Abstract
A series of highly ordered N—F-codoped TiO2 nanotubes were synthesized with a simple template technique and the obtained samples were detected by FE-SEM and XPS. The UV-Vis absorption spectrum showed that after N—F-codoping, TiO2 nanotubes had a new absorption band at 425 nm, leading to a photoresponse in the visible region. These modified nanotubes showed a significant visible-induced photocatalytic activity for the degradation of methylene blue in aqueous solution.
Similar content being viewed by others
References
Mor G K, Shankar K, Paulose M, Varghese O K, Grimes C A. Enhanced photocleavage of water using titania nanotube arrays. Nano Lett, 2005, 5(1): 191–195
Mor G K, Varghese O K, Grimes C A, Carvalho M A, Pishko M V. A room-temperature TiO2-nanotube hydrogen sensor able to self-clean photoactively from environmental contamination. J Mater Res, 2004, 19: 628–634
Mor G K, Shankar K, Paulose M, Varghese O K, Grimes C A. Use of highly-ordered TiO2 nanotube arrays in dye-sensitized solar cells. Nano Lett, 2006, 6(2): 215–218
Yang S G, Liu Y Z, Sun C. Preparation of anatase TiO2/Ti nanotube-like electrodes and their high photoelectrocatalytic activity for the degradation of PCP in aqueous solution. Appl Catal A, 2006, 301: 284–291
Yang S G, Liu Y Z, Sun C. Preparation of anatase TiO2/Ti nanotube-like electrodes and their high photoelectrocatalytic activity for the degradation of PCP in aqueous solution. Appl Catal A, 2006, 301: 284–291
Hong J, Cao J, Sun J Z, Li H Y, Chen H Z, Wang M. Electronic structure of titanium oxide nanotubules. Chem Phys Lett, 2003, 380: 366–371
Gole J L, Stout J D, Burda C, Lou Y B, Chen X B. Highly efficient formation of visible light-tunable TiO2-xNx photocatalysts and their transformation at the nanoscale. J Phys Chem B, 2004, 108: 1230–1240
Hyeok P J, Sungwook K, Bard A J. Novel carbon-doped TiO2 nanotube arrays with high aspect ratios for efficient solar water splitting. Nano Lett, 2006, 6: 24–28
Graham A, Armstrong A R, Canales J, Bruce P G. Nanotubes with the TiO2—B structure. Chem Commun, 2005, (19): 2454–2456
Yu J C, Yu J, Ho W, Jiang Z, Zhang L. Effects of F-doping on the photocatalytic activity and microstructures of nanocrystalline TiO2 powders. Chem Mater, 2002, 14: 3808–3816
Takashi T, Sachiko T, Kiyohiko K, Masayuki E. Photocatalytic oxidation reactivity of holes in the sulfur- and carbon-doped TiO2 powders studied by time-resolved diffuse reflectance spectroscopy. J Phys Chem B, 2004, 108: 19299–19306
Li D, Haneda H, Hishita S, Ohashi N. Visible-light-driven N—F-codoped TiO2 photocatalysts. Synthesis by spray pyrolysis and surface characterization. Chem Mater, 2005, 17: 2588–2595
Lee S, Jeon C, Park Y C. Fabrication of TiO2 tubules by template synthesis and hydrolysis with water vapor. Chem Mater, 2004, 16: 4292–4295
Li D, Ohashi N, Hishita S, Kolodiazhnyi T, Haneda H. Origin of visible-light-driven photocatalysis: A comparative study on N—F-doped and N—F-codoped TiO2 powders by means of experimental characterizations and theoretical calculations. J Solid State Chem, 2005, 178: 3293–3302
Li D, Haneda H, Hishita S, Ohashi N. Visible-light-driven N—F-codoped TiO2 photocatalysts. 2. Optical characterization, photocatalysis, and potential application to air purification. Chem Mater, 2005, 17: 2596–2602
Lin H, Kumon S, Kozuka H, Yoko T. Electrical properties of sol-gel-derived transparent titania films doped with ruthenium and tantalum. Thin Solid Films, 1998, 315: 266–272
Ihara T, Miyoshi M, Iriyama Y, Matsumoto O, Sugihara S. Visible-light-active titanium oxide photocatalyst realized by an oxygen-deficient structure and by nitrogen doping. Appl Catal B-Environ, 2003, 42: 403–409
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Pan, S., Liang, H., Wang, C. et al. Template synthesis of N—F-codoped TiO2 nanotubes with high visible light activity. Sci. China Ser. B-Chem. 52, 2043–2046 (2009). https://doi.org/10.1007/s11426-009-0133-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11426-009-0133-9