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One-pot synthesis of hyperbranched poly(amido amine) clicked with a sugar shell via Michael addition polymerization and thiol click reaction

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  • Special Topic Advances in Principles of Polymerization
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Abstract

This paper reports the production of glycopolymers via a simple and flexible method. A novel glycopolymer with a hyperbranched poly(amido amine) core and a sugar shell (HPAA-GLc) was synthesized by using thiol-ene click reaction via facile one-pot method. Hyperbranched poly(amido amine) with vinyl terminals was first synthesized by Michael addition polymerization of N,N′-methylene bisacrylamide (MBA) with 1-(2-aminoethyl) piperazine (AEPZ). Subsequently, thiol-ene click reaction between vinyl units of hyperbranched poly(amido amine) and thio-glucose was performed in situ. Based on the NMR result, all the vinyl groups reacted with thiol-glucose in 120 min. Strong photoluminescence emission was observed from the aqueous solution of HPAA-GLc.

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Authors and Affiliations

  1. CAS Key Lab of Soft Matter Chemistry; Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, 230026, China

    ZhiQiang Yu, MengMeng Cui, JunJie Yan & YeZi You

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  1. ZhiQiang Yu
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  2. MengMeng Cui
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  3. JunJie Yan
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  4. YeZi You
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Correspondence to YeZi You.

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Yu, Z., Cui, M., Yan, J. et al. One-pot synthesis of hyperbranched poly(amido amine) clicked with a sugar shell via Michael addition polymerization and thiol click reaction. Sci. China Chem. 53, 1663–1668 (2010). https://doi.org/10.1007/s11426-010-4050-8

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  • DOI: https://doi.org/10.1007/s11426-010-4050-8

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