Abstract
Objective
This work aims to investigate the correlation between the photocatalytic activity determined by methylene blue bleaching (DIN 52980), stearic acid degradation, and degradation of acetone in gas phase.
Method
The photocatalytic TiO2 coatings included in this investigation ranged from thin commercially available coatings (ActivTM and BioCleanTM) and ready to use suspensions (Nano-X PK1245) to lab-produced PVD and sol–gel coatings. XRD analysis of the photocatalytic coatings showed that all the coatings consisted of nanocrystalline anatase, although the thickness and porosity varied considerably.
Results
The study showed that the reproducibility of the activity measurements was good. However, more importantly, the investigation showed that there is a good correlation between the activities determined by the different methods even though the characteristics of the photocatalytic coatings and the organic probe molecules varied considerably.
Conclusion
The overall findings of this work suggest that there is a good correlation between the investigated methods. These results are promising for the future work concerning standardization of methods for determination of the activity of photocatalytic films.
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The authors would like to acknowledge the Danish Agency for Science, Technology and Innovation under the Danish Ministry of Science, Technology and Innovation and the members of the Clean Catalytic Surfaces Consortium for funding of this research.
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Simonsen, M.E., Sørensen, M.B. & Søgaard, E.G. Comparison of methods for evaluation of activity of photocatalytic films. Environ Sci Pollut Res 19, 3772–3781 (2012). https://doi.org/10.1007/s11356-011-0695-x
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DOI: https://doi.org/10.1007/s11356-011-0695-x