google Scholar 

  51. Wang C, Kim J, Tang J, Na J, Kang YM, Kim M, Lim H, Bando Y, Li J, Yamauchi Y. Angew Chem, 2020, 132: 2082–2086

    Google Scholar 

  52. Liu L, Yin YX, Li JY, Wang SH, Guo YG, Wan LJ. Adv Mater, 2018, 30: 1706216

    Google Scholar 

  53. Cao D, Yin C, Shi D, Fu Z, Zhang J, Li C. Adv Funct Mater, 2017, 27: 1701130

    Google Scholar 

  54. Luo W, Tang F, Jiang Y, Liu L, Sun W, Feng Y, Pan H, Rui X, Yu Y. Adv Funct Mater, 2022, 32: 2200178

    CAS  Google Scholar 

  55. Xia X, Du C-, Zhong S, Jiang Y, Yu H, Sun W, Pan H, Rui X, Yu Y. Adv Funct Mater, 2021, 32: 2110280

    Google Scholar 

  56. Zhang W, Xia H, Zhu Z, Lv Z, Cao S, Wei J, Luo Y, Xiao Y, Liu L, Chen X. CCS Chem, 2021, 3: 1245–1255

    CAS  Google Scholar 

  57. Guo Y, Wu S, He YB, Kang F, Chen L, Li H, Yang QH. eScience, 2022, 2: 138–163

    Google Scholar 

  58. Chen K, Lei M, Yao Z, Zheng Y, Hu J, Lai C, Li C. Sci Adv, 2021, 7: eabj1491

    CAS  PubMed  PubMed Central  Google Scholar 

  59. Boebinger MG, Yarema O, Yarema M, Unocic KA, Unocic RR, Wood V, McDowell MT. Nat Nanotechnol, 2020, 15: 475–481

    CAS  PubMed  Google Scholar 

  60. Li M, Lu J, Ji X, Li Y, Shao Y, Chen Z, Zhong C, Amine K. Nat Rev Mater, 2020, 5: 276–294

    CAS  Google Scholar 

  61. Li Z, Guo X. Sci China Chem, 2021, 64: 673–680

    CAS  Google Scholar 

  62. Gu ZY, Guo JZ, Sun ZH, Zhao XX, Li WH, Yang X, Liang HJ, Zhao CD, Wu XL. Sci Bull, 2020, 65: 702–710

    CAS  Google Scholar 

  63. Choi J, Jeong H, Jang J, Jeon AR, Kang I, Kwon M, Hong J, Lee M. J Am Chem Soc, 2021, 143: 9169–9176

    CAS  PubMed  Google Scholar 

  64. Shi Y, Liu GX, Wan J, Wen R, Wan LJ. Sci China Chem, 2021, 64: 734–738

    CAS  Google Scholar 

  65. Zhang S, Liu Y, Qi M, Cao A. Acta Phys Chim Sin, 2021, 37: 2011007

    Google Scholar 

  66. Xu B, Qi S, Li F, Peng X, Cai J, Liang J, Ma J. Chin Chem Lett, 2020, 31: 217–222

    CAS  Google Scholar 

  67. Hou BH, Wang YY, Guo JZ, Zhang Y, Ning QL, Yang Y, Li WH, Zhang JP, Wang XL, Wu XL. ACS Appl Mater Interfaces, 2018, 10: 3581–3589

    CAS  PubMed  Google Scholar 

  68. Chi X, Li M, Di J, Bai P, Song L, Wang X, Li F, Liang S, Xu J, Yu J. Nature, 2021, 592: 551–557

    CAS  PubMed  Google Scholar 

  69. Yan Z, Yang QW, Wang Q, Ma J. Chin Chem Lett, 2020, 31: 583–588

    CAS  Google Scholar 

  70. Du W, Yin Y, Guo Y, Wan LJ. Sci Sin Chim, 2016, 46: 1110–1118

    Google Scholar 

  71. Kim M, Fernando JFS, Wang J, Nanjundan AK, Na J, Hossain MSA, Nara H, Martin D, Sugahara Y, Golberg D, Yamauchi Y. Chem Commun, 2022, 58: 863–866

    CAS  Google Scholar 

  72. Zhou L, Zhuang Z, Zhao H, Lin M, Zhao D, Mai L. Adv Mater, 2017, 29: 1602914

    Google Scholar 

  73. Wang J, Tang H, Zhang L, Ren H, Yu R, Jin Q, Qi J, Mao D, Yang M, Wang Y, Liu P, Zhang Y, Wen Y, Gu L, Ma G, Su Z, Tang Z, Zhao H, Wang D. Nat Energy, 2016, 1: 16050

