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Removal of Fluoride from Water by Adsorption onto Lanthanum Oxide

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Abstract

Rare earth mineral based adsorbent viz. lanthanum oxide was investigated for potential application in defluoridation of drinking water for isolated and rural communities. Results of batch experiments indicated about 90% removal in 30 min from a 4 mg L−1 synthetic fluoride solution. The effects of various parameters like contact time, pH, initial concentration, and sorbent dose on sorption efficiency were investigated. Adsorption efficiency was dependent on initial fluoride concentration and the sorption process followed BET model. Variation of pH up to 9.5 has insignificant effect on sorption and beyond a pH of 9.5, the effect was drastic. Among anions investigated, carbonates exhibited high detrimental effect on fluoride adsorption while anions like bicarbonates, chlorides, and sulfates did not seriously affect the process. Adsorbent showed negligible desorption of fluoride in distilled water. Alum was more effective regenerant than HCl and NaOH. Results of cyclic regeneration with alum indicated that the sorbent could be regenerated for ten cycles without significant loss of sorption capacity. Studies with upflow fixed-bed continuous flow columns indicated the usefulness of sorbent for fluoride removal in continuous flow process.

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References

  • Alexander, F., & McKay, M. (1977). Kinetics of the removal of basic dye from effluents using silica (Part I). Chemical Engineer, 31(9), 243.

    Google Scholar 

  • APHA. (1995). Standard Methods for Examination of Water and Wastewater (19th ed.). Washington: APHA, AWWA, WEF.

    Google Scholar 

  • Bhakuni, T.A. (1970) Studies on removal of Fluorides from drinking water by different ion exchange materials developed indigenously, Ph.D. Thesis, University of Nagpur, Nagpur, India.

  • Bishop, P. L. & Sansoucy, G. (1978). Fluoride removal from drinking water by fludized activated alumina. J American Water Works Association, 70(10), 554–558.

    Google Scholar 

  • Boruff, C. S. (1934). Removal of fluorides from drinking water. Industrial and Engineering Chemistry, 26(1), 69–71.

    Article  CAS  Google Scholar 

  • Brunauer, J., Emmett, P. H., & Teller, E. (1938). Adsorption of gases in multimolecular layers. Journal of the American Chemical Society, 60, 309.

    Article  CAS  Google Scholar 

  • Bulusu, K. R., & Pathak, B. N. (1969). Fluorine—It’s Effect on Human Health and Defluoridation of Water—Methods and Their Limitations. Nagpur: National Environmental Engineering Research Institute Report.

    Google Scholar 

  • Bulusu, K. R., Sundaresan, B. B., Pathak, B. N., Nawlakhe, W. G., Kulkarni, D. N., & Thergaonkar, V. P. (1979). Fluoride in water, defluoridation methods and their limitations. J. Institution of Engineers (India). Environmental Engineering Division, 60, 1–25.

    Google Scholar 

  • Bureau of Indian Standards: IS 10500–1991. Drinking Water Specifications, Third Reprint, 1996, Bureau of Indian Standards, New Delhi, India

  • Chen, D. Z., Zhang, J. X., & Chen, J. M. (2010). Adsorption of methyl tert-butyl ether using granular activated carbon: Equilibrium and kinetic analysis. Int. J. Environ. Sci. Tech., 7(2), 235–242.

    CAS  Google Scholar 

  • Crank, J. (1965). The Mathematics of Diffusion. London: Clarendon.

    Google Scholar 

  • Davis, J. A., & Leckie, J. O. (1980). Surface ionization and complexation at the oxide/water interface. J. Colloid and Interface Science, 74(1), 32.

    Article  CAS  Google Scholar 

  • Fink, G. J., & Lindsay, F. K. (1936). Activated alumina for removing fluorides from drinking water. Industrial and Engineering Chemistry, 28(80), 947–948.

    Article  CAS  Google Scholar 

  • Giles, C. H. (1970). Interpretation and use of sorption isotherms. Sorption and Transport in Soils, S.C.I. Monograph No.37. London: Society of Chemical Industry.

    Google Scholar 

  • Gupta, G. S., Prasad, G., Pandey, K. K., & Singh, V. N. (1988). Removal of chrome dye from aqueous solutions by fly ash. J Water, Air, and Soil Pollution, 37, 13.

    CAS  Google Scholar 

  • Helfferich, F. (1962). Ion Exchange. New York: McGraw-Hill Book Company Inc.

    Google Scholar 

  • Hendricks, D. W., & Kuratti, L. G. (1982). Derivation of an empirical sorption equation by analysis of experimental data. Water Research, 16(6), 829.

    Article  CAS  Google Scholar 

  • Imai, H., Nomura, J., Ishibashi, Y., & Konishi, T. (1987). Nippon Kagaku Kaishi, 5, 807.

    Article  Google Scholar 

  • Islam, M., Mishra, P. C., & Patel, R. (2010). Fluoride adsorption fromaqueous solution by a hybrid thorium phosphate composite. Chemical Engineering Journal, 166(3), 978–985.

    Article  Google Scholar 

  • Jiao, Z., Zhang, Y., Yang, M., Huang, X., & Ma, Ke-Min. (2002). Removal of Fluoride using rare earth based inorganic adsorbent, State Key Lab. of Environmental aquatic chemistry, Research Center for Eco-Environmental Science, Chinese Academy of Sciences, Beijing, China. Huanjing Huaxue, 21(4), 365–370.

