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TiO2 mesocrystals: Synthesis, formation mechanisms and applications

  • Reviews
  • Special Topic Growth Mechanism of Nanostructures
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Abstract

Mesocrystals, which are assemblies of crystallographically oriented nanocrystals, have received increasing attention due to their unique properties such as high crystallinity, high porosity, oriented subunit alignment, and similarity to highly sophisticated biominerals. However, the controlled synthesis of TiO2 mesocrystals has not been realized until recently, probably because of the difficulty in accurately controlling the reaction processes that produce TiO2 crystals. In this review, recent advances in the synthesis and applications of TiO2 mesocrystals are summarized with particular attention paid to the mechanisms of their formation. Three typical pathways for the preparation of TiO2 mesocrystals are discussed, namely topotactic transformation, direct synthesis in solution, and growth on supports. The potential applications of TiO2 mesocrystals in lithium ion batteries, photocatalysis, enzyme immobilization, and antireflection materials are also described.

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References

  1. Talapin DV, Lee J-S, Kovalenko MV, Shevchenko EV. Prospects of colloidal nanocrystals for electronic and optoelectronic applications. Chem Rev, 2010, 110: 389–458

    Article  CAS  Google Scholar 

  2. Nie Z, Petukhova A, Kumacheva E. Properties and emerging applications of self-assembled structures made from inorganic nanoparticles. Nat Nanotech, 2010, 5: 15–25

    Article  CAS  Google Scholar 

  3. Cölfen H, Antonietti M. Mesocrystals: Inorganic superstructures made by highly parallel crystallization and controlled alignment. Angew Chem Int Ed, 2005, 44: 5576–5591

    Article  Google Scholar 

  4. Zhou L, O’Brien P. Mesocrystals: A new class of solid materials. Small, 2008, 4: 1566–1574

    Article  CAS  Google Scholar 

  5. Song R-Q, Cölfen H. Mesocrystals — Ordered nanoparticle superstructures. Adv Mater, 2010, 22: 1301–1330

    Article  CAS  Google Scholar 

  6. Fang J, Ding B, Gleiter H. Mesocrystals: Syntheses in metals and applications. Chem Soc Rev, 2011, 40: 5347–5360

    Article  CAS  Google Scholar 

  7. Zhou L, O’Brien P. Mesocrystals — Properties and applications. J Phys Chem Lett, 2012, 3: 620–628

    Article  CAS  Google Scholar 

  8. Niederberger M, Cölfen H. Oriented attachment and mesocrystals: Non-classical crystallization mechanisms based on nanoparticle assembly. Phys Chem Chem Phys, 2006, 8: 3271–3287

    Article  CAS  Google Scholar 

  9. Zhang Q, Liu S-J, Yu S-H. Recent advances in oriented attachment growth and synthesis of functional materials: Concept, evidence, mechanism, and future. J Mater Chem, 2009, 19: 191–207

    Article  CAS  Google Scholar 

  10. Chen X, Mao SS. Titanium dioxide nanomaterials: Synthesis, properties, modifications, and applications. Chem Rev, 2007, 107: 2891–2959

    Article  CAS  Google Scholar 

  11. Zhou L, Smyth-Boyle D, O’Brien P. Uniform NH4TiOF3 mesocrystals prepared by an ambient temperature self-assembly process and their topotaxial conversion to anatase. Chem Commun, 2007: 144–146

  12. Zhou L, Smyth-Boyle D, O’Brien P. A facile synthesis of uniform NH4TiOF3 mesocrystals and their conversion to TiO2 mesocrystals. J Am Chem Soc, 2008, 130: 1309–1320

    Article  CAS  Google Scholar 

  13. Liu YQ, Zhang Y, Tan H, Wang J. Formation and anisotropic dissolution behavior of NH4TiOF3 mesocrystals. Cryst Growth Des, 2011, 11: 2905–2912

    Article  CAS  Google Scholar 

  14. Feng J, Yin M, Wang Z, Yan S, Wan L, Li Z, Zou Z. Facile synthesis of anatase TiO2 mesocrystal sheets with dominant {001} facets based on topochemical conversion. CrystEngComm, 2010, 12: 3425–3429

    Article  CAS  Google Scholar 

  15. Liu S-J, Gong J-Y, Hu B, Yu S-H. Mesocrystals of rutile TiO2: Mesoscale transformation, crystallization, and growth by a biologic molecules-assisted hydrothermal process. Cryst Growth Des, 2008, 9: 203–209

    Article  Google Scholar 

  16. Zhang D, Li G, Wang F, Yu J C. Green synthesis of a self-assembled rutile mesocrystalline photocatalyst. CrystEngComm, 2010, 12: 1759–1763