    CAS  Google Scholar 

  74. Sun YG, Sun TQ, Lin XJ, Tao XS, Zhang D, Zeng C, Cao AM, Wan LJ. Sci China Chem, 2018, 61: 670–676

    CAS  Google Scholar 

  75. Aurbach D, Markovsky B, Weissman I, Levi E, Ein-Eli Y. Electrochim Acta, 1999, 45: 67–86

    CAS  Google Scholar 

  76. Billaud J, Bouville F, Magrini T, Villevieille C, Studart AR. Nat Energy, 2016, 1: 16097

    CAS  Google Scholar 

  77. Wang SH, Yue J, Dong W, Zuo TT, Li JY, Liu X, Zhang XD, Liu L, Shi JL, Yin YX, Guo YG. Nat Commun, 2019, 10: 4930

    PubMed  PubMed Central  Google Scholar 

  78. Goodenough JB, Gao H. Sci China Chem, 2019, 62: 1555–1556

    CAS  Google Scholar 

  79. Ko M, Chae S, Ma J, Kim N, Lee HW, Cui Y, Cho J. Nat Energy, 2016, 1: 16113

    CAS  Google Scholar 

  80. Wu Z, Li F, Sun Y, Bin D, Piao J, Lin X, Liu X, Cao A, Wan L. Sci China Chem, 2017, 60: 1180–1186

    CAS  Google Scholar 

  81. Ji X, Lee KT, Nazar LF. Nat Mater, 2009, 8: 500–506

    CAS  PubMed  Google Scholar 

  82. Yin YX, Xin S, Guo YG, Wan LJ. Angew Chem Int Ed, 2013, 52: 13186–13200

    CAS  Google Scholar 

  83. Yan M, Wang WP, Yin YX, Wan LJ, Guo YG. EnergyChem, 2019, 1: 100002

    Google Scholar 

  84. Zhou L, Danilov DL, Eichel R-, Notten PHL. Adv Energy Mater, 2021, 11: 2001304

    CAS  Google Scholar 

  85. Zhao M, Li BQ, Peng HJ, Yuan H, Wei JY, Huang JQ. Angew Chem Int Ed, 2020, 59: 12636–12652

    CAS  Google Scholar 

  86. Jiang S, Huang S, Yao M, Zhu J, Liu L, Niu Z. Chin Chem Lett, 2020, 31: 2347–2352

    CAS  Google Scholar 

  87. Lim WG, Kim S, Jo C, Lee J. Angew Chem, 2019, 131: 18920–18931

    Google Scholar 

  88. Du Z, Chen X, Hu W, Chuang C, Xie S, Hu A, Yan W, Kong X, Wu X, Ji H, Wan LJ. J Am Chem Soc, 2019, 141: 3977–3985

    CAS  PubMed  Google Scholar 

  89. Han Y, Yang M, Zhang Y, Xie J, Yin D, Li C. Chem Mater, 2016, 28: 3139–3147

    CAS  Google Scholar 

  90. Fan S, Lei M, Wu H, Hu J, Yin C, Liang T, Li C. Energy Storage Mater, 2020, 31: 87–94

    Google Scholar 

  91. Zhu YF, Xiao Y, Dou SX, Kang YM, Chou SL. eScience, 2021, 1: 13–27

    Google Scholar 

  92. Wang Z, Zhou M, Qin L, Chen M, Chen Z, Guo S, Wang L, Fang G, Liang S. eScience, 2022, 2: 209–218

    Google Scholar 

  93. Liang HJ, Hou BH, Li WH, Ning QL, Yang X, Gu ZY, Nie XJ, Wang G, Wu XL. Energy Environ Sci, 2019, 12: 3575–3584

    CAS  Google Scholar 

  94. Hou BH, Wang YY, Ning QL, Li WH, Xi XT, Yang X, Liang HJ, Feng X, Wu XL. Adv Mater, 2019, 31: 1903125

    CAS  Google Scholar 

  95. Song M, Wang C, Du D, Li F, Chen J. Sci China Chem, 2019, 62: 616–621

    CAS  Google Scholar 

  96. Zhao C, Wang Q, Yao Z, Wang J, Sánchez-Lengeling B, Ding F, Qi X, Lu Y, Bai X, Li B, Li H, Aspuru-Guzik A, Huang X, Delmas C, Wagemaker M, Chen L, Hu YS. Science, 2020, 370: 708–711

    CAS  PubMed  Google Scholar 

  97. Luo W, Shen F, Bommier C, Zhu H, Ji X, Hu L. Acc Chem Res, 2016, 49: 231–240

    CAS  PubMed  Google Scholar 

  98. Hu YS, Lu Y. ACS Energy Lett, 2019, 4: 2689–2690

    CAS  Google Scholar 

  99. Chen K, Qiu W, Wu Q, Zhou X, Liu J, Li C. J Mater Chem A, 2021, 9: 6160–6171

    CAS  Google Scholar 

  100. Fang G, Wu Z, Zhou J, Zhu C, Cao X, Lin T, Chen Y, Wang C, Pan A, Liang S. Adv Energy Mater, 2018, 8: 1703155

    Google Scholar 

  101. Xu R, Yao Y, Wang H, Yuan Y, Wang J, Yang H, Jiang Y, Shi P, Wu X, Peng Z, Wu ZS, Lu J, Yu Y. Adv Mater, 2020, 32: 2003879

