Skip to main content
SpringerLink
Log in

Synthesis and characterization of two novel coordination polymers based on the rigid 1H-1,2,3-triazole-4,5-dicarboxylic acid ligand

  • Articles
  • Published:
Science China Chemistry Aims and scope Submit manuscript

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

Two novel three-dimensional (3-D) coordination polymers, [Pb(HTDA)] n (1) and [Co5(TDA)2(H2TDA)2(H2O)8] n (2) [H3TDA = 1H-1,2,3-triazole-4,5-dicarboxylic acid], have been prepared by hydrothermal reactions and characterized by elemental analysis, infrared spectroscopy and single-crystal X-ray diffraction. Compound 1 is constructed from rod-shaped secondary building units (SBUs) and exhibits a 3-D network with (410·65)(410·63·82) topology. Compound 2 is built up from ligands bridging three different cobalt ions and exhibits a 3-D network with (4·82)3(4·82·103) topology. In addition, the thermal stabilities of the two compounds, the photoluminescence properties of compound 1 and the magnetic properties of compound 2 have been studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Rowsell JLC, Yaghi OM. Metal-organic frameworks: A new class of porous materials. Micropor Mesopor Mater, 2004, 73: 3–14

    Article  CAS  Google Scholar 

  2. Wang XL, Qin C, Wang EB, Li YG, Su ZM, Xu L, Carlucci L. Entangled coordination networks with inherent features of polycatenation, polythreading, and polyknotting. Angew Chem Int Ed, 2005, 44: 5824–5827

    Article  CAS  Google Scholar 

  3. Banerjee R, Phan A, Wang B, Knobler C, Furukawa H, O’Keeffe M, Yaghi OM, High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture. Science, 2008, 319: 939–943

    Article  CAS  Google Scholar 

  4. Sun CY, Liu SX, Liang DD, Shao KZ, Ren YH, Su ZM. Highly stable crystalline catalysts based on a microporous metal-organic framework and polyoxometalates. J Am Chem Soc, 2009, 131: 1883–1888

    Article  CAS  Google Scholar 

  5. Zhang WX, Xue W, Zheng YZ, Chen XM. Two spin-competing manganese(II) coordination polymers exhibiting unusual multi-step magnetization jumps. Chem Commun, 2009, 3804–3806

  6. Zhao YH, Xu HB, Shao KZ, Xing Y, Su ZM, Ma JF. Syntheses, characterization, and luminescent properties of three 3D lead-organic frameworks with 1D channels. Cryst Growth Des, 2007, 7: 513–520

    Article  CAS  Google Scholar 

  7. He Z, Wang ZM, Yan CH. Ligand-controlled dimensionality: 1D, 2D and 3D Gd(III) coordination polymers based on SO –4 and pyridine carboxylate N-oxide ligands. CrystEngComm, 2005, 7: 143–150

    Article  CAS  Google Scholar 

  8. Tong ML, Kitagawa S, Chang HC, Ohba M. Temperature-controlled hydrothermal synthesis of a 2D ferromagnetic coordination bilayered polymer and a novel 3D network with inorganic Co3(OH)2 ferrimagnetic chains. Chem Commun, 2004, 418–419

  9. Fu ZY, Hu SM, Dai JC, Zhang JJ, Wu XT. Three novel polymeric frameworks assembled from CdII, CoII, and MnII with the mixed organic ligands 3,4-pyridinedicarboxylate, 1,3-bis(4-pyridyl)propane, or 1,2-bis(4-pyridyl)ethane. Eur J Inorg Chem, 2003, 2670–2677

  10. Gu XJ, Xue DF. Self-assembly of 3D 4de–4f coordination frameworks based on 1D inorganic heterometallic chains and linear organic linkers. CrystEngComm, 2007, 9: 471–477

    Article  CAS  Google Scholar 

  11. Weng DF, Zheng XJ, Chen XB, Li LC, Jin LP. Synthesis, upconversion luminescence and magnetic properties of new lanthanide-organic frameworks with (43)2(46,66,83) topology. Eur J Inorg Chem, 2007, 3410–3415

  12. Yang JH, Zheng SL, Yu XL, Chen XM. Syntheses, structures, and photoluminescent properties of three silver(I) cluster-based coordination polymers with heteroaryldicarboxylate. Cryst Growth Des, 2004, 4: 831–836

    Article  CAS  Google Scholar 

  13. Sun YQ, Zhang J, Chen YM, Yang GY. Porous lanthanide-organic open frameworks with helical tubes constructed from interweaving triple-helical and double-helical chains. Angew Chem Int Ed, 2005, 44: 5814–5817

    Article  CAS  Google Scholar 

  14. Liu GX, Huang LF, Xu H, Ren XM. Synthesis, structure and photo luminescent property of a novel potassic compound. Chin Chem Lett, 2007, 18: 1539–1542

