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Spent MgO-carbon refractory bricks as a material for permeable reactive barriers to treat a nickel- and cobalt-contaminated groundwater

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Abstract

Spent magnesia (MgO)-carbon refractory bricks were repurposed as a permeable reactive barrier reactive media to treat a nickel (5 mg l−1)- and cobalt (0.3 mg l−1)-contaminated groundwater. MgO has been used for decades as a heavy metal precipitating agent as it hydrates and buffers the pH in a range of 8.5–10 associated with the minimum solubility of various divalent metals. The contaminated groundwater site’s conditions are typical of contaminated neutral drainage with a pH of 6 as well as high concentrations of iron (220 mg l−1) and sulphates (2500 mg l−1). Using synthetic contaminated water, batch and small-scale column tests were performed to determine the treatment efficiency and longevity. The increase and stabilization of the pH at 10 observed during the tests are associated with the hydration and dissolution of the MgO and promoted the removal not only of a significant proportion of the contaminants but also of iron. During the column test, this accumulation of precipitates over time clogged and passivated the MgO resulting in a loss of chemical performance (pH lowering, metal breakthrough) after 210 pore volumes of filtration. Precipitation also affected the hydraulic conductivity values which dropped from 2.3·10−3 to 4.2·10−4 m s−1 at the end of test. Saturation indices and XRD analyses suggest the precipitates formed are likely composed of goethite as well as iron, cobalt and nickel hydroxides. Recycled MgO-C refractory bricks were demonstrated to be an efficient reactive material for the removal of Co and Ni, but careful considerations should be taken of the potential clogging and passivation phenomena given particular physicochemical conditions.

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References

  • Bildstein O (1998) Modélisation géochimique des interactions eau-gaz-roche Application a la diagenèse minérale dans les réservoirs géologiques. Université de Strasbourg 1 (in French)

  • Blowes DW, Ptacek CJ, Benner SG, McRae CWT, Bennett TA, Puls RW (2000) Treatment of inorganic contaminants using permeable reactive barriers. J Contam Hydrol 45:123–137

    Article  CAS  Google Scholar 

  • Calugaru IL, Neculita CM, Genty T, Bussière B, Potvin R (2016) Performance of thermally activated dolomite for the treatment of Ni and Zn in contaminated neutral drainage. J Hazard Mater 310:48–55

    Article  CAS  Google Scholar 

  • Calugaru IL, Neculita CM, Genty T, Zagury GJ (2018) Metals and metalloids treatment in contaminated neutral effluents using modified materials. J Environ Manag 212:142–159

    Article  CAS  Google Scholar 

  • Caraballo MA, Rötting TS, Silva V (2010) Implementation of an MgO-based metal removal step in the passive treatment system of Shilbottle, UK: Column experiments. J Hazard Mater 181:923–930

    Article  CAS  Google Scholar 

  • Chimenos J, Fernandez A, Villalba G, Segarra M, Urruticoechea A, Artaza B, Espiell F (2003) Removal of ammonium and phosphates from wastewater resulting from the process of cochineal extraction using MgO-containing by-product. Water Res 37:1601–1607

    Article  CAS  Google Scholar 

  • Cortina J-L, Lagreca I, De Pablo J, Cama J, Ayora C (2003) Passive in situ remediation of metal-polluted water with caustic magnesia: evidence from column experiments. Environ Sci Technol 37:1971–1977

    Article  CAS  Google Scholar 

  • Courcelles B, Modaressi-Farahmand-Razavi A, Gouvenot D, Esnault-Filet A (2011) Influence of precipitates on hydraulic performance of permeable reactive barrier filters. Int J Geomech 11:142–151

    Article  Google Scholar 

  • Davies PJ, Bubela B (1973) The transformation of nesquehonite into hydromagnesite. Chem Geol 12:289–300

    Article  CAS  Google Scholar 

  • de Repentigny C, Courcelles B (2014) A simplified model to predict clogging of reactive barriers. Environ Geotechn 3:166–177

    Article  Google Scholar 

  • del Valle-Zermeño R, Giró-Paloma J, Formosa J, Chimenos J (2015) Low-grade magnesium oxide by-products for environmental solutions: characterization and geochemical performance. J Geochem Explor 152:134–144

    Article  CAS  Google Scholar 

  • Faghihi-Sani M-A, Yamaguchi A (2002) Oxidation kinetics of MgO–C refractory bricks. Ceram Int 28:835–839

    Article  CAS  Google Scholar 

  • Gibert O, de Pablo J, Luis Cortina J, Ayora C (2003) Evaluation of municipal compost/limestone/iron mixtures as filling material for permeable reactive barriers for in-situ acid mine drainage treatment. J Chem Technol Biotechnol 78:489–496

    Article  CAS  Google Scholar 

  • Gustafsson J (2011) Visual MINTEQ ver. 3.0 KTH Department of Land and Water Resources Engineering, Stockholm, Sweden Based on de Allison JD, Brown DS, Novo-Gradac KJ, MINTEQA2 ver 4, 1991

  • Hänchen M, Prigiobbe V, Baciocchi R, Mazzotti M (2008) Precipitation in the Mg-carbonate system—effects of temperature and CO2 pressure. Chem Eng Sci 63:1012–1028

    Article  CAS  Google Scholar 

  • ITRC (2011) Permeable reactive barrier: technology update. The Interstate Technology & Regulatory Council, PRB: Technology Update Team, Washington, D.C.

