Skip to main content
SpringerLink
Log in

Synthesis, structure, and magnetic properties of two novel lanthanide-organic frameworks

  • Published:
Science in China Series B: Chemistry Aims and scope Submit manuscript

Abstract

Two novel metal-organic frameworks, {[Eu(phen)(NDA)1.5(H2O)]} n ((1); NDA = 2,6-naphthalenedicarboxylate ions, phen = 1,10-phenanthroline) and {[Gd(phen)(NDA)1.5]·0.5H2NDA} n (2), have been synthesized under hydrothermal conditions. The structure analyses of 1 and 2 reveal that the two compounds belong to the triclinic system with space group P-1. Compound 1 features a 2D lattice structure while compound 2 displays a novel 3D architecture. The two frameworks were further characterized by elemental analyses, luminescent spectrua, and variable-temperature magnetic susceptibilities. The investigation of luminescent property reveals that 1 exhibits characteristic red emission of Eu3+. Magnetic investigation suggests that the ferromagnetic coupling exists between adjacent Gd3+ in compound 2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Zhang J, Bu X H. Chiralization of diamond nets: Stretchable helices and chiral and achiral nets with nearly identical unit cells. Angew Chem Int Ed, 2007, 46: 6115–6118

    Article  CAS  Google Scholar 

  2. Rowsell J L C, Yaghi O M. Effects of functionalization, catenation, and variation of the metal oxide and organic linking units on the low-pressure hydrogen adsorption properties of metal-organic frameworks. J Am Chem Soc, 2006, 128: 1304–1315

    Article  CAS  Google Scholar 

  3. Ma S Q, Wang X S, Yuan D Q, Zhou H C. A coordinatively linked Yb metal-organic framework demonstrates high thermal stability and uncommon gas-adsorption selectivity. Angew Chem Int Ed, 2008, 47: 4130–4133

    Article  CAS  Google Scholar 

  4. Li H, Eddaoudi M, O’keeffe M, Yaghi O M. Design and synthesis of an exceptionally stable and highly porous metal-organic framework. Nature, 1999, 402: 276–279

    Article  CAS  Google Scholar 

  5. Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O’keeffe M, Yaghi O M. Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage. Science, 2002, 295: 469–472

    Article  CAS  Google Scholar 

  6. Yaghi O M, Li H. T-Shaped Molecular Building Units in the Porous Structure of Ag(4,4′-bpy)·NO3. J Am Chem Soc, 1996, 118: 295–298

    Article  CAS  Google Scholar 

  7. Min K S, Suh M P. Silver(I)-polynitrile network solids for anion exchange: Anion-induced transformation of supramolecular structure in the crystalline state. J Am Chem Soc, 2000, 122: 6834–6840

    Article  CAS  Google Scholar 

  8. Halper S R, Do L, Stork J R, Cohen S M. Topological Control in Heterometallic metal—organic frameworks by anion templating and metalloligand design. J Am Chem Soc, 2006, 128: 15255–15268

    Article  CAS  Google Scholar 

  9. Seo J S, Whang D, Lee H, Jun S I, Oh J, Jeon Y J, Kim K. A homochiral metal-organic porous material for enantioselective separation and catalysis. Nature, 2000, 404: 982–986

    Article  CAS  Google Scholar 

  10. Sawaki T, Aoyama Y. Immobilization of a soluble metal complex in an organic network. Remarkable catalytic performance of a porous dialkoxyzirconium polyphenoxide as a functional organic zeolite analogue. J Am Chem Soc, 1999, 121: 4793–4798

    Article  CAS  Google Scholar 

  11. Ostrovsky S, Tomkowicz Z, Haase W. High Spin Co(II) in monomeric, exchange coupled oligomeric structures: Magnetic and Magnetic Circular Dichroism investigation. Coord Chem Rev, 2009, in press. Doi: 10.1016/j.ccr.2008.10.015

  12. Sessoli R, Powell A K, Strategies towards Single Molecule Magnets based on Lanthanide ions. Coord Chem Rev, 2009, in press. Doi:10.1016/j.ccr.2008.12.014

  13. Zhao B, Cheng P, Dai, Y, Cheng C, Liao D Z, Yan S P, Jiang Z H, Wang G L. A nanotubular 3D coordination polymer based on a 3d-4f heterometallic assembly. Angew Chem Int Ed, 2003, 42: 934–936