    Article  CAS  Google Scholar 

  15. Shi W, Chen XY, Xu N, Song HB, Zhao B, Cheng P, Liao DZ, Yan SP. Synthesis, crystal structures, and magnetic properties of 2D manganese(II) and 1D gadolinium(III) coordination polymers with 1H-1,2,3-triazole-4,5-dicarboxylic acid. Eur J Inorg Chem, 2006, 4931–4937

  16. Olson JR, Yamauchi M, Butler WM. Copper(II) complexes of 1,2,3-triazolecarboxylic acids. Inorg Chim Acta, 1985, 99: 121–128

    Article  CAS  Google Scholar 

  17. Yue YF, Liang J, Gao EQ, Fang CJ, Yan ZG, Yan CH. Suprarnolecular engineering of a 2D Kagomé lattice: Synthesis, structures, and magnetic properties. Inorg Chem, 2008, 47: 6115–6117

    Article  CAS  Google Scholar 

  18. Liu GF, Ren ZG, Chen Y, Liu D, Li HX, Zhang Y, Lang JP. Solvothermal synthesis, structure and luminescent properties of a new 3D coordination polymer [K2Cd(Htda)2]n (Htda=1,2,3-triazole-4,5-dicarboxylate). Inorg Chem Commun, 2008, 11: 225–229

    Article  CAS  Google Scholar 

  19. Yue YF, Wang BW, Gao EQ, Fang CJ, He C, Yan CH. A novel three-dimensional heterometallic compound: Templated assembly of the unprecedented planar “Na_[Cu4]” metalloporphyrin-like subunits. Chem Commun, 2007, 2034–2036

  20. Zhang WX, Xue W, Lin JB, Zheng YZ, Chen XM. 3D geometrically frustrated magnets assembled by transition metal ion and 1,2,3-triazole-4,5-dicarboxylate as triangular nodes. CrystEngComm, 2008, 10: 1770–1776

    Article  CAS  Google Scholar 

  21. Yuan G, Shao KZ, Wang XL, Lan YQ, Du DY, Su ZM. A series of novel chiral lanthanide coordination polymers with channels constructed from 16Ln-based cage-like building units. CrystEngComm, 2010, 12: 1147–1152

    Article  CAS  Google Scholar 

  22. Sheldrick GM. SHELXS97, Program for Crystal Structure Refinement. Göttingen: University of Göttingen, 1997

    Google Scholar 

  23. Sheldrick GM. SHELXL97, Program for Crystal Structure Solution. Göttingen: University of Göttingen, 1997

    Google Scholar 

  24. Ford PC, Vogler A. Photochemical and photophysical properties of tetranuclear and hexanuclear clusters of metals with d10 and s2 electronic configurations. Acc Chem Res, 1993, 26: 220–226

    Article  CAS  Google Scholar 

  25. Vogler A, Paukner A, Kunkely H. Relationships between the carbon-oxygen stretching frequencies of carboxylato complexes and the type of carboxylate coordination. Coord Chem Rev, 1980, 33: 227–250

    Article  Google Scholar 

  26. Nikol H, Becht A, Vogler A. Photoluminescence of germanium(II), tin(II), and lead(II) chloride complexes in solution. Inorg Chem, 1992, 31: 3277–3279

    Article  CAS  Google Scholar 

  27. Liu QY, Xu L. Synthesis, crystal structures, and photophysical properties of two novel lead(II)-SIP coordination polymers (NaH2SIP = 5-sulfoisophthalic acid monosodium salt) containing tetranuclear lead(II) units. Eur J Inorg Chem, 2006, 1620–1628

  28. Strasser A, Vogler A. Optical properties of thallium(I), lead(II) and bismuth(III) hexafluoroacetylacetonates. Intraligand phosphorescence under ambient conditions. Inorg Chem Commun, 2004, 7: 528–530

    Article  CAS  Google Scholar 

  29. Strasser A, Vogler A. Intraligand phosphorescence of lead(II) betadiketonates under ambient conditions. J Photochem Photobiol A Chem, 2004, 165: 115–118

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China

    Gang Yuan, KuiZhan Shao, DongYing Du, XinLong Wang & ZhongMin Su

Authors
  1. Gang Yuan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. KuiZhan Shao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. DongYing Du
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. XinLong Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. ZhongMin Su
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to ZhongMin Su.

Electronic supplementary material

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yuan, G., Shao, K., Du, D. et al. Synthesis and characterization of two novel coordination polymers based on the rigid 1H-1,2,3-triazole-4,5-dicarboxylic acid ligand. Sci. China Chem. 53, 2177–2182 (2010). https://doi.org/10.1007/s11426-010-4127-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11426-010-4127-4

Keywords

Search

Navigation