Abstract
Purpose
Modification of sediment properties used in fingerprinting applications occurs along transport pathways as a result of particle size and organic matter enrichment/depletion, and geochemical transformations. Statistical approaches have been widely used to correct for enrichment and depletion, but detection of, and the un-mixing errors and uncertainties that arise from non-conservative behaviour remains under-recognised. Additionally, the over-determined nature of sediment fingerprint un-mixing models results in a range of potential solutions which are yet to be formally assessed.
Materials and methods
Synthetic source data comprising 50 tracers and four sources were ‘mixed’ to generate known target tracer compositions. Firstly, both conservative and deliberately corrupted tracer behaviours were processed by repeated un-mixing from the minimum permissible number of tracers (n = 3) to the maximum (n = 50) using the FR2000 model. Secondly, using a smaller synthetic dataset, one tracer was deliberately corrupted in a controlled way to determine the impact on results and the ability of the permutation version of the Monte-Carlo FR2000 un-mixing model to detect non-conservative behaviour. Finally, this approach, and the particular case of near equivalent (or equifinal) solutions, was applied to data from on-going sediment provenance studies in Ireland.
Results and discussion
Uncertainty in source predictions was better reduced by increasing, rather than decreasing the number of tracers, therefore questioning the justification for tracer reduction strategies. Non-conservative behaviour negatively affected the accuracy of mean source predictions but had no significant effect on uncertainty. The degree of tracer corruption (−90 to +155 %) from the ‘perfect’ target value resulted in a wide range of source predictions. The applied permutation un-mixing model was successful at detecting and rejecting the corrupted tracer below −50 % and above +20 % corruption. The true corruption (the uncertainty bounds reported by prediction at the upper and lower levels) was, therefore, significantly improved. The methodology to examine multiple solutions identified reasonably consistent source predictions when applied to field data. The suitability of this technique on data with limited tracers and no particle-size or organic matter correction is, however, questionable and warrants further investigation.
Conclusions
Tracer selection is a key stage in reliable sediment fingerprinting applications. Non-conservative behaviour results in inaccurate source group prediction. Existing studies may therefore require critical evaluation, particularly where small sample numbers are collected in systems where enrichment/depletion of source group signatures (particle size, organic effects and geochemical alteration) results in non-conservative tracer behaviour (corruption) during entrainment and transport or storage within sediment sinks.
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References
Bilotta GS, Brazier RE (2008) Understanding the influence of suspended solids on water quality and aquatic biota. Water Res 42:2849–2861
Blake WH, Ficken KJ, Taylor P, Russell MA, Walling DE (2012) Tracing crop-specific sediment sources in agricultural catchments. Geomorphology 139–140:322–329
Collins AL, Walling DE (2002) Selecting fingerprint properties for discriminating potential suspended sediment sources in river basins. J Hydrol 261:218–244
Collins AL, Walling DE (2007) Sources of fine sediment recovered from the channel bed of lowland groundwater-fed catchments in the UK. Geomorphology 88:120–138
Collins AL, Walling DE, Leeks GJL (1997) Fingerprinting the origin of fluvial suspended sediment in larger river basins: combining assessment of spatial provenance and source type. Geogr Ann Ser A 79:239–254