    Article  CAS  Google Scholar 

  17. Ye J, Liu W, Cai J, Chen S, Zhao X, Zhou H, Qi L. Nanoporous anatase TiO2 mesocrystals: Additive-free synthesis, remarkable crystalline-phase stability, and improved lithium insertion behavior. J Am Chem Soc, 2010, 133: 933–940

    Article  Google Scholar 

  18. Hong Z, Wei M, Lan T, Jiang L, Cao G. Additive-free synthesis of unique TiO2 mesocrystals with enhanced lithium-ion intercalation properties. Energy Environ Sci, 2012, 5: 5408–5413

    Article  CAS  Google Scholar 

  19. Hong Z, Wei M, Lan T, Cao G. Self-assembled nanoporous rutile TiO2 mesocrystals with tunable morphologies for high rate lithium-ion batteries. Nano Energy, 2012, 1: 466–471

    Article  Google Scholar 

  20. Li L, Liu C-Y. Organic small molecule-assisted synthesis of high active TiO2 rod-like mesocrystals. CrystEngComm, 2010, 12: 2073–2078

    Article  Google Scholar 

  21. Da Silva RO, Goncalves RH, Stroppa DG, Ramirez AJ, Leite ER. Synthesis of recrystallized anatase TiO2 mesocrystals with Wulff shape assisted by oriented attachment. Nanoscale, 2011, 3: 1910–1916

    Article  Google Scholar 

  22. Wang H, Liu Y, Liu Z, Xu H, Deng Y, Shen H. Hierarchical rutile TiO2 mesocrystals assembled by nanocrystals-oriented attachment mechanism. CrystEngComm, 2012, 14: 2278–2282

    Article  CAS  Google Scholar 

  23. Tartaj P. Sub-100 nm TiO2 mesocrystalline assemblies with mesopores: Preparation, characterization, enzyme immobilization and photocatalytic properties. Chem Commun, 2011, 47: 256–258

    Article  CAS  Google Scholar 

  24. Tartaj P, Amarilla JM. Multifunctional response of anatase nanostructures based on 25 nm mesocrystal-like porous assemblies. Adv Mater, 2011, 23: 4904–4907

    Article  CAS  Google Scholar 

  25. Liu B, Zeng HC. Carbon nanotubes supported mesoporous mesocrystals of anatase TiO2. Chem Mater, 2008, 20: 2711–2718

    Article  CAS  Google Scholar 

  26. Cai J, Ye J, Chen S, Zhao X, Zhang D, Chen S, Ma Y, Jin S, Qi L. Self-cleaning, broadband and quasi-omnidirectional antireflective structures based on mesocrystalline rutile TiO2 nanorod arrays. Energy Environ Sci, 2012, 5: 7575–7581

    Article  CAS  Google Scholar 

  27. Aoyama Y, Oaki Y, Ise R, Imai H. Mesocrystal nanosheet of rutile TiO2 and its reaction selectivity as a photocatalyst. CrystEngComm, 2012, 14: 1405–1411

    Article  CAS  Google Scholar 

  28. Lou XW, Archer LA. A general route to nonspherical anatase TiO2 hollow colloids and magnetic multifunctional particles. Adv Mater, 2008, 20: 1853–1858

    Article  CAS  Google Scholar 

  29. Guo YG, Hu YS, Sigle W, Maier J. Superior electrode performance of nanostructured mesoporous TiO2 (anatase) through efficient hierarchical mixed conducting networks. Adv Mater, 2007, 19: 2087–2091

    Article  CAS  Google Scholar 

  30. Liao J-Y, Lei B-X, Chen H-Y, Kuang D-B, Su C-Y. Oriented hierarchical single crystalline anatase TiO2 nanowire arrays on Ti-foil substrate for efficient flexible dye-sensitized solar cells. Energy Environ Sci, 2012, 5: 5750–5757

    Article  CAS  Google Scholar 

  31. Qi L. Colloidal chemical approaches to inorganic micro- and nanostructures with controlled morphologies and patterns, Coord Chem Rev, 2010, 254: 1054–1071

    Article  CAS  Google Scholar 

  32. Huang T, Qi L. Solution-phase synthesis of inorganic nanostructures by chemical transformation from reactive templates. Sci China Chem, 2010, 53: 365–371

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Beijing National Laboratory for Molecular Sciences; State Key Laboratory for Structural Chemistry of Unstable and Stable Species; College of Chemistry, Peking University, Beijing, 100871, China

    JinGuang Cai & LiMin Qi

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  1. JinGuang Cai
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  2. LiMin Qi
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Correspondence to LiMin Qi.

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Cai, J., Qi, L. TiO2 mesocrystals: Synthesis, formation mechanisms and applications. Sci. China Chem. 55, 2318–2326 (2012). https://doi.org/10.1007/s11426-012-4706-7

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  • DOI: https://doi.org/10.1007/s11426-012-4706-7

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