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Enhancement in the selectivity of O2/N2 via ZIF-8/CA mixed-matrix membranes and the development of a thermodynamic model to predict the permeability of gases

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Abstract

Zeolitic imidazolate framework-8 (ZIF-8) has a sodalite topology. ZIF-8 is composed of zinc ion coordinated by four imidazolate rings. The pore aperture of ZIF-8 is 3.4 Å, which readily retains large gas molecules like N2. In this work, mixed-matrix membranes (MMMs) have been fabricated by utilizing ZIF-8 and pristine cellulose acetate (CA) for O2/N2 separation. Membranes of pristine CA and MMMs of ZIF-8/CA at various ZIF-8 concentrations were prepared in tetrahydrofuran (THF). Permeation results of the fabricated membranes revealed increasing selectivity for O2/N2 with increasing pressure as well as ZIF-8/CA concentration up to 5% (w/w). The selectivity of O2/N2 increased 4 times for MMMs containing 5% (w/w) of ZIF-8/CA as compared with the pristine CA membrane. A thermodynamic model has also been developed to predict the permeability of gases through polymeric membranes. The results were compared with literature data as well as the pristine CA membrane produced in this work for model validation.

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  1. School of Chemical & Materials Engineering (SCME), National University of Sciences & Technology (NUST), Islamabad, Pakistan

    Shakir Ul Azam, Arshad Hussain, Sarah Farrukh & Tayyaba Noor

  2. School of Energy and Power Engineering, Jiangsu University, Zhenjiang, China

    Yangxian Liu

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  1. Shakir Ul Azam
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  2. Arshad Hussain
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Correspondence to Sarah Farrukh.

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Azam, S.U., Hussain, A., Farrukh, S. et al. Enhancement in the selectivity of O2/N2 via ZIF-8/CA mixed-matrix membranes and the development of a thermodynamic model to predict the permeability of gases. Environ Sci Pollut Res 27, 24413–24429 (2020). https://doi.org/10.1007/s11356-020-08778-1

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