    Google Scholar 

  102. Jiang L, Lu Y, Zhao C, Liu L, Zhang J, Zhang Q, Shen X, Zhao J, Yu X, Li H, Huang X, Chen L, Hu YS. Nat Energy, 2019, 4: 495–503

    CAS  Google Scholar 

  103. Xie X, Qi S, Wu D, Wang H, Li F, Peng X, Cai J, Liang J, Ma J. Chin Chem Lett, 2020, 31: 223–226

    CAS  Google Scholar 

  104. Xue L, Li Y, Gao H, Zhou W, Lü X, Kaveevivitchai W, Manthiram A, Goodenough JB. J Am Chem Soc, 2017, 139: 2164–2167

    CAS  PubMed  Google Scholar 

  105. Hosaka T, Kubota K, Hameed AS, Komaba S. Chem Rev, 2020, 120: 6358–6466

    CAS  PubMed  Google Scholar 

  106. Jian Z, Luo W, Ji X. J Am Chem Soc, 2015, 137: 11566–11569

    CAS  PubMed  Google Scholar 

  107. Xu YS, Guo SJ, Tao XS, Sun YG, Ma J, Liu C, Cao AM. Adv Mater, 2021, 33: 2100409

    CAS  Google Scholar 

  108. Xu YS, Duan SY, Sun YG, Bin DS, Tao XS, Zhang D, Liu Y, Cao AM, Wan LJ. J Mater Chem A, 2019, 7: 4334–4352

    CAS  Google Scholar 

  109. Dhir S, Wheeler S, Capone I, Pasta M. Chem, 2020, 6: 2442–2460

    CAS  Google Scholar 

  110. Kubota K, Dahbi M, Hosaka T, Kumakura S, Komaba S. Chem Rec, 2018, 18: 459–479

    CAS  PubMed  Google Scholar 

  111. Ge J, Fan L, Rao AM, Zhou J, Lu B. Nat Sustain, 2022, 5: 225–234

    Google Scholar 

  112. Song Z, Ding J, Liu B, Liu X, Han X, Deng Y, Hu W, Zhong C. Adv Mater, 2020, 32: 1908127

    CAS  Google Scholar 

  113. Zhou T, Zhang N, Wu C, Xie Y. Energy Environ Sci, 2020, 13: 1132–1153

    CAS  Google Scholar 

  114. Zhang J, Zhao Z, Xia Z, Dai L. Nat Nanotech, 2015, 10: 444–452

    CAS  Google Scholar 

  115. Zhang Y, Deng YP, Wang J, Jiang Y, Cui G, Shui L, Yu A, Wang X, Chen Z. Energy Storage Mater, 2021, 35: 538–549

    Google Scholar 

  116. Li Y, Gong M, Liang Y, Feng J, Kim JE, Wang H, Hong G, Zhang B, Dai H. Nat Commun, 2013, 4: 1805

    PubMed  Google Scholar 

  117. Tang T, Ding L, Jiang Z, Hu JS, Wan LJ. Sci China Chem, 2020, 63: 1517–1542

    CAS  Google Scholar 

  118. Zhang M, Dai Q, Zheng H, Chen M, Dai L. Adv Mater, 2018, 30: 1705431

    Google Scholar 

  119. Cai P, Peng X, Huang J, Jia J, Hu X, Wen Z. Sci China Chem, 2019, 62: 385–392

    CAS  Google Scholar 

  120. Li D, Xu HQ, Jiao L, Jiang HL. EnergyChem, 2019, 1: 100005

    CAS  Google Scholar 

  121. Chen X, Fang Y, Lu H, Li H, Feng X, Chen W, Ai X, Yang H, Cao Y. Small, 2021, 17: 2102248

    CAS  Google Scholar 

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (21931012, 22025507, 22109052), Guangdong Basic and Applied Basic Research Foundation (2022B1515020001), Guangzhou Science and Technology Program (202201010703), and the Fundamental Research Funds for the Central Universities (21621033).

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  1. College of Chemistry and Materials Science, Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination, Materials and Applications, Jinan University, Guangzhou, 510632, China

    De-Shan Bin & Ze-Lin Zheng

  2. CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing, 100190, China

    An-Min Cao & Li-Jun Wan

  3. University of Chinese Academy of Sciences, Beijing, 100049, China

    An-Min Cao & Li-Jun Wan

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  1. De-Shan Bin
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Bin, DS., Zheng, ZL., Cao, AM. et al. Template-free synthesis of hollow carbon-based nanostructures from MOFs for rechargeable battery applications. Sci. China Chem. 66, 65–77 (2023). https://doi.org/10.1007/s11426-022-1398-5

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