    Google Scholar 

  • Jin F, Al-Tabbaa A (2014) Characterisation of different commercial reactive magnesia. Adv Cem Res 26:101–113

    Article  CAS  Google Scholar 

  • Kojima Y, Sadotomo A, Yasue T, Arai Y (1992) Control of crystal shape and modification of calcium carbonate prepared by precipitation from calcium hydrogencarbonate solution. J Ceram Soc Jpn 100:1145–1153

    Article  CAS  Google Scholar 

  • Macías F, Caraballo MA, Rötting TS, Pérez-López R, Nieto JM, Ayora C (2012) From highly polluted Zn-rich acid mine drainage to non-metallic waters: implementation of a multi-step alkaline passive treatment system to remediate metal pollution. Sci Total Environ 433:323–330

    Article  CAS  Google Scholar 

  • MOE (2011) Soil, ground water and sediment standards for use under part XV.1 of the Environmental Protection Act. Table 9—generic site condition standards for use within 30 m of a water body in a non-potable ground water condition. Ontario Ministry of the Environment

  • Navarro A, Chimenos JM, Muntaner D, Fernandez AI (2006) Permeable reactive barriers for the removal of heavy metals: lab-scale experiments with low-grade magnesium oxide. Ground Water Monit Remediat 26:142–152

    Article  CAS  Google Scholar 

  • Obiri-Nyarko F, Grajales-Mesa SJ, Malina G (2014) An overview of permeable reactive barriers for in situ sustainable groundwater remediation. Chemosphere 111:243–259

    Article  CAS  Google Scholar 

  • Oustadakis P, Agatzini-Leonardou S, Tsakiridis PE (2006) Nickel and cobalt precipitation from sulphate leach liquor using MgO pulp as neutralizing agent. Miner Eng 19:1204–1211

    Article  CAS  Google Scholar 

  • Rocha SD, Mansur MB, Ciminelli VS (2004) Kinetics and mechanistic analysis of caustic magnesia hydration. J Chem Technol Biotechnol 79:816–821

    Article  CAS  Google Scholar 

  • Rötting TS, Ayora C, Carrera J (2008) Improved passive treatment of high Zn and Mn concentrations using caustic magnesia (MgO): particle size effects. Environ Sci Technol 42:9370–9377

    Article  CAS  Google Scholar 

  • Rötting TS, Cama J, Ayora C, Cortina J-L, De Pablo J (2006) Use of caustic magnesia to remove cadmium, nickel, and cobalt from water in passive treatment systems: column experiments. Environ Sci Technol 40:6438–6443

    Article  CAS  Google Scholar 

  • Schiller JE, Tallman DN, Khalafalla SE (1984) Mineral processing water treatment using magnesium oxide. Environ Prog 3:136–141

    Article  CAS  Google Scholar 

  • Terringo J III (1987) Magnesium hydroxide reduces sludge/improves filtering. Pollut Eng 19:78–83

    Google Scholar 

  • USEPA (2008) Incorporating sustainable environmental practices into remediation of contaminated sites. U.S. Environmental Protection Agency. Office of Solid Waste and Emergency Response

  • Wray JL, Daniels F (1957) Precipitation of calcite and aragonite. J Am Chem Soc 79:2031–2034

    Article  CAS  Google Scholar 

  • Zagury GJ, Colombano SM, Narasiah KS, Ballivy G (1997) Neutralization of acid mine tailings by addition of alkaline sludges from pulp and paper industry. Environ Technol 18:959–973

    CAS  Google Scholar 

  • Zagury GJ, Kulnieks VI, Neculita CM (2006) Characterization and reactivity assessment of organic substrates for sulphate-reducing bacteria in acid mine drainage treatment. Chemosphere 64:944–954

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors would like to thank the Quebec Fonds de Recherche Nature et Technologies, the Natural Sciences and Engineering Research Council of Canada and BluMetric Environmental Inc. for supporting this research.

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Authors and Affiliations

  1. Department of Civil, Geological and Mining Engineering, Polytechnique Montréal, Montreal, QC, H3C 3A7, Canada

    Carl de Repentigny, Benoît Courcelles & Gérald J. Zagury

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  1. Carl de Repentigny
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  2. Benoît Courcelles
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  3. Gérald J. Zagury
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Correspondence to Gérald J. Zagury.

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Responsible editor: Bingcai Pan

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de Repentigny, C., Courcelles, B. & Zagury, G.J. Spent MgO-carbon refractory bricks as a material for permeable reactive barriers to treat a nickel- and cobalt-contaminated groundwater. Environ Sci Pollut Res 25, 23205–23214 (2018). https://doi.org/10.1007/s11356-018-2414-3

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