    Article  CAS  Google Scholar 

  14. Zhao B, Cheng P, Chen X Y, Cheng C, Shi W, Liao D Z, Yan S P, Jiang Z H. Design and synthesis of 3d-4f metal-based zeolite-type materials with a 3D nanotubular structure encapsulated “water” pipe. J Am Chem Soc, 2004, 126: 3012–3013

    Article  CAS  Google Scholar 

  15. Zhao B, Chen, X Y, Cheng P, Liao D Z, Yan S P, Jiang Z H. Coordination polymers containing 1D channels as selective luminescent probes. J Am Chem Soc, 2004, 126: 15394–15395

    Article  CAS  Google Scholar 

  16. Zhao B, Gao H L, Chen X Y, Cheng P, Shi W, Liao D Z, Yan S P, Jiang Z H. A promising Mg-II-ion-selective luminescent probe: Structures and properties of Dy-Mn polymers with high symmetry. Chem Eur J, 2006, 12: 149–158

    Article  CAS  Google Scholar 

  17. Zhao X Q, Zhao B, Ma Y, Shi W, Cheng P, Jiang Z H, Liao D Z, Yan S P. Lanthanide(III)-cobalt(II) heterometallic coordination polymers with radical adsorption properties. Inorg Chem 2007, 46: 5832–5834

    Article  CAS  Google Scholar 

  18. Wang H S, Zhao B, Zhai B, Shi W, Cheng P, Liao D Z, Yan S P. Syntheses, structures, and photoluminescence of one-dimensional lanthanide coordination polymers with 2,4,6-pyridinetricarboxylic acid. Cryst Growth&Des, 2007, 7: 1851–1857

    Article  CAS  Google Scholar 

  19. Chen Z, Zhao B, Zhang Y, Shi W, Cheng P. Construction and characterization of several new lanthanide-organic frameworks: From 2D lattice to 2D double-layer and to porous 3D net with interweaving triple-stranded helixes. Cryst Growth&Des, 2008, 8: 2291–2298

    Article  CAS  Google Scholar 

  20. Zhao B, Yi L, Dai Y, Chen X Y, Cheng P, Liao D Z, Yan S P, Jiang Z H. Systematic investigation of the hydrothermal syntheses of Pr(III)-PDA (PDA = pyridine-2,6-dicarboxylate anion) metal-organic frameworks. Inorg Chem, 2005, 44: 911–920

    Article  CAS  Google Scholar 

  21. Go Y B, Wang X Q, Anokhina E V, Jacobson A J. A chain of changes: Influence of noncovalent interactions on the one-dimensional structures of nickel(II) dicarboxylate coordination polymers with chelating aromatic amine ligands. Inorg Chem, 2004, 43: 5360–5367

    Article  CAS  Google Scholar 

  22. Anokhina E V, Vougo-Zanda M, Wang X Q, Jacobson A J. In(OH)BD·0.75BDCH2 (BDC = benzenedicarboxylate), a hybrid inorganic-organic vernier structure. J Am Chem Soc, 2005, 127: 15000–15001

    Article  CAS  Google Scholar 

  23. Zou R Q, Bu X H, Zhang R H. Novel eclipsed 2D cadmium(II) coordination polymers with open-channel structure constructed from terephthalate and 3-(2-pyridyl) pyrazole: Crystal structures, emission properties, and inclusion of guest molecules. Inorg Chem, 2004, 43: 5382–5386

    Article  CAS  Google Scholar 

  24. Rosi N L, Eckert J, Eddaoudi M, Vodak D T, Kim J, O’Keeffe M, Yaghi O M. Hydrogen storage in microporous metal-organic frameworks. Science 2003, 300: 1127–1129

    Article  CAS  Google Scholar 

  25. Serre C, Millange F, Thouvenot C, should be changed into: Nogues M, Marsolier G, Louer D, Ferey G. Very large breathing effect in the first nanoporous chromium(III)-based solids: MIL-53 or CrIII(OH)·{O2C-C6H4-CO2}·{HO2C-C6H4-CO2H}x·H2Oy. J Am Chem Soc, 2002, 124: 13519–13526