    CAS  Google Scholar 

  • Karthikeyan, J. (1982) Enhancement of mercury (II) removal by coal through Chemical treatment, M.Tech. Thesis, Dept. of Civil Engineering, IIT, Kanpur, India.

  • Kaufhold, S., Dohrmann, R., Abidin, Z., Henmi, T., Matsue, N., Eichinger, A., et al. (2010). Allophane compared with other sorbent minerals for the removal of fluorides from water with a particular focus on a minerable Ecuadorian allophane. Applied Clay Science, 50(1), 25–33.

    Article  CAS  Google Scholar 

  • Kenesato, M., Yokoyama, T., & Suzuki, T. (1988). Chemical Letter, 2, 207.

    Article  Google Scholar 

  • Killedar, D. J., & Bhargava, D. S. (1988a). An overview of defluoridation methods (Part I). J Institute of Public Health Engineers (India), 1988(1), 6–13.

    Google Scholar 

  • Killedar, D. J., & Bhargava, D. S. (1988b). An overview of defluoridation methods (Part II). J Institute of Public Health Engineers (India), 1988(2), 37–44.

    Google Scholar 

  • Kulkarni, D., & Nawlakhe, G. W. (1974). Serpentine—Its limitations as a defluoridation medium. Indian J. of Environmental Health, 16, 151.

    CAS  Google Scholar 

  • McKay, G. (1980). Color removal by adsorption. American Dyestuff Reporter, 67(3), 38.

    Google Scholar 

  • McKay, G., Otternburn, M. S., & Sweeney, A. G. (1980). The removal of color from effluent using various adsorbent-III silica: Rate processes. Water Research, 14, 15.

    Article  CAS  Google Scholar 

  • McKee, R. H., & Jhonston, W. S. (1934). Removal of fluorides from drinking water. Industrial and Engineering Chemistry, 26(8), 849–850.

    Article  CAS  Google Scholar 

  • Michelson, L.D., Gideon, P.G., Pace, E.G. and Kutat, L.H. (1975). Removal of soluble mercury from wastewaters by complexing technique, Bulletin No. 74, USDI Office of Water Research and Technology.

  • Mlilo, T. B., Brunson, L. R., & Sabatini, D. A. (2010). Arsenic and fluoride removal using simple materials. J. Environmental Engineering Division, ASCE, 136(4), 391–398.

    Article  CAS  Google Scholar 

  • Muthukumaran, K. (1995) Studies on chemically activated carbon for the removal of trace inorganics from water, Ph.D. Thesis, Dept. of Chemistry, IIT, Madras, India.

  • Nawlakhe, W. G., Kulkarni, D. N., Pathak, B. N., & Bulusu, K. R. (1975). Defluoridation of water by Nalgonda Technique. Indian Journal of Environmental Health, 17(1), 26.

    CAS  Google Scholar 

  • Raichur, A. M., & Jyothi Basu, M. (2001). Adsorption of fluoride onto mixed rare earth oxides. Separation and Purification Technology, 24, 121–127.

    Article  CAS  Google Scholar 

  • Savinelli, E. A., & Black, A. P. (1958). Defluoridation of water with activated alumina. J American Water Works Association, 50(1), 33–44.

    CAS  Google Scholar 

  • Smith, H. V., & Smith, H. C. (1937). Bone contact removes fluorides. Water Works Engineering, 97(1), 990.

    Google Scholar 

  • Swope, G. H., & Hess, R. H. (1937). Removal of fluoride from natural water by deFluoride. Industrial and Engineering Chemistry, 29(40), 424–426.

    Article  CAS  Google Scholar 

  • Tokunaga, S., Hakuta, T., & Wasay, S. A. (1999). Journal of the National Institute of Materials and Chemical Research, 7(6), 291–334.

    CAS  Google Scholar 

  • Venkata Mohan, S., & Karthikeyan, J. (1997). Removal of lignin and tannin colour from aqueous solution by adsorption onto activated charcoal. Environmental Pollution, 97(1–2), 183–187.

    Article  Google Scholar 

  • Weber, W. J., Jr. (1972). Physicochemical processes for water and quality control. New York: Wiley Inter Science.

    Google Scholar 

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Authors and Affiliations

  1. National Institute of Technical Teachers Training and Research (Chennai), Hyderabad Extension Centre, S. V. Bhavan, Masab Tank, Hyderabad, 500 028. A. P, India

    C. R. Nagendra Rao

  2. Department of Civil Engineering, SVU College of Engineering, Tirupati, 517 502, Andhra Pradesh, India

    Janakiraman Karthikeyan

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  1. C. R. Nagendra Rao
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  2. Janakiraman Karthikeyan
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Correspondence to Janakiraman Karthikeyan.

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Rao, C.R.N., Karthikeyan, J. Removal of Fluoride from Water by Adsorption onto Lanthanum Oxide. Water Air Soil Pollut 223, 1101–1114 (2012). https://doi.org/10.1007/s11270-011-0928-0

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  • DOI: https://doi.org/10.1007/s11270-011-0928-0

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