Collins AL, Walling DE, Leeks GJL (1998) Use of composite fingerprints to determine the provenance of the contemporary suspended sediment load transported by rivers. Earth Surf Process Landf 23:31–52
Collins AL, Walling DE, Webb L, King P (2010) Apportioning catchment scale sediment sources using a modified composite fingerprinting technique incorporating property weightings and prior information. Geoderma 155:249–261
Collins AL, Zhang Y, McChesney D, Walling DE, Haley SM, Smith P (2012) Sediment source tracing in a lowland agricultural catchment in southern England using a modified procedure combining statistical analysis and numerical modelling. Sci Total Environ 414:301–317
Collins AL, Williams LJ, Zhang Y, Marius M, Dungait JAJ, Smallman DJ, Dixon ER, Stringfellow A, Sear DA, Jones JI, Naden PS (2013) Catchment source contributions to the sediment-bound organic matter degrading salmonid spawning gravels in a lowland river, southern England. Sci Total Environ 456–457:181–195
Cooper RJ, Krueger T, Hiscock KM, Rawlins BG (2015) High-temporal resolution fluvial sediment source fingerprinting with uncertainty: a Bayesian approach. Earth Surf Process Landf 40:78–92
D’Haen K, Verstraeten G, Degryse P (2012) Fingerprinting historical fluvial sediment fluxes. Prog Phys Geogr 36:154–186
Davis C, Fox J (2009) Sediment fingerprinting: review of the method and future improvements for allocating nonpoint source pollution. J Environ Eng 135:490–504
Deasy C, Baxendale SA, Heathwaite AL, Ridall G, Hodgkinson R, Brazier RE (2011) Advancing understanding of runoff and sediment transfers in agricultural catchments through simultaneous observations across scales. Earth Surf Process Landf 36:1749–1760
European Union (2000) Establishing a framework for Community action in the field of water policy (Water Framework Directive) 2000/60/EC, EU, Brussels, L327
Foster IDL, Lees JA (2000) Tracers in geomorphology: theory and applications in tracing fine sediments. In: Foster IDL (ed) Tracers in geomorphology. Wiley, Chichester, pp 3–20
Foster IDL, Lees JA, Owens PN, Walling DE (1998) Mineral magnetic characterization of sediment sources from an analysis of lake and floodplain sediments in the catchments of the Old Mill reservoir and Slapton Ley, South Devon, UK. Earth Surf Process Landf 23:685–703
Fox JF, Papanicolaou AN (2008) An un-mixing model to study watershed erosion processes. Adv Water Resour 31:96–108
Franks SW, Rowan JS (2000) Multi-parameter fingerprinting of sediment sources: uncertainty estimation and tracer selection. In: Bentley LR, Sykes JF, Gray WG, Brebbia CA, Pinder GF (eds) Computational methods in water resources XIII. Balkema, Rotterdam, pp 1067–1074
Fryirs K (2013) (Dis)Connectivity in catchment sediment cascades: a fresh look at the sediment delivery problem. Earth Surf Process Landf 38:30–46
Gruszowski KE, Foster IDL, Lees JA, Charlesworth SM (2003) Sediment sources and transport pathways in a rural catchment, Herefordshire, UK. Hydrol Process 17:2665–2681
Guzmán G, Quinton J, Nearing M, Mabit L, Gómez J (2013) Sediment tracers in water erosion studies: current approaches and challenges. J Soils Sediments 13:816–833
Hatfield RG, Maher BA (2009) Fingerprinting upland sediment sources: particle size-specific magnetic linkages between soils, lake sediments and suspended sediments. Earth Surf Process Landf 34:1359–1373
Hatfield R, Maher B, Pates J, Barker P (2008) Sediment dynamics in an upland temperate catchment: changing sediment sources, rates and deposition. J Paleolimnol 40:1143–1158
Horowitz AL (2003) A primer on sediment-trace element chemistry, 2nd edn, USGS Report 91-76, p 136
Koiter AJ, Owens PN, Petticrew EL, Lobb DA (2013a) The behavioural characteristics of sediment properties and their implications for sediment fingerprinting as an approach for identifying sediment sources in river basins. Earth-Sci Rev 125:24–42
Koiter AJ, Lobb DA, Owens PN, Petticrew EL, Tiessen KD, Li S (2013b) Investigating the role of connectivity and scale in assessing the sources of sediment in an agricultural watershed in the Canadian prairies using sediment source fingerprinting. J Soils Sediments 13:1676–1691
Krause AK, Franks SW, Kalma JD, Loughran RJ, Rowan JS (2003) Multi-parameter fingerprinting of sediment deposition in a small gullied catchment in SE Australia. Catena 53:327–348
Laceby JP, Olley J (2015) An examination of geochemical modelling approaches to tracing sediment sources incorporating distribution mixing and elemental correlations. Hydrol Process 29:1669–1685
Martínez-Carreras N, Gallart F, Iffly JF, Pfister L, Walling DE, Krein A (2008) Uncertainty assessment in suspended sediment fingerprinting based on tracer mixing models: a case study from Luxembourg. In: Schmidt J, Cochrane T, Phillips T, Elliot C, Davies T, Basher L (eds) Sediment dynamics in changing environments, IAHS Publ 325. IAHS Press, Wallingford, pp 94–105
Martínez-Carreras N, Krein A, Gallart F, Iffly JF, Pfister L, Hoffmann L, Owens PN (2010) Assessment of different colour parameters for discriminating potential suspended sediment sources and provenance: a multi-scale study in Luxembourg. Geomorphology 118:118–129
Mellander P-E, Melland AR, Murphy PNC, Wall DP, Shortle G, Jordan P (2014) Coupling of surface water and groundwater nitrate-N dynamics in two permeable agricultural catchments. J Agric Sci 152:107–124
Motha JA, Wallbrink PJ, Hairsine PB, Grayson RB (2003) Determining the sources of suspended sediment in a forested catchment in southeastern Australia. Water Resour Res 39:1056
Motha JA, Wallbrink PJ, Hairsine PB, Grayson RB (2004) Unsealed roads as suspended sediment sources in an agricultural catchment in south-eastern Australia. J Hydrol 286:1–18
Mukundan R, Radcliffe DE, Ritchie JC, Risse LM, McKinley RA (2010) Sediment fingerprinting to determine the source of suspended sediment in a southern Piedmont stream. J Environ Qual 39:1328–1337
Mukundan R, Walling DE, Gellis AC, Slattery MC, Radcliffe DE (2012) Sediment source fingerprinting: transforming from a research tool to a management tool. JAWRA J Am Water Resour Assoc 48:1241–1257
Nosrati K, Govers G, Semmens BX, Ward EJ (2014) A mixing model to incorporate uncertainty in sediment fingerprinting. Geoderma 217–218:173–180
Parsons AJ, Foster IDL (2011) What can we learn about soil erosion from the use of 137Cs? Earth-Sci Rev 108:101–113
Phillips JM, Russell MA, Walling DE (2000) Time-integrated sampling of fluvial suspended sediment: a simple methodology for small catchments. Hydrol Process 14:2589–2602
Pittam N, Foster I, Mighall T (2009) An integrated lake-catchment approach for determining sediment source changes at Aqualate Mere, Central England. J Paleolimnol 42:215–232
Regan JT, Fenton O, Healy MG (2012) A review of phosphorus and sediment release from Irish tillage soils, the methods used to quantify losses and the current state of mitigation practice. Biol Environ 112B:1–25
Rowan JS, Goodwill P, Franks SW (2000) Uncertainty estimation in fingerprinting suspended sediment sources. In: Foster IDL (ed) Tracers in geomorphology. Wiley, Chichester, pp 3–20
Rowan JS, Black S, Franks SW (2012) Sediment fingerprinting as an environmental forensics tool explaining cyanobacteria blooms in lakes. Appl Geogr 32:832–843
Russell MA, Walling DE, Hodgkinson RA (2001) Suspended sediment sources in two small lowland agricultural catchments in the UK. J Hydrol 252:1–24
Shore M, Murphy PNC, Jordan P, Mellander P-E, Kelly-Quinn M, Cushen M, Mechan S, Shine O, Melland AR (2013) Evaluation of a surface hydrological connectivity index in agricultural catchments. Environ Model Softw 47:7–15
Small IF, Rowan JS, Franks SW (2002) Quantitative sediment fingerprinting using a Bayesian uncertainty estimation framework. In: Dyer FJ, Thoms MC, Olley JM (eds) The structure, function and management implications of fluvial sedimentary systems, IAHS Publ 27. IAHS Press, Wallingford, pp 443–450
Small IF, Rowan JS, Franks SW, Wyatt A, Duck RW (2004) Bayesian sediment fingerprinting provides a robust tool for environmental forensic geoscience applications. Geol Soc Lond Spec Publ 232:207–213
Smith HG, Blake WH (2014) Sediment fingerprinting in agricultural catchments: a critical re-examination of source discrimination and data corrections. Geomorphology 204:177–191
Smith TA, Owens PN (2014) Flume- and field-based evaluation of a time-integrated suspended sediment sampler for the analysis of sediment properties. Earth Surf Process Landf 39:1197–1207
Thompson J, Cassidy R, Doody DG, Flynn R (2013) Predicting critical source areas of sediment in headwater catchments. Agric Ecosyst Environ 179:41–52
USEPA (1996) SW-846 Method 3052: microwave assisted acid digestion of siliceous and organically based matricies. U.S. Gov. Print Office, Washington DC
Vigiak O, Borselli L, Newham LTH, McInnes J, Roberts AM (2012) Comparison of conceptual landscape metrics to define hillslope-scale sediment delivery ratio. Geomorphology 138:74–88
Walling DE (2005) Tracing suspended sediment sources in catchments and river systems. Sci Total Environ 344:159–184
Walling DE (2013) The evolution of sediment source fingerprinting investigations in fluvial systems. J Soils Sediments 13:1658–1675
Walling DE, Woodward JC, Nicholas AP (1993) A multi-parameter approach to fingerprinting suspended-sediment sources. In: Peters NE, Hoehn E, Leibundgut C, Tase N, Walling DE (eds) Tracers in hydrology, IAHS Publ 215. IAHS Press, Wallingford, pp 329–337
Walling DE, Collins AL, McMellin GK (2002) Provenance of interstitial sediment retrieved from salmonid spawning gravels in England and Wales: a reconnaissance survey based on the fingerprinting approach. Environment Agency Technical Report W2-046/TR3, Environment Agency, Bristol, UK
Wilkinson SN, Wallbrink PJ, Hancock GJ, Blake WH, Shakesby RA, Doerr SH (2009) Fallout radionuclide tracers identify a switch in sediment sources and transport-limited sediment yield following wildfire in a eucalypt forest. Geomorphology 110:140–151
Wilkinson SN, Hancock GJ, Bartley R, Hawdon AA, Keen RJ (2013) Using sediment tracing to assess processes and spatial patterns of erosion in grazed rangelands, Burdekin River basin, Australia. Agric Ecosyst Environ 180:90–102
Acknowledgments
This study was funded by the Walsh Fellowship Programme, Teagasc, Ireland, allied to the University of Dundee, UK. Overseas placements facilitating this study were supported by the Walsh Fellowship Overseas Training Award, the Australian Bicentennial Scholarship Fund (Menzies Centre for Australian Studies, Kings College London), University of Tasmania, the University of Dundee and Dr. John Walden (University of St Andrews). Prof. Phil Jordan (Ulster University) and Dr. Alice Melland (University of Southern Queensland) are thanked for their comments and Linda Moloney-Finn (Teagasc) for performing geochemical analysis. We acknowledge support from the Teagasc Agricultural Catchments Programme (funded by the Department of Agriculture, Food and the Marine, Ireland) and the farmers and landowners of the study catchment. Thanks are extended to Prof. Des Walling and one anonymous reviewer for comments which greatly improved the manuscript.
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Sherriff, S.C., Franks, S.W., Rowan, J.S. et al. Uncertainty-based assessment of tracer selection, tracer non-conservativeness and multiple solutions in sediment fingerprinting using synthetic and field data. J Soils Sediments 15, 2101–2116 (2015). https://doi.org/10.1007/s11368-015-1123-5
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DOI: https://doi.org/10.1007/s11368-015-1123-5