    Article  CAS  Google Scholar 

  26. Luo F, Zheng J M, Battenb S R. Unprecedented (3,4)-connected metal-organic frameworks (MOFs) with 3-fold interpenetration and considerable solvent-accessible void space. Chem Commun, 2007, 3744–3746

  27. Loiseau T, Lecroq L, Volkringer C, Marrot J, Ferey G, Haouas M, Taulelle F, Bourrelly S, Llewellyn P L, Latroche M. MIL-96, a porous aluminum trimesate 3D structure constructed from a hexagonal network of 18-membered rings and μ3-oxo-centered trinuclear units. J Am Chem Soc, 2006, 128: 10223–10230

    Article  CAS  Google Scholar 

  28. Ene C D, Tuna F, Fabelo O, Ruiz-Perez C, Madalan A M, Roesky H W, Andruh M. One-dimensional and two-dimensional coordination polymers constructed from copper(II) nodes and polycarboxylato spacers: Synthesis, crystal structures and magnetic properties. Polyhedron, 2008, 27: 574–582

    Article  CAS  Google Scholar 

  29. Wang Z, Jin C M, Shao T, Li Y Z, Zhang K L, Zhang H T, You X Z. Syntheses, structures, and luminescence properties of a new family of three-dimensional open-framework lanthanide coordination polymers. Inorg Chem Commun, 2002, 5: 642–648

    Article  CAS  Google Scholar 

  30. Ma B Q, Mulfort K L, Hupp J T. Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions. Inorg Chem, 2005, 44: 4912–4914

    Article  CAS  Google Scholar 

  31. Dincă M, Long J R. Strong H2 binding and selective gas adsorption within the microporous coordination solid Mg3(O2C-C10H6-CO2)3. J Am Chem Soc, 2005, 127: 9376–9377

    Article  Google Scholar 

  32. Zheng X J, Wang Z M, Gao S, Liao F H, Yan C H, Jin L P. Hydrothermal syntheses, structures, and properties of three 3-D lanthanide coordination polymers that form 1-D channels. Eur J Inorg Chem, 2004, 2968-2973

  33. He X, Lu C Z, Yuan D Q, Chen L J, Zhang Q Z, Wu C D. Hydrothermal synthesis, crystal structures, and properties of a class of 2D coordination polymers. Eur J Inorg Chem, 2005, 4598-4606

  34. Zheng X J, Sun C Y, Lu S Z, Liao F H, Gao S, Jin L P. New porous lanthanide-organic frameworks: synthesis, characterization, and properties of lanthanide 2,6-naphthalenedicarboxylates. Eur J Inorg Chem 2004, 3262-3268

  35. Zhang Z H, Okamura T, Hasegawa Y, Kawaguchi H, Kong L Y, Sun W Y, Ueyama N. Syntheses, structures, and luminescent and magnetic properties of novel three-dimensional lanthanide complexes with 1,3,5-benzenetriacetate. Inorg Chem, 2005, 44: 6219–6227

    Article  CAS  Google Scholar 

  36. Zang S Q, Su Y, Lin J G, Li Y Z, Gao S, Meng Q J. Four coordination polymers constructed from a multicarboxylate ligand and metal centers various from Ba2+, Cu2+, Zn2+ to Gd3+: Syntheses, crystal structures and properties. Inorg Chim Acta, 2009, 362: 2440–2446

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Nankai University, Tianjin, 300071, China

    XiuHua Li, Ming Fang & Bin Zhao

  2. Department of Chemistry, Chifeng College, Inner Mongolia, 024000, China

    XiuHua Li

Authors
  1. XiuHua Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ming Fang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Bin Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Bin Zhao.

Additional information

Supported by the Foundation for the Author of National Excellent Doctoral Dissertation of China (Grant No. 200732), NCET (Grant No. 07-0463), and Natural Science Foundation of Tianjin (Grant No. 07JCYBJC02000)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Li, X., Fang, M. & Zhao, B. Synthesis, structure, and magnetic properties of two novel lanthanide-organic frameworks. Sci. China Ser. B-Chem. 52, 1456–1462 (2009). https://doi.org/10.1007/s11426-009-0219-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11426-009-0219-4

Keywords

Search

Navigation