Skip to main content
Log in

Template synthesis of N—F-codoped TiO2 nanotubes with high visible light activity

  • Published:
Science in China Series B: Chemistry Aims and scope Submit manuscript

Abstract

A series of highly ordered N—F-codoped TiO2 nanotubes were synthesized with a simple template technique and the obtained samples were detected by FE-SEM and XPS. The UV-Vis absorption spectrum showed that after N—F-codoping, TiO2 nanotubes had a new absorption band at 425 nm, leading to a photoresponse in the visible region. These modified nanotubes showed a significant visible-induced photocatalytic activity for the degradation of methylene blue in aqueous solution.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Mor G K, Shankar K, Paulose M, Varghese O K, Grimes C A. Enhanced photocleavage of water using titania nanotube arrays. Nano Lett, 2005, 5(1): 191–195

    Article  CAS  Google Scholar 

  2. Mor G K, Varghese O K, Grimes C A, Carvalho M A, Pishko M V. A room-temperature TiO2-nanotube hydrogen sensor able to self-clean photoactively from environmental contamination. J Mater Res, 2004, 19: 628–634

    Article  CAS  Google Scholar 

  3. Mor G K, Shankar K, Paulose M, Varghese O K, Grimes C A. Use of highly-ordered TiO2 nanotube arrays in dye-sensitized solar cells. Nano Lett, 2006, 6(2): 215–218

    Article  CAS  Google Scholar 

  4. Yang S G, Liu Y Z, Sun C. Preparation of anatase TiO2/Ti nanotube-like electrodes and their high photoelectrocatalytic activity for the degradation of PCP in aqueous solution. Appl Catal A, 2006, 301: 284–291

    Article  CAS  Google Scholar 

  5. Yang S G, Liu Y Z, Sun C. Preparation of anatase TiO2/Ti nanotube-like electrodes and their high photoelectrocatalytic activity for the degradation of PCP in aqueous solution. Appl Catal A, 2006, 301: 284–291

    Article  CAS  Google Scholar 

  6. Hong J, Cao J, Sun J Z, Li H Y, Chen H Z, Wang M. Electronic structure of titanium oxide nanotubules. Chem Phys Lett, 2003, 380: 366–371

    Article  CAS  Google Scholar 

  7. Gole J L, Stout J D, Burda C, Lou Y B, Chen X B. Highly efficient formation of visible light-tunable TiO2-xNx photocatalysts and their transformation at the nanoscale. J Phys Chem B, 2004, 108: 1230–1240

    Article  CAS  Google Scholar 

  8. Hyeok P J, Sungwook K, Bard A J. Novel carbon-doped TiO2 nanotube arrays with high aspect ratios for efficient solar water splitting. Nano Lett, 2006, 6: 24–28

    Article  Google Scholar 

  9. Graham A, Armstrong A R, Canales J, Bruce P G. Nanotubes with the TiO2—B structure. Chem Commun, 2005, (19): 2454–2456

  10. Yu J C, Yu J, Ho W, Jiang Z, Zhang L. Effects of F-doping on the photocatalytic activity and microstructures of nanocrystalline TiO2 powders. Chem Mater, 2002, 14: 3808–3816

    Article  CAS  Google Scholar 

  11. Takashi T, Sachiko T, Kiyohiko K, Masayuki E. Photocatalytic oxidation reactivity of holes in the sulfur- and carbon-doped TiO2 powders studied by time-resolved diffuse reflectance spectroscopy. J Phys Chem B, 2004, 108: 19299–19306

    Article  Google Scholar 

  12. Li D, Haneda H, Hishita S, Ohashi N. Visible-light-driven N—F-codoped TiO2 photocatalysts. Synthesis by spray pyrolysis and surface characterization. Chem Mater, 2005, 17: 2588–2595

    Article  CAS  Google Scholar 

  13. Lee S, Jeon C, Park Y C. Fabrication of TiO2 tubules by template synthesis and hydrolysis with water vapor. Chem Mater, 2004, 16: 4292–4295

    Article  CAS  Google Scholar 

  14. Li D, Ohashi N, Hishita S, Kolodiazhnyi T, Haneda H. Origin of visible-light-driven photocatalysis: A comparative study on N—F-doped and N—F-codoped TiO2 powders by means of experimental characterizations and theoretical calculations. J Solid State Chem, 2005, 178: 3293–3302

    Article  CAS  Google Scholar 

  15. Li D, Haneda H, Hishita S, Ohashi N. Visible-light-driven N—F-codoped TiO2 photocatalysts. 2. Optical characterization, photocatalysis, and potential application to air purification. Chem Mater, 2005, 17: 2596–2602

    Article  CAS  Google Scholar 

  16. Lin H, Kumon S, Kozuka H, Yoko T. Electrical properties of sol-gel-derived transparent titania films doped with ruthenium and tantalum. Thin Solid Films, 1998, 315: 266–272

    Article  CAS  Google Scholar 

  17. Ihara T, Miyoshi M, Iriyama Y, Matsumoto O, Sugihara S. Visible-light-active titanium oxide photocatalyst realized by an oxygen-deficient structure and by nitrogen doping. Appl Catal B-Environ, 2003, 42: 403–409

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to SuJuan Pan.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pan, S., Liang, H., Wang, C. et al. Template synthesis of N—F-codoped TiO2 nanotubes with high visible light activity. Sci. China Ser. B-Chem. 52, 2043–2046 (2009). https://doi.org/10.1007/s11426-009-0133-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11426-009-0133-9

Keywords